CAS 106-99-0 MFCD00008659-1,3-Butadiene 1,3-丁二烯 TAO{mole}

1,3-Butadiene 1,3-丁二烯

CAS 106-99-0 MFCD00008659

化学结构图

SMILES: C=CC=C

化学属性

Mol. Formula	C4H6
Mol. Weight	54.09
Autoignition Point	788 °F
Density	0.62 g/mL at 20 °C(lit.)
Vapor Density	1.9 (15 °C, vs air)
Boiling Point	-4.5 °C(lit.)
Vapor Pressure	1863 mmHg ( 21 °C)
Melting Point	-109 °C(lit.)
Refractive index	n20/D 1.376
Solubility	溶于丙酮、苯、乙酸、酯等多数有机溶剂。
Flash Point	-105 °F
Stability	对热和湿度敏感
Danger-Level	-
pH	-:-
Redox	-

别名和识别编码

Chemical Name	Buta-1,3-Diene
MDL Number	MFCD00008659
CAS Number	106-99-0
Synonym	1,3-butadiene Vinylethylene BUTADIENE {uni_hamburg} 1 乙烯基乙烯 BIETHYLENE 丁间二烯 VINYLETHYLENE butadiene(non-specificname) Α,Γ-丁二烯 1，3-丁二烯 divinyl BIVINYL α,γ-butadiene 联乙烯二乙烯 a,g-Butadiene Butadieen alpha-butadiene 雙乙烯基 alpha,gamma-Butadiene Bivinyl 1,3-丁二烯 1,3-BUTADIENE NCI-C50602 Butadien-(1,3) PYRROLYLENE butadien(polish) 3-丁二烯丁二烯残液 Biethylene Erythrene 雙乙烯 Butadiene Buta-1,3-dien 1,3-Butadiene vinylethylene 聯乙烯 Buta-1,3-diene bivinyl (E)-CH2=CHCH=CH2 1,3-丁二烯 062-01 [2.1] Butadien erythrene a, g-Butadiene DIVINYL Buta-1,3-dieen butadiene-1,3 1,3-丁二烯溶液 Pyrrolylene BUDIENE buta-1,3-diene biethylene ERYTHRENE 1-methylallene Divinyl 丁二烯 C₄H₆ (buta-1,3-diene)
EC Number	203-450-8
Beilstein Registry Number	605258
PubChem Substance ID	253660912
Chemical Name Translation	1,3-丁二烯
Merck Number	1509
Reaxys-RN	605258
Wiswesser Line Notation	1U2U1
LabNetwork Molecule ID	LN00241931
InChI	InChI=1S/C4H6/c1-3-4-2/h3-4H,1-2H2

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产品应用

丁二烯是生产合成橡胶（丁苯橡胶、顺丁橡胶、丁腈橡胶、氯丁橡胶）的主要原料。

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
H350 May cause cancer 可能致癌
H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
H340 May cause genetic defects 可能导致遗传性缺陷
H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
H220 Extremely flammable gas 极易燃气体。
H280 Contains gas under pressure; may explode if heated 内含高压气体，遇热可能爆炸。

Precautionary statements

P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P410+P403
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P308+P313
P201 Obtain special instructions before use. 使用前获取专门指示。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P332+P313
P501 Dispose of contents/container to..… 处理内容物/容器.....
P301+P312+P330
P337+P313
P403+P233
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P303+P361+P353
P302+P352+P332+P313+P362+P364
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P301+P310
P304+P340+P312
P331 Do NOT induce vomiting.. 不要催吐。
P304+P340
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P304+

Signal word Danger

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Eyeshields, Faceshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)

Safety Statements

S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S33 Take precautionary measures against static discharges 对静电采取预防措施；
S46 If swallowed, seek medical advice immediately and show this container or label 食入时，立即求医并出示容器/标签；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Hazard Codes F+,T F+,T,F,N F,T F,T,N

Risk Statements

R46 May cause inheritable genetic damage 可能引起遗传基因损害
R12 Extremely flammable 极端易燃
R45 May cause cancer 可能致癌
R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
R11 Highly flammable 非常易燃
R48/20
R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
R51/53
R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
R38 Irritating to skin 刺激皮肤
R62 Possible risk of impaired fertility 有削弱生殖能力的危险

Storage condition 0-6°C 0-10°C 储存温度-20℃

Hazard Class3

UN Number UN 1010 2.1 1993

RTECSEI9275000

Packing GroupII

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 625 ppm/6H/13W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Sense Organs and Special Senses (Olfaction) - tumors
   Cardiac - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   50,6592,1990

TYPE OF TEST            : TC - Toxic concentration (other than lowest)
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8000 ppm/6H/2Y-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Gastrointestinal - tumors
   Endocrine - thyroid tumors
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   48,407,1987

TYPE OF TEST            : TC - Toxic concentration (other than lowest)
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 ppm/40W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Gastrointestinal - tumors
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 86,37,1990

TYPE OF TEST            : TC - Toxic concentration (other than lowest)
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 63 ppm/6H/2Y-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Vascular - tumors
   Liver - tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 2000 ppm/7H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - effect, not otherwise specified
   Behavioral - hallucinations, distorted perceptions
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information,

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 285 gm/m3/4H
TOXIC EFFECTS :
   Behavioral - general anesthetic
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   RPTOAN Russian Pharmacology and Toxicology (English Translation).
   Translation of FATOAO.  (Euromed Pub., 33, Woodlands Rd., Surbiton, Surrey,
   UK)  V.30-    1967-  Volume(issue)/page/year: 31,162,1968

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 8000 ppm
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - visual field changes
   Sense Organs and Special Senses (Eye) - conjunctive irritation
   Lungs, Thorax, or Respiration - cough
REFERENCE :
   INMEAF Industrial Medicine.  (Chicago, IL)  V.1-18, 1932-49.  For publisher
   information, see IOHSA5.  Volume(issue)/page/year: 17,199,1948

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5480 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,14,1986

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 2 pph
REFERENCE :
   TOLED5 Toxicology Letters.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1977-  Volume(issue)/page/year: 6,125,1980

TYPE OF TEST            : Sperm Morphology
ROUTE OF EXPOSURE       : Inhalation
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 130 ppm/5D/6H (Continuous)
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pu

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 500 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 2

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Inhalation
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 625 ppm/6H/10D (Intermittent)
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 9,235,1987

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 25 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 263,47,1991

TYPE OF TEST            : Mutation in mammalian somatic cells
ROUTE OF EXPOSURE       : Inhalation
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 625 ppm/6H/2W (Intermittent)
REFERENCE :
   CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House,
   Southfield Road, Eynsham, Oxford OX8 1JJ, UK)  V.1-    1980-
   Volume(issue)/page/year: 15,719,1994

TY

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 8000 ppm/6H
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   EPASR* United States Environmental Protection Agency, Office of Pesticides
   and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW,
   Washington, DC 20460)  History unknown.  Volume(issue)/page/year:
   8EHQ-0382-0441

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 1000 ppm/6H
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Maternal Effects - uterus, cervix, vagina
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 86,79,1990

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 500 ppm/6H
SEX/DURATION            : male 5 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
   Reproductive - Effects on Embryo or Fetus - cytological changes (including
   somatic cell genetic material)
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amste

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 1000 ppm/6H
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS

Restrict -

其他信息

外观性质:无色无臭气体。
上游原料:甲苯 --> 氮 --> 乙腈 --> 石脑油，原油 --> 碳化钙 --> 正丁烷
常规方法:丁二烯在贮存中易聚合，主要由于容器中存在空气以至生成过氧化物。避免的方法是保证容器清洁和干燥，并进行惰性气体置换和氮封。较长时间贮存及运输时，为防止其自动聚合，需考虑加入一定量的阻聚剂。加入阻聚剂的丁二烯在使用前必须进行酸洗（无机酸）脱除阻聚剂。
TCI Shanghai:1,3-丁二烯(置于无阀气瓶中)(含稳定剂叔丁基邻苯二酚) 1,3-Butadiene (stabilized with TBC) (in cylinder without valve) [To use this product charged in cylinder, a valve is required which is sold separately (Product Code:V0030)],>;95.0%(GC)(106-99-0)
防护措施:本品毒性较小，其毒性与乙烯类似，但对皮肤和粘膜的刺激较强，高浓度时有麻醉作用。动物吸入0.67%浓度的丁二烯，每天7.5小时，经8个月，除少数例外，一般对生长和健康无妨碍。工作场所最高容许浓度为2200mg/m3。液态丁二烯因低温可造成冻伤
用途二:丁二烯是生产合成橡胶（丁苯橡胶、顺丁橡胶、丁腈橡胶、氯丁橡胶）的主要原料。随着苯乙烯塑料的发展，利用苯乙烯与丁二烯共聚，生产各种用途广泛的树脂（如ABS树脂、SBS树脂、BS树脂、MBS树脂），使丁二烯在树脂生产中逐渐占有重要地位。此外，丁二
急
储运特性:库房通风低温干燥; 轻装轻卸; 与氧气、空气等助燃气体钢瓶分开存放
用途一:用作合成橡胶、合成树脂、合成纤维、增塑剂和乳胶漆等的原料
下游产品:环丁砜 --> 1,6-已烷二胺 --> 聚苯乙烯丁二烯共聚物 --> 离子交换树脂 --> 4-乙烯基-1-环己烯二环氧化物,异构体混合物 --> 杂醇油 --> 正丁烯 --> N-羟甲基-3,4,5,6-四氢邻苯二甲酰亚胺 --> 2-(2-氯乙氧基)苯磺酰胺 --> 克菌丹 --> 1,4-二氰基丁烷 --> 甲萘醌 --> 四氢苯酐 --> 顺丁烯二酰肼 --> 交联剂 --> 六溴环十二烷 --> 仲丁醇 --> 十二烷二酸 --> 乙叉降冰生烯 --> N,N,N',N'-四甲基-2-丁烯-1,4-二胺 --> 甲基丙烯腈 --> 改性SBR涂饰剂 --> 环十二烷 --> 四氢化邻苯二甲酸酐 --> 酮麝香 --> 丁腈胶NBR --> 聚丁二烯 --> ABS 树脂 --> 1-烯丙基丙烯 --> 3-环丁烯砜 --> 聚乙烯吡咯烷酮 --> LHYJ-DS50型丁二烯树脂乳液 --> 1,5,9-环十二烷三烯 --> 2,4,4-三甲基-1-戊烯 --> 钛、钴齐格勒催化剂等 --> 羧基丁苯胶乳 --> 4-(2,5,6,6-四甲基-2-环己烯-1-基)-3-丁烯-2-酮 --> 丁苯胶乳 --> 1,4-二乙酰氧基-2-甲基萘 --> 1,2,3,4-四溴丁烷
用途三:丁二烯是生产合成橡胶（丁苯橡胶、顺丁橡胶、丁腈橡胶、氯丁橡胶）的主要原料。
毒性分级:中毒
下游产品:环丁砜 --> 1,6-已烷二胺 --> 聚苯乙烯丁二烯共聚物 --> 离子交换树脂 --> 4-乙烯基-1-环己烯二环氧化物,异构体混合物 --> 杂醇油 --> 正丁烯 --> N-羟甲基-3,4,5,6-四氢邻苯二甲酰亚胺 --> 2-(2-氯乙氧基)苯磺酰胺 --> 克菌丹 --> 1,4-二氰基丁烷 --> 甲萘醌 --> 四氢苯酐 --> 顺丁烯二酰肼 --> 交联剂 --> 六溴环十二烷 --> 仲丁醇 --> 十二烷二酸 --> 乙叉降冰生烯 --> N,N,N',N'-四甲基-2-丁烯-1,4-二胺 --> 甲基丙烯腈 --> 改性SBR涂饰剂 --> 环十二烷 --> 四氢化邻苯二甲酸酐 --> 酮麝香 --> 丁腈胶NBR --> 聚丁二烯 --> ABS 树脂 --> 1-烯丙基丙
职业标准:TWA 22
F:4.5-31