Triethyl methanetricarboxylate, 98% 甲烷三羧酸三乙酯
CAS 6279-86-3 MFCD00009150
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分类
- {SNA} Building Blocks, C10 to C11, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
相关文献及参考
- Methanetricarboxylates have been used as "blocked" malonic esters, restricting reaction with alkyl halides to monoalkylation. The unwanted carboxyl group can be removed by treatment with Na alkoxide, LDA or BCl3: J. Org. Chem., 44, 3492 (1979). Adds to Michael acceptors under phase-transfer conditions, providing a useful 2-carbon chain extension method: Synthesis, 1125 (1990):
- The tricarboxylate also undergoes free-radical addition to the terminal position of alkenes: Angew. Chem. Int. Ed., 5, 586 (1966). Arylation with electron-rich aromatics is promoted by Mn(III): Synthesis, 567 (1991).
- Under similar conditions, diethyl malonate gives only 36% yield.
安全信息
GHS Symbol
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- MOL 文件:6279-86-3.mol
- Acros Organics:Triethyl methanetricarboxylate, 98%(6279-86-3)
- Alfa Aesar:甲烷三羧酸三乙酯,98% Triethyl methanetricarboxylate, 98%(6279-86-3)
- 甲烷三羧酸三乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1481 甲烷三甲酸三乙酯 Triethyl Methanetricarboxylate 5G 325元 2014/06/02 T1481 甲烷三甲酸三乙酯 Triethyl Methanetricarboxylate 25G 993元 2010/06/21 139630250 甲烷三羧酸三乙酯 Triethyl methanetricarboxylate 98% 25 ML 1080元
- MSDS 信息:Triethyl methanetricarboxylate (6279-86-3).msds
- Sigma Aldrich:6279-86-3(sigmaaldrich)
- TCI Shanghai:甲烷三甲酸三乙酯 Triethyl Methanetricarboxylate,>;95.0%(GC)(6279-86-3)
- 海关编码:29171990