Cyclopropyl(Phenyl)Sulfane 环丙基(苯基)硫烷

CAS 14633-54-6 MFCD00009684

化学结构图

14633-54-6
SMILES: c1ccc(SC2CC2)cc1

化学属性

Mol. FormulaC9H10S
Mol. Weight150.24
Density1.045
Refractive index1.5810 to 1.5830
Flash Point91°C(lit.)
TSCANo
Boiling Point90°C/4.7mmHg(lit.)

别名和识别编码

Chemical NameCyclopropyl(Phenyl)Sulfane
MDL NumberMFCD00009684
Synonym Phenylthiocyclopropane 环丙基苯硫醚 环丙基苯基硫醚 环丙基苯基硫
CAS Number14633-54-6
Beilstein Registry Number2075701
EC Number250-023-7
PubChem Substance ID87566055
Chemical Name Translation环丙基(苯基)硫烷
Reaxys-RN2075701
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfides/Disulfides, Sulfur Compounds

相关文献及参考

  • Readily undergoes lithiation with n-BuLi: J. Am. Chem. Soc., 99, 3080, 3088 (1977); Synthesis, 821, 3088 (1978). Subsequent reaction with a variety of electrophiles provides a route to substituted cyclopropanes and ring-opened products.

安全信息

Packing GroupIII
UN Number UN3334
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Signal word
GHS Symbol
WGK Germany3
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P302+P350
  • P337+P313
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P312+P362+P364
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi

系列性分类


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