CAS 6485-79-6 MFCD00009657-Triisopropylsilane 三异丙基硅烷 TAO{mole}

Triisopropylsilane 三异丙基硅烷

CAS 6485-79-6 MFCD00009657

化学结构图

SMILES: CC(C)[SiH](C(C)C)C(C)C

化学属性

Mol. Formula	C9H22Si
Mol. Weight	158.36
Density	0.773
Refractive index	1.4340 to 1.4370
Flash Point	37°C(lit.)
TSCA	No
Boiling Point	84-86 °C at 35 mmHg
Stability	对湿度敏感
Melting Point	99°F
Appearance	无色液体, B.P.84-85℃(35mmHg), F.P.35℃,d 0.773.nD201.4340 .本品易燃,有刺激性
Danger-Level	甲类

别名和识别编码

Chemical Name	Triisopropylsilane
MDL Number	MFCD00009657
Synonym	Triisopropylsilane {LY} Triisopropylsilane {} {LY} Triisopropylsilane {} {} {LY} Triisopropylsilane {} {} {} {LY} Triisopropylsilane {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triiso
CAS Number	6485-79-6
Beilstein Registry Number	1733718
EC Number	250-023-7
PubChem Substance ID	87577292
Chemical Name Translation	三异丙基硅烷
Reaxys-RN	1733718
InChIKey	YDJXDYKQMRNUSA-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00009319
InChI	InChI=1S/C9H21Si/c1-7(2)10(8(3)4)9(5)6/h7-9H,1-6H3
Canonical SMILES	CC([SiH](C(C)C)C(C)C)C

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产品应用

大体积异丙基（与乙基相比）能实现选择性更高的还原反?应（例如，异头 C-苯基缩酮的 β-选择性还原），但是不会降低它们的活性（例如，三甲基硅醚的三氟甲烷?磺酸酮催化型还原醚化）。
用于 Ni(O) N-杂环卡宾络合物催化的反式-1,2-二醇的高度非?对映选择性制备。

安全信息

UN Number 1993

Risk Statements

R10 Flammable 易燃
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；

Signal word Warning

GHS Symbol

WGK Germany3

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P241+P242+P243
P242 Use only non-sparking tools. 只能使用无火花工具。
P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352
P302+P352+P332+P313+P362+P364
P303+P361+P353
P304+P340
P305+P351+P338
P305+P351+P338+P337+P313
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P313
P333+P313
P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P370+P378
P403+
P403+P233
P403+P235
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H226 Flammable liquid and vapour 易燃液体和蒸气
H315 Causes skin irritation 会刺激皮肤
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Packing GroupIII

Hazard Codes 3

Storage condition 2-8°C {LY} 2-8°C Store at RT. {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C

Hazard Class3

其他信息

用途一:肽合成保护剂。
Acros Organics:三异丙基硅烷 Triisopropylsilane, 98%(6485-79-6)
Alfa Aesar:三异丙基硅烷,98% Triisopropylsilane, 98%(6485-79-6)
存储注意事项:湿度敏感
Triisopropylsilane is a highly selective reducing agent which can be used to prepare anti-1,2-diols.
Sigma Aldrich:6485-79-6(sigmaaldrich)
F:10-21
TSCA:No
检测方法:GC,NMR
三异丙基硅烷价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 xw010187 三异丙基硅烷 100ml 500元 2011/04/16 T1533 三异丙基硅烷 Triisopropylsilane 100ML 2140元 2011/04/16 T1533 三异丙基硅烷 Triisopropylsilane 25ML 713元
敏感性:Moisture Sensitive
图谱信息:三异丙基硅烷(6485-79-6)红外图谱(IR1) 三异丙基硅烷(6485-79-6)核磁图( 1 HNMR) 三异丙基硅烷(6485-79-6)质谱(MS) 三异丙基硅烷(6485-79-6)核磁图( 13 CNMR)
TCI Shanghai:三异丙基硅烷 Triisopropylsilane,>;98.0%(GC)(6485-79-6)
MOL 文件:6485-79-6.mol