Ethyl diphenylphosphinite 二苯基乙氧基膦

CAS 719-80-2 MFCD00009087

化学结构图

719-80-2
SMILES: CCOP(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC14H15OP
Mol. Weight230.24
Density1.066
Refractive index1.5880 to 1.5920
Flash Point176.4±23.4°C
TSCANo
Boiling Point316.1±25.0°C at 760 mmHg
Melting Point164-167 °C

别名和识别编码

Chemical NameEthyl Diphenylphosphinite
CAS Number719-80-2
EC Number211-951-8
Beilstein Registry Number16(4)969
MDL NumberMFCD00009087
Synonym Ethoxydiphenylphosphine {LY} Ethoxydiphenylphosphine {} {LY} Ethoxydiphenylphosphine {} {} {LY} Ethoxydiphenylphosphine {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethoxydiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethoxydiphe
PubChem Substance ID69754
Reaxys-RN1641750
Chemical Name Translation二苯基乙氧基膦
InChIKeyJCRCPEDXAHDCAJ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00190184
InChIInChI=1S/C14H15OP/c1-2-15-16(13-9-5-3-6-10-13)14-11-7-4-8-12-14/h3-12H,2H2,1H3
Canonical SMILESCCOP(C1=CC=CC=C1)C2=CC=CC=C2
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors

相关文献及参考

  • An iminophosphorane, formed with an azido ester (Staudinger), reacts with a carboxyl group to form an amide, providing the basis of a novel peptide coupling method. The reaction occurs at lower temperatures with this reagent rather than tributyl- or triphenylphosphine: J. Org. Chem., 50, 2601 (1985). See Appendix 6.
  • Arbuzov reaction with alkyl halides gives diphenyl phosphine oxides, useful as Wittig-Horner intermediates. See, for example: Synthesis, 126 (1977); Tetrahedron Lett., 2433 (1979); Appendix 1.
  • Beilstein:16(4)969

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Air & Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, prote
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Packing GroupIII

其他信息

  • MOL 文件:719-80-2.mol
  • 二苯基乙氧基膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D2558 乙氧基二苯基膦 Ethoxydiphenylphosphine 5G 660元 2014/06/02 D2558 乙氧基二苯基膦 Ethoxydiphenylphosphine 25G 2160元 2010/06/21 165280050 二苯基乙氧基膦 Ethyl diphenylphosphinite 99% 5 GR 671元
  • 溶于乙醇。
  • Sigma Aldrich:719-80-2(sigmaaldrich)
  • TCI Shanghai:二苯基乙氧基膦 Ethoxydiphenylphosphine,>;93.0%(T)(719-80-2)
  • Alfa Aesar:二苯基乙氧基磷,98% Ethyl diphenylphosphinite, 98%(719-80-2)
  • MSDS 信息:Ethyl diphenylphosphinite(719-80-2).msds
  • Acros Organics:乙氧基二苯基磷 Ethyl diphenylphosphinite, 99%(719-80-2)
  • 敏感性:Air & Moisture Sensitive

系列性分类


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