(+)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane (+)-4,5-双[羟基(二苯基)甲基]-2,2-二甲基-1,3-二氧戊环
CAS 93379-49-8 MFCD00010079
化学结构图
SMILES: CC1(C)O[C@@H]([C@H](O1)C(O)(C1C=CC=CC=1)C1C=CC=CC=1)C(O)(C1C=CC=CC=1)C1C=CC=CC=1 |&1:4,5|
化学属性
| Melting Point | 193-196 |
|---|---|
| Mol. Formula | C31H30O4 |
| Appearance | white to light yellow pwdr. |
| Mol. Weight | 467 |
别名和识别编码
| Chemical Name | (+)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane |
|---|---|
| Synonym | (+)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-D-threitol, (+)-trans-,-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) (+)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-D-threitol, (+)-trans-α,α′-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) (+)-2,3-O-异亚丙基-1,1,4,4-四苯基-D-苏糖醇 (+)-2,3-O-异亚丙基-1,1,4,4-四苯基-D-苏糖醇 (+)-反式-α,α′-(2,2-二甲基-1,3-二氧戊环-4,5-二基)双(二苯基甲醇) (4S,5S)-4,5-双(二苯基羟甲基)-2,2-二甲基二氧戊环 (+)-反式-α,α′-(2,2-二甲基-1,3-二氧戊环-4,5-二基)双(二苯基甲醇) (4S,5S)-4,5-双(二苯基羟甲基)-2,2-二甲基二氧戊环 |
| MDL Number | MFCD00010079 |
| PubChem Substance ID | 87564922 |
| Beilstein Registry Number | 4724097 |
| Reaxys-RN | 4724096 |
| Chemical Name Translation | (+)-4,5-双[羟基(二苯基)甲基]-2,2-二甲基-1,3-二氧戊环 |
| CAS Number | 93379-49-8 |
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分类
- {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, TADDOLs
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, TADDOLs
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, TADDOLs
相关文献及参考
- 1. Quinkert, G. et al. Tetrahedron Lett. 33 , 3617, (1992)
- 2. Hafner, A. et al. J. Am. Chem. Soc. 114 , 2321, (1992)
- 3. Bernardi, A. et al. Tetrahedron Lett. 36 , 1363, (1995)
- FT-NMR 1 (2), 377:A / RegBook 1 (1), 1337:F / Structure Index 1 , 206:C:3
- Fieser 17 ,322
安全信息
GHS Symbol
