CAS 90-93-7 MFCD00009044-4,4'-Bis(diethylamino)benzophenone 4,4’-双(二乙胺基)二苯甲酮 TAO{mole}

4,4'-Bis(diethylamino)benzophenone 4,4’-双(二乙胺基)二苯甲酮

CAS 90-93-7 MFCD00009044

化学结构图

SMILES: CCN(CC)c1ccc(C(=O)c2ccc(N(CC)CC)cc2)cc1

化学属性

Mol. Formula	C21H28N2O
Mol. Weight	324.46
Melting Point	89-92 °C
Density	1.048
Flash Point	151°(303°F)
TSCA	Yes
Solubility	不溶
Stability	对光敏感
Appearance	浅黄色均匀粉末，熔点 95°C，闪点151°C，不溶于水。
Boiling Point	475.7±30.0 °C at 760 mmHg

别名和识别编码

Chemical Name	4,4′-Bis(diethylamino)benzophenone
CAS Number	90-93-7
PubChem Substance ID	66663
EC Number	202-025-4
Beilstein Registry Number	14,98
MDL Number	MFCD00009044
Reaxys-RN	2148611
Synonym	4,4'-Bis(diethylamino)benzophenone {LY} 4,4'-Bis(diethylamino)benzophenone {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {}
Chemical Name Translation	4,4’-双(二乙胺基)二苯甲酮
InChIKey	VYHBFRJRBHMIQZ-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00202261
InChI	InChI=1S/C21H28N2O/c1-5-22(6-2)19-13-9-17(10-14-19)21(24)18-11-15-20(16-12-18)23(7-3)8-4/h9-16H,5-8H2,1-4H3
Canonical SMILES	O=C(C1=CC=C(C=C1)N(CC)CC)C2=CC=C(C=C2)N(CC)CC

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安全信息

GHS Symbol

WGK Germany2

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes 9

RTECSOS9545500

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+
P302+P352
P302+P352+P332+P313+P362+P364
P304+P340
P305+P351+P338
P305+P351+P338+P337+P313
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P313
P332+P317
P337+P313
P337+P317
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Warning

Safety Statements

S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R50/53
R51/53
R36 Irritating to eyes 刺激眼睛

UN Number UN3077 UN 3077 9/PG 3 3077

Storage condition 2-8°C {LY} 2-8°C Light Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

Packing GroupIII

Hazard Class9

其他信息

四乙基米氏酮作用:碱性染料的重要中间体，用于碱性艳蓝B、碱性艳蓝R等的生产。
MOL 文件:90-93-7.mol
制备碱性兰7:以四乙基米氏酮 [benzophenone, 4, 4'-bis (diethylamino)] 和 N-乙基-1-萘胺为原料，将两者在三氯氧磷存在下缩合，经稀释、水解、提纯、盐析即得成品。
Acros Organics:4,4'-双(二乙胺基)二苯甲酮 4,4'-Bis(diethylamino)benzophenone, 99+%(90-93-7)
用途三:光引发剂EMK 用作染料中间体,用于合成三芳甲烷类染料，如碱性艳蓝BO；也可作为光敏剂用于电影胶片工业；作为特种光学材料用于微电工业；还可用作橡胶交联剂。由N,N-二乙基苯胺与光气反应而得，也可采用氧化法合成。
F:8
图谱信息:四乙基米氏酮(90-93-7)红外图谱(IR1) 四乙基米氏酮(90-93-7)质谱(MS) 四乙基米氏酮(90-93-7)核磁图( 1 HNMR) 四乙基米氏酮(90-93-7)核磁图( 13 CNMR) 四乙基米氏酮(90-93-7)红外图谱(IR2)
不溶于水。
下游产品:碱性蓝 7
四甲基米氏酮合成方法:由N,N-二甲基苯胺与光气缩合而得。
MSDS 信息:4,4'-Bis(diethylamino) benzophenone(90-93-7).msds
Sigma Aldrich:90-93-7(sigmaaldrich)
Hazard Note:Irritant
用途二:UV固化型涂料和油墨
TCI Shanghai:4,4'-双二乙氨基二苯甲酮 4,4'-Bis(diethylamino)benzophenone,>;98.0%(T)(90-93-7)
上游原料:光气(无法供)
敏感性:Light Sensitive
用途一:用作染料中间体
四乙基米氏酮价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 B1275 4,4'-双(二乙氨基)苯甲酮 4,4'-Bis(diethylamino)benzophenone 500G 1640元 2014/06/02 B1275 4,4'-双(二乙氨基)苯甲酮 4,4'-Bis(diethylamino)benzophenone 25G 190元 2014/06/02 B0139 4,4'-双(二乙氨基)二苯甲酮 4,4'-Bis(diethylamino)benzophenone 25G 242元
Alfa Aesar:4,4'-二(二乙氨基)苯甲酮,99% 4,4'-Bis(diethylamino)benzophenone, 99%(90-93-7)