Trimethyl(prop-1-yn-1-yl)silane 1-(三甲基硅基)丙炔
CAS 6224-91-5 MFCD00009271
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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现货库存
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分类
- Alkynes, Building Blocks, Chemical Synthesis, Internal, Organic Building Blocks
- {uni_hamburg} no charge; 1fragment
- {SNA} Alkynes, Building Blocks, Chemical Synthesis, Internal, Organic Building Blocks
产品应用
- 经由钯催化的碳环合成高取代的茚类; 铑催化的和二溴苯硼酸的反应合成二氢茚酮(indenones);在Cp2Zr(H)CI存在下把醛转化成1,3-二烯烃等等。
相关文献及参考
- Zlotos, D., et al.: J. Med. Chem., 47, 3561 (2004),
- Falck, J., et al.: Bioorg. Med. Chem. Lett., 14, 4987 (2004),
- J. Am. Chem. Soc. 129 , 5766, (2007) 摘要
- Beil. 4 ,IV,3938
- Beilstein: 4,IV,3938
- Short: III/35F
- Alkylation of the lithio-derivative proceeds with only a small amount of allylic rearrangement to the allene, and is thus a useful route to substituted terminal alkynes: Tetrahedron Lett., 5041 (1968):
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H319 Causes serious eye irritation 严重刺激眼睛
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P241+P242+P243
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P303+P361+P353
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P370+P378
- P403+P235
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S29 Do not empty into drains 不要排入下水道;
- S33 Take precautionary measures against static discharges 对静电采取预防措施;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
- R11 Highly flammable 非常易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- Sigma Aldrich:6224-91-5(sigmaaldrich)
- TCI Shanghai:1-(三甲基硅基)-1-丙炔 1-(Trimethylsilyl)-1-propyne,>;98.0%(GC)(6224-91-5)
- MOL 文件:6224-91-5.mol
- 蒸气密度:>;1 (vs air)
- 1-(三甲基硅基)丙炔价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1123 1-(三甲基硅基)-1-丙炔 1-(Trimethylsilyl)-1-propyne 5ML 652元 2014/06/02 T1123 1-(三甲基硅基)-1-丙炔 1-(Trimethylsilyl)-1-propyne 25ML 1930元 2010/06/21 223530010 1-(三甲基硅基)丙炔 1-(Trimethylsilyl)-1-propyne 98% 1 GR 423元
- Acros Organics:1-(Trimethylsilyl)-1-propyne, 98%(6224-91-5)
- 用途一:经由钯催化的碳环合成高取代的茚类; 铑催化的和二溴苯硼酸的反应合成二氢茚酮(indenones);在Cp2Zr(H)CI存在下把醛转化成1,3-二烯烃等等。
- Alfa Aesar:1-三甲基甲硅烷基-1-丙炔,98% 1-Trimethylsilyl-1-propyne, 98%(6224-91-5)
- TSCA:Yes