Tri-n-butylphosphite, min. 94% 三(正丁氧基)膦

CAS 102-85-2 MFCD00009437

化学结构图

102-85-2
SMILES: CCCCOP(OCCCC)OCCCC

化学属性

Mol. FormulaC12H27O3P
Mol. Weight250.31
Refractive index1.4310 to 1.4330
Boiling Point125 °C at 760 mmHg
Density0.925 g/mL at 25 °C(lit.)
Flash Point91.67°C
TSCAYes
Melting Point-80 °C
Solubility不溶于水,溶于多数有机溶剂。

别名和识别编码

Chemical NameTri-n-butylphosphite, min. 94%
CAS Number102-85-2
PubChem Substance ID7623
EC Number203-061-3
Beilstein Registry Number1(1)187
MDL NumberMFCD00009437
Synonym Tributyl phosphite {LY} Tributyl phosphite {} {LY} Tributyl phosphite {} {} {LY} Tributyl phosphite {} {} {} {LY} Tributyl phosphite {} {} {} {} {LY} Tributyl phosphite {} {} {} {} {} {LY} Tributyl phosphite {} {} {} {} {} {} {LY} Tributyl phosphite {} {} {} {} {} {} {} {LY} Tributyl phosphite {} {} {} {} {} {} {} {} {LY} Tributyl phosphite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tributyl phosphite {} {} {} {} {} {} {} {} {} {} {LY} Tributyl phosphite {} {} {} {} {} {} {} {} {} {} {} {LY} Tributyl phosphite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tributyl phosphite {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tributyl phosphite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tributyl phosphite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tributyl phosphite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tributyl phosphite
Reaxys-RN1703866
Chemical Name Translation三(正丁氧基)膦
Wiswesser Line Notation4OPO4&O4
LabNetwork Molecule IDLN00223835
InChIInChI=1S/C12H27O3P/c1-4-7-10-13-16(14-11-8-5-2)15-12-9-6-3/h4-12H2,1-3H3
Canonical SMILESCCCCOP(OCCCC)OCCCC
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分类

  • Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds

相关文献及参考

  • Beilstein:1(1)187
  • Short: IV/10A
  • Short: III/38A

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H312 Harmful in contact with skin 皮肤接触有害
  • H303 May be harmfully swallowed 吞食可能有害
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C
RTECSTH0875000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P332+P313
  • P302+P352+P312+P362+P364
  • P305+P351+P338+P337+P313
  • P302+P350
Signal word Danger
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air & Moisture Sensitive {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
UN Number UN 3265 8/PG 3
TYPE OF TEST            : LC - Lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >220 ppm/6H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   34,286,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   34,286,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 26,269,1944

其他信息

  • Sigma Aldrich:102-85-2(sigmaaldrich)
  • Acros Organics:三(正丁氧基)膦即[CH3(CH2)3O]3P Tributyl phosphite, 94%(102-85-2)
  • MSDS 信息:亚磷酸三丁酯(102-85-2).msds
  • 外观性质:无色液体。
  • 图谱信息:三丁基,三丁酯(102-85-2)核磁图( 13 CNMR) 三丁基,三丁酯(102-85-2)质谱(MS) 三丁基,三丁酯(102-85-2)红外图谱(IR2) 三丁基,三丁酯(102-85-2)Raman光谱 三丁基,三丁酯(102-85-2)核磁图( 1 HNMR) 三丁基,三丁酯(102-85-2)红外图谱(IR1)
  • TCI Shanghai:亚磷酸三丁酯 Tributyl Phosphite,>;93.0%(GC)(102-85-2)
  • 微溶于水 (分解),溶于常规有机溶剂。
  • Alfa Aesar:亚磷酸三正丁酯,94% Tri-n-butyl phosphite, 94%(102-85-2)
  • 三丁基,三丁酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0362 亚磷酸三丁酯 Tributyl Phosphite 25ML 129元 2014/06/02 T0362 亚磷酸三丁酯 Tributyl Phosphite 500ML 506元 2010/06/21 169922500 三丁基,三丁酯 Tributyl phosphite 94% 250 GR 370元
  • MOL 文件:102-85-2.mol
  • 用途一:用作润滑油的增强剂、防腐剂、热稳定剂

系列性分类


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