Trimethylacetic anhydride 三甲基乙酸酐
CAS 1538-75-6 MFCD00008842
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                 专业采购外包团队在线服务   
                  
                
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            分类
- Pharmaceuticals
 - {uni_hamburg} no charge; carbo-anhydride; 1fragment
 - Intermediates & Fine Chemicals
 - {SNA} Building Blocks, Carbonyl Compounds, Carboxylic Acid Anhydrides, Chemical Synthesis, Organic Building Blocks
 - Aliphatics
 - Metabolites & Impurities
 
产品应用
- A metabolite of a double prodrug (6-dGCV-DPiv
 
相关文献及参考
- Krasny, H.C.
 - Short: EINECS
 - Alcohols can be protected as their pivaloyl (Pv) esters by reaction with the anhydride in the presence of MgBr2 - Et3N or Sc(OTf)3 in acetonitrile: J. Org. Chem., 61, 5702 (1996). See also Trimethylacetyl chloride, A15051.
 - The direct hydrogenation of carboxylic acids to aldehydes has been achieved in the presence of pivalic anhydride and Tetrakis(triphenylphosphine)palladium(0), 10548: Chem. Lett., 1143 (1998).
 - Short: III/38B
 
安全信息
 GHS Symbol
 
        
            
            
 - S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
 - S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
 - S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
 
- R34 Causes burns 会导致灼伤
 
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
 - P233 Keep container tightly closed. ?保持容器密闭。
 - P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
 - P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
 - P242 Use only non-sparking tools. 只能使用无火花工具。
 - P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
 - P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
 - P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
 - P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
 - P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
 - P301+P330+P331
 - P301+P330+P331+P310
 - P303+P361+P353
 - P304+P340
 - P305+P351+P338
 - P305+P351+P338+P310
 - P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
 - P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
 - P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
 - P370+P378
 - P403+P235
 - P405 Store locked up. 上锁保管。
 - P501 Dispose of contents/container to..… 处理内容物/容器.....
 
- H226 Flammable liquid and vapour 易燃液体和蒸气
 - H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
 
其他信息
- MOL 文件:1538-75-6.mol
 - TCI Shanghai:2,2-二甲基丙酸酐 Pivalic Anhydride,>;98.0%(GC)(1538-75-6)
 - 三甲基乙酸酐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1414 特戊酸酐 Pivalic Anhydride 25ML 486元 2014/06/02 P1414 特戊酸酐 Pivalic Anhydride 250ML 2550元 2010/06/21 162440500 三甲基乙酸酐 Trimethylacetic anhydride 99% 50 ML 1072元
 - Sigma Aldrich:1538-75-6(sigmaaldrich)
 - 图谱信息:三甲基乙酸酐(1538-75-6)质谱(MS) 三甲基乙酸酐(1538-75-6)红外图谱(IR1) 三甲基乙酸酐(1538-75-6)核磁图( 1 HNMR) 三甲基乙酸酐(1538-75-6)Raman光谱 三甲基乙酸酐(1538-75-6)核磁图( 13 CNMR)
 - Acros Organics:三甲基乙酸酐 Trimethylacetic anhydride, 99%(1538-75-6)
 - F:9-13-21
 - 敏感性:Moisture Sensitive
 - Alfa Aesar:三甲基乙酸酐,99% Trimethylacetic anhydride, 99%(1538-75-6)
 
