Lead tetraacetate 四乙酸铅

CAS 546-67-8 MFCD00008693

化学结构图

546-67-8
SMILES: CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Pb]

化学属性

Mol. FormulaC8H12O8Pb
Mol. Weight443.38
Density2.28
TSCAYes
Melting Point175°
Solubility分解
Stability易吸潮
Boiling Point118.1°C
pH:A

别名和识别编码

Chemical NameLead tetraacetate
Synonym acetic acid; lead(IV) salt leadtetracetate 铅糖、乙酸铅 四醋酸铅,乙酸高铅 lead tetracetate LEAD TETRAACETATE Plumbic acetate 乙酸铅(IV);乙酸高铅;四醋酸铅;醋酸高铅;乙酸高铅盐 lead (IV) acetate lead tetra-acetate Lead(IV) tetraacetate 乙酸高铅盐 PB(ACAC)4 lead tetra acetate 四乙酸鉛 Aceticacid,lead(4+)salt Leadacetateaceticacidwhitetolightbrownxtl Lead acetate [Pb(OAc)4] 乙酸铅(IV), 96%(DRY WT.), STAB. WITH 5-10% GLACIAL ACETIC 四乙酸铅 乙酸高铅盐,醋酸高铅 Blei(IV)acetat Lead tetraacetate 4 乙酸鉛(IV) Bleitetraacetat Pb(acac)4 四乙酸铅 乙酸铅(Ⅳ) LTA 四醋酸铅 四醋酸鉛 乙酸高铅 Tetrakis(acetyloxy)plumbane LEAD(+4)ACETATE 乙酸铅(IV) tetra-leadacetat Lead(IV) acetate LEAD(IV) TETRAACETATE Blei(IV)-acetat (angefeuchtet mit Essigsäure) Pb(acac) LEAD(IV) ACETATE GM LEAD(IV) ACETATE aceticacid,lead(4++)salt Leadtetraacetate Blei(IV)-acetat LEAD ACETATE leadacetate(pb(oac)4) leadacetate(pb(o2c2h3)4) plumbicacetate Lead(IV) acetate (5-10% acetic acid) Lead acetate (Pb(O2C2H3)4) 醋酸高铅 醋酸铅 Acetic acid, lead(4+) salt
Beilstein Registry Number3595640
PubChem Substance ID9846230
CAS Number546-67-8
MDL NumberMFCD00008693
EC Number208-908-0
Merck Number5423
Chemical Name Translation四乙酸铅
Reaxys-RN3595640
LabNetwork Molecule IDLN00841725
InChIInChI=1S/4C2H4O2.Pb/c4*1-2(3)4;/h4*1H3,(H,3,4);/p-4
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分类

  • Analytical Reagents, Analytical/Chromatography, Derivatization Reagents, Derivatization Reagents TLC, Glycosides, Phenols, TLC Reagents, G-M, TLC Visualization Reagents (alphabetic sort), TLC Visualization Reagents (by application)
  • {uni_hamburg} no charge; carboxylate; 5fragments; ionic
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Inorganic Salts, Solutions and Reagents, Lead, Reagent Grade, Research Essentials
  • {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Lead, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors

产品应用

  • 有机合成中的选择性氧化剂。

相关文献及参考

  • N-Formylanilines are oxidized to isocyanates. In the presence of methanol, the reaction affords the methyl urethanes directly: Synthesis, 225 (1982).
  • Carboxylic acids undergo oxidative decarboxylation; review: Org. React., 19, 279 (1972). In the presence of LiCl, the alkyl chloride is obtained (Kochi reaction): J. Am. Chem. Soc., 87, 2500 (1965); Synth. Commun., 20, 1011 (1990). Yields are lower for the bromide and iodide, cf Hunsdiecker reaction (see Mercury(II)­ oxide, A16157). Use of NCS allows successful scale-up: Synthesis, 493 (1973).
  • Merck:14,5423 Beilstein: 2,IV,118
  • Intramo
  • Short: EINECS
  • Short: III/10a
  • Versatile oxidizing agent and source of acetoxy radicals. For a review of one-step acetoxylation at carbon, see: Synthesis, 567 (1973). See also: M. Hudlicky, Oxidations in Organic Chemistry, ACS Monograph 186, Washington DC (1990). Oxidizes silyl enol ethers to ɑ-acetoxycarbonyl compounds in high yields: Tetrahedron, 39, 861 (1983). In combination with a metal halide, enol ethers are similarly converted to ɑ-halocarbonyl compounds: Synthesis, 1021 (1982).
  • Merck:14,5423
  • Cleaves vic-glycols to carbonyl compounds; see, e.g.: Org. Synth. Coll., 4, 124 (1963).

安全信息

Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P301+P312+P330
  • P302+P350
  • P308+P313
  • P302+P352+P332+P313+P362+P364
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P221 Take any precaution to avoid mixing with combustibles/… 采取一切防范措施,避免与可燃物混合/...
  • P304+P340+P312
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P273 Avoid release to the environment. 避免释放到环境中。
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Symbol
Signal word Danger
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H302 Harmful if swallowed 吞食有害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H272 May intensify fire; oxidizer 可能加剧火势;氧化剂。
Hazard Codes T,N T,N,O O,T,N T;N
WGK Germany3
RTECSAI5300000
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S17 Keep away from combustible material 远离可燃物料;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Packing GroupIII
UN Number UN1616 UN 2923 8/PG 2 2923 3087
Risk Statements
  • R33 Danger of cumulative effects 有累积作用的危险
  • R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R48/22
  • R50/53
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
  • R35 Causes severe burns 会导致严重灼伤
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
Storage condition Moisture Sensitive 0-10°C 0-6°C 易吸潮,密封保存。 储存温度2-8℃ 密封保存,储存温度2-8℃ 储存温度2-8℃,充氩储存
Hazard Class5.1/6.1

其他信息

  • 灭火剂:水, 二氧化碳, 干粉, 砂土
  • TCI Shanghai:四乙酸铅(含乙酸) Lead Tetraacetate (contains Acetic Acid),>;80.0%(T)(546-67-8)
  • 四乙酸铅价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30108916 四乙酸铅 100g 214元 2011/04/16 L0021 四乙酸铅(含乙酸) Lead Tetraacetate (contains Acetic Acid) 500G 2010元 2011/04/16 L0021 四乙酸铅(含乙酸) Lead Tetraacetate (contains Acetic Acid) 25G 256元
  • 常规方法:用塑料袋外加木箱包装,每袋25kg。按有毒化学品规定贮运。
  • 上游原料:铅粉(灰色)
  • F:10-21
  • Sigma Aldrich:546-67-8(sigmaaldrich)
  • 用途一:用作颜料、稳定剂及催化剂
  • 防护措施:毒性较高。主要对循环系统有损害。其气体经由上呼吸道进入呼吸系统,会引起口干,咽喉发热,胃部疼痛,有时流涎、恶心、胸痛、便秘,甚至排出黑褐色的血便,脉膊不规则,头脑发呆等症状。 呈现醋酸铅中毒者,应停止从事铅的作业,进行治疗。 生产设备应严格密封,定期检查。生产人员要戴好防护用品,定期检查身体。
  • 在空气中不稳定,有腐蚀性。遇水分解,形成PbO2和醋酸,溶于热冰乙酸、苯、氯仿、四氯化碳、甲苯、乙腈、硝基苯和二氯甲烷。有毒。无水醋酸液封。
  • 类别:有毒物质
  • 在空气中不稳定,有腐蚀性。遇水分解,形成PbO2和醋酸,溶于热冰乙酸、苯、氯仿、四氯化碳、甲苯、乙腈、硝基苯和二氯甲烷。有毒。密封保存。
  • TSCA:Yes
  • 外观性质:白色单斜结晶,在空气中不稳定,有腐蚀性。遇水分解,形成PbO2和醋酸,溶于热冰乙酸、苯、氯仿、四氯化碳、甲苯、乙腈、硝基苯和二氯甲烷。有毒。密封保存。熔点:175℃密度:2.28
  • MOL 文件:546-67-8.mol
  • 储运特性:库房低温, 通风, 干燥
  • 用途二:有机合成中的选择性氧化剂。
  • Alfa Aesar:乙酸铅(IV),96%(drywt.),stab.with5-10%glacialaceticacid Lead(IV) acetate, 96% (dry wt.), stab. with 5-10% glacial acetic acid(546-67-8)
  • 下游产品:3-氨基吡啶 --> 拉米夫定 --> 硬脂酸铅 --> 异辛酸铅 --> 二盐基硬脂酸铅
  • 图谱信息:四乙酸铅(546-67-8)红外图谱(IR1) 四乙酸铅(546-67-8)红外图谱(IR2) 四乙酸铅(546-67-8)质谱(MS) 四乙酸铅(546-67-8)核磁图( 13 CNMR)
  • 可燃性危险特性:可燃, 火场排出含铅辛辣刺激烟雾
  • Acros Organics:醋酸铅 Lead(IV) acetate, stabilized, 95%(546-67-8)
  • 敏感性:Moisture Sensitive
  • 在空气中不稳定,有腐蚀性。遇水分解,形成PbO2和醋酸,溶于热冰乙酸、苯、氯仿、四氯化碳、甲苯、乙腈、硝基苯和二氯甲烷。有毒。无水醋酸液封.

系列性分类