CAS 121-69-7 MFCD00008304-N,N-Dimethylaniline N,N-二甲基苯胺 TAO{mole}

N,N-Dimethylaniline N,N-二甲基苯胺

CAS 121-69-7 MFCD00008304

化学结构图

SMILES: CN(C)c1ccccc1

化学属性

Mol. Formula	C8H11N
Mol. Weight	121
Density	0.95
Refractive index	1.5560 to 1.5600
Boiling Point	193-194
Melting Point	1.5-2.5
Flash Point	73°C(lit.)
TSCA	Yes
Solubility	1 G/L (20 ºC)
Stability	对光敏感
pH	:A

别名和识别编码

Chemical Name	N,N-Dimethylaniline
Synonym	(Dimethylamino)benzene (Dimethylamino)benzol ACETIC ACID DIMETHYLAMIDE Aniline, N,N-dimethyl- DIMETHYLAMINOBENZENE Dimethylanilin Dimethylphenylamine N,N-(Dimethylamino)benzene N,N-DIMETHYLACETAMIDE N,N-Dimethylaminobenzene N,N-Dimethylaminobenzol N,N-Dimethylaniline N,N-Dimethylbenzenamine N,N-dimethyl-aniline N,N-二甲基苯胺 N,N-二甲苯胺,二甲基苯胺 N-二甲基苯胺 NCI-C56428 Versneller NL 63/10 u-5954 二甲氨基苯
CAS Number	121-69-7
EC Number	204-493-5
Beilstein Registry Number	507140
MDL Number	MFCD00008304
PubChem Substance ID	949
Merck Number	3234
Reaxys-RN	507140
Chemical Name Translation	N,N-二甲基苯胺
Wiswesser Line Notation	1N1&R
LabNetwork Molecule ID	LN00198806
InChI	InChI=1S/C8H11N/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

检定甲醇、甲基呋喃甲醛、过氧化氢、硝酸盐、乙醇、甲醛和叔胺，比色测定亚硝酸盐等，溶剂，制造香荚兰素、甲基紫、米蚩酮和其他染料。亦用于对称和不对称光导体新工艺。

安全信息

Signal word Danger

GHS Symbol

WGK Germany3

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R36 Irritating to eyes 刺激眼睛
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R51/53
R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P301+P312+P330
P302+P350
P304+P340
P305+P351+P338
P308+P313
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P332+P313
P337+P313
P370+P378
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H351 Suspected of causing cancer 怀疑致癌
H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
H319 Causes serious eye irritation 严重刺激眼睛
H301+H311+H331
H331 Toxic if inhaled 吸入中毒
H311 Toxic in contact with skin 皮肤接触中毒
H301 Toxic if swallowed 吞食有毒
H227 Combustible liquid 可燃液体

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSBX4725000

Packing GroupII

UN Number 2253 UN 2253 6.1/PG 2

Hazard Codes 6.1 T,N

Storage condition 密封避光保存。 0-6°C

Hazard Class6.1

Warnings 危化品目录(2015)

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 15450 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Endocrine - tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-360,1989

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 15450 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Endocrine - tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-360,1989

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1410 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : LDLo - Lowest published let

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 250 mg/m3/4H
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - excitement
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 37(4),35,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1770 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Gastrointestinal - nausea or vomiting
   Gastrointestinal - other changes
REFERENCE :
   NCPBBY National Clearinghouse for Poison Control Centers, Bulletin.  (U.S.
   Department of Health, Education, and Welfare, Washington, DC)
   Volume(issue)/page/year: Jan/Feb,1969

TYPE O

TYPE OF TEST            : Micronucleus test
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 900 umol/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   21,349,1993

TYPE OF TEST            : DNA damage
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 485 mg/kg
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   21,349,1993

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 30 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   13,60,1989

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 83 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   13,60,1989

TYPE OF TEST            : DNA damage
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 485 mg/kg
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   21,349,1993

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 20 mg/L
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Vo

Restrict 危险品

其他信息

{
毒性分级:中毒
Alfa Aesar:N,N-二甲基苯胺,99% N,
下游产品:2,6-二三氟甲基-4-氯嘧啶 --> 亚甲兰 --> 碱性蓝 26 --> 2-三氟甲基-4-氯嘧啶 --> 6-氰嘌呤 --> 2,4-二甲氧基嘧啶-6-甲酸 --> 6-苄胺基嘌呤 --> 3-[(甲氧羰基)氨基]苯基-N-(3-甲基苯基)氨基甲酸酯 --> 米非司酮 --> 甲基红 --> 2-氨基-4-乙基吡啶 --> 酸性紫 17 --> 敌克松 --> 2,4-二硝基苯甲醛 --> 6-碘嘌呤 --> N,N,N',N'-四甲基联苯胺 --> 4,6-二氯-5-溴嘧啶 --> 6-二甲基氨基嘌呤 --> 4,4'-(对二甲氨基)二苯基甲烷 --> 碱性品绿 --> 溶剂紫 8 --> 4-溴-N,N-二甲基苯胺 --> 碱性兰53 --> 助拨剂 O,二甲基苄基苯基氯化铵 --> 金胺 --> 2,4-二氯-5-氟嘧啶 --> 7-甲基鸟嘌呤 --> 4,4^<'^>-双(二甲基氨基)二苯甲酮 --> 碱性红22 --> 健那绿 B --> 碱性染料 --> N,N-二甲基-3-硝基苯胺
刺激数据:皮肤- 兔子 10 毫克/24小时轻度; 眼-兔子 LD50: 20 毫克/24小时中度
N,N-二甲基苯胺价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80051218 N，N-二甲基苯胺;二甲氨基苯 500ml 25元 2011/08/23 80051228 N，N-二甲基苯胺;二甲氨基苯 500ml 24元 2011/04/16 D3866 N,N-二甲基苯胺[用于生化研究] N,
防护措施:高毒。吸入其蒸气或经皮肤吸收引起中毒。其毒性和苯胺大致相同。具有血液毒、神经毒和致癌性。空气中最高容许浓度5×10 -6。应避免与皮肤接触。操作现场应有良好通风，设备应密闭。操作人员要穿戴防护用具。
爆炸物危险特性:与空气混合可爆
图谱信息:N,N-二甲基苯胺(121-69-7)核磁图( 13 CNMR) N,N-二甲基苯胺(121-69-7)红外图谱(IR1) N,N-二甲基苯胺(121-69-7)质谱(MS) N,N-二甲基苯胺(121-69-7)核磁图( 1 HNMR)
MOL 文件:121-69-7.mol
常规方法:采用铁桶密封包装，每桶180kg。贮存于阴凉通风处。按易燃有毒物品规定贮运。
蒸气密度:3 (vs air)
类别:有毒物品
用途五:检定甲醇、甲基呋喃甲醛、过氧化氢、硝酸盐、乙醇、甲醛和叔胺，比色测定亚硝酸盐等，溶剂，制造香荚兰素、甲基紫、米蚩酮和其他染料。亦用于对称和不对称光导体新工艺。
用途四:该品为重要的染料中间体。可用于制备碱性嫩黄、碱性紫5BN、碱性品绿、碱性湖蓝BB、碱性艳蓝R、阳离子红2BL、艳红5GN、紫3BL、艳蓝等。在医药工业中，该品可用于制造头孢菌素V、磺胺-b-甲氧嘧啶、磺胺
MSDS 信息:N,N-二甲基苯胺(121-69-7).msds
Acros Organics:N,N-二甲基苯胺 N,N-Dimethylaniline, 99%(121-69-7)
N,N-二甲基苯胺价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80051218 N，N-二甲基苯胺;二甲氨基苯 500ml 25元 2011/08/23 80051228 N，N-二甲基苯胺;二甲氨基苯 500ml 24元 2011/04/16 D3866 N,N-二甲基苯胺[用于生化研究] N,N-Dimet
蒸气压:2 mm Hg ( 25 °C)
上游原料:氨基苯 --> 磷酸三甲酯
方法一:由苯胺与甲醇在硫酸存在下，经高温高压反应而得。原料消耗定额：苯胺790kg/
外观性质:黄色油状液体。
用途四:该品为重要的染料中间体。可用于制备碱性嫩黄、碱性紫5BN、碱性品