(Trimethylsilyl)Methyl Trifluoromethanesulfonate (三甲基硅基)甲基三氟甲烷磺酸酯

CAS 64035-64-9 MFCD00009914

化学结构图

64035-64-9
SMILES: C[Si](C)(C)COS(=O)(=O)C(F)(F)F

化学属性

Mol. FormulaC5H11F3O3SSi
Mol. Weight236
Refractive index1.3760 to 1.3780
Boiling Point49-51
Density1.182
Flash Point48°C(lit.)

别名和识别编码

Chemical Name(Trimethylsilyl)Methyl Trifluoromethanesulfonate
Synonym (三甲基硅基)甲基三氟甲烷磺酸酯 Trifluoromethanesulfonic acid (trimethylsilyl)methyl ester, (Trimethylsilyl)methyl triflate 三甲基硅基甲基三氟甲磺酸酯
CAS Number64035-64-9
PubChem Substance ID87577336
Beilstein Registry Number2365813
MDL NumberMFCD00009914
Reaxys-RN2365813
Chemical Name Translation(三甲基硅基)甲基三氟甲烷磺酸酯
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Fluorinated Building Blocks, Organic Building Blocks, Organic Fluorinated Building Blocks, Organic Triflates, Sulfur Compounds

相关文献及参考

  • Fieser 10 ,434 / Fieser 13 ,329 / Fieser 14 ,332
  • FT-IR 2 (3), 4411:C / FT-NMR 1 (3), 697:C / RegBook 1 (2), 2993:A / Structure Index 1 , 474:C:2

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 C
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 2920
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R10 Flammable 易燃
  • R34 Causes burns 会导致灼伤
Packing GroupII
Hazard Class8/3

系列性分类


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