1,4-己二烯(顺反异构体混合物) 1,4-己二烯 (顺反异构体混合物)
CAS 592-45-0 MFCD00009298
化学结构图
SMILES: C=CCC=CC
化学属性
| Mol. Formula | CH3CH=CHCH2CH=CH2 |
|---|---|
| Mol. Weight | 82 |
| Density | 0.71 g/mL at 25 °C(lit.) |
| Refractive index | n20/D 1.411(lit.) |
| Flash Point | -21°C(lit.) |
| TSCA | Yes |
| Boiling Point | 64-66 °C(lit.) |
| Solubility | 不溶于水。 |
别名和识别编码
| Chemical Name | 1,4-己二烯(顺反异构体混合物) |
|---|---|
| Synonym | {uni_hamburg} cis,trans-hexa-1,4-diene 1,4-HEXADIENE 1，4-己二烯 1,4-已二烯 1,4-Hexadiene cis-trans 1-烯丙基丙烯 1,4-Hexadiene, cis + trans 1,4-Hexadiene,c&t; 1,4-Hexadien, cis/trans Gemisch 1,4-Hexadien Isomerengemisch cis/trans 1,4-hexadiene cis,trans-hexa-1,4-diene 1-甲基-4-戊二烯 1,4-Hexadien, cis/trans TRANS-1,4-HEXADIENE Hexadienecistrans 1,4-己二烯,CIS +TRANS allylpropenyl hexa-1,4t-diene 1,4-Hexadiene (cis- and trans- mixture) hexa-1,4-diene 1,4-Hexadiene, mixture of cis and trans 1,4-HEXADIENE, 99%, MIXTURE OF CIS AND T RANS 1,4-hexadiene,mixtureofcisandtrans 1-Allylpropene 1-Methylpenta-1,4-diene 1,4-己二烯（顺反异构体混合物） |
| MDL Number | MFCD00009298 |
| CAS Number | 592-45-0 |
| EC Number | 209-756-8 |
| Beilstein Registry Number | 1,253 |
| PubChem Substance ID | 5365552 |
| Chemical Name Translation | 1,4-己二烯 (顺反异构体混合物) |
| Reaxys-RN | 1839520 |
| InChI | InChI=1S/C6H10/c1-3-5-6-4-2/h3-4,6H,1,5H2,2H3/b6-4+ |
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信息真实价格透明
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现货库存
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分类
- {SNA} Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Organic Building Blocks
- {uni_hamburg} no charge; 1fragment
相关文献及参考
- Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
- Short: IV/8C Title: Densities of Aliphatic Hydrocarbons: Alkenes, Alkadienes, Alkynes, and Miscellaneous Compounds Author: Wilhoit, R.C.; Marsh, K.N.; Hong, X.; Gadalla, N.; Frenkel, M. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8C Year: 1996 Keyword: organic compounds; density; liquids ISBN: 3-540-61554-7 ISBN: 978-3-540-61554-5 Internet Resource: DOI:10.1007/b59735 RefComment: 78 figs., X, 381 pages, Hardcover
- Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
安全信息
- R11 Highly flammable 非常易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S33 Take precautionary measures against static discharges 对静电采取预防措施；
- S37 Wear suitable gloves 戴适当手套；
- S29 Do not empty into drains 不要排入下水道；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H319 Causes serious eye irritation 严重刺激眼睛
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P332+P313
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P337+P313
- P302+P352+P332+P313+P362+P364
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P303+P361+P353
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P370+P378
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P301+P310+P331
- P305+P351+P338+P337+P313
- P241+P242+P243
- P405 Store locked up. 上锁保管。
- P233 Keep container tightly closed. ?保持容器密闭。
- P403+P235
其他信息
- 1-烯丙基丙烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0333 1,4-己二烯 (顺反异构体混和物) 1,4-Hexadiene (cis- and trans- mixture) 5ML 701元 2014/06/02 H0333 1,4-己二烯 (顺反异构体混和物) 1,4-Hexadiene (cis- and trans- mixture) 25ML 2090元 2010/06/21 156550050 1-烯丙基丙烯 1,4-Hexadiene 99%, mixture of cis and trans 5 GR 956元
- 方法一:由乙烯和丁二烯经催化反应而得。乙烯和丁二烯在溶剂甲苯中反应，催化剂为氯化钴、氯化磷、三乙基铝，反应浊度为80-104℃，压力为3.92MPa。产品中除1,4-已二烯外，还含少量变，4-已二烯和碳八双烯类。
- 上游原料:1,3-丁二烯 --> 氯化钴 --> 醋酸妊娠双烯醇酮酯 --> 三乙基铝
- TCI Shanghai:1,4-己二烯 (顺反异构体混合物) 1,4-Hexadiene (cis- and trans- mixture),>;99.0%(GC)(592-45-0)
- Alfa Aesar:1,4-己二烯,cis+trans,99% 1,4-Hexadiene, cis + trans, 99%(592-45-0)
- 外观性质:无色液体。
- MOL 文件:592-45-0.mol
- Sigma Aldrich:592-45-0(sigmaaldrich)
- Acros Organics:1,4-己二烯 1,4-Hexadiene, mixture of cis and trans, 99%(592-45-0)
- MSDS 信息:1,4-己二烯(592-45-0).msds
- 用途一:用作乙丙胶的第三单体。
