(S)-(+)-2-(Methoxymethyl)Pyrrolidine (S)-(+)-2-(甲氧基甲基)吡咯烷

CAS 63126-47-6 MFCD00010408

化学结构图

63126-47-6
SMILES: COC[C@@H]1CCCN1

化学属性

Mol. FormulaC6H13NO
Mol. Weight115
Refractive index1.4450 to 1.4470
Density0.932
Flash Point45°C(lit.)
TSCANo
Boiling Point62
Stability对空气敏感
Danger-Level乙类

别名和识别编码

Chemical Name(S)-(+)-2-(Methoxymethyl)Pyrrolidine
Synonym O-Methyl-L-prolinol (S)-(+)-2-(甲氧基甲基)吡咯烷 O-甲基-L-脯氨醇 SMP
PubChem Substance ID87573123
Beilstein Registry Number3587324
MDL NumberMFCD00010408
CAS Number63126-47-6
Reaxys-RN3587324
EC Number250-023-7
Chemical Name Translation(S)-(+)-2-(甲氧基甲基)吡咯烷
InChIKeyCHPRFKYDQRKRRK-UHFFFAOYSA-N
LabNetwork Molecule IDLN00001447
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Proline-Based Organocatalysts

产品应用

  • 手性助剂,用于不对称合成炔丙醇 和 4-硝基环己酮, 以及用于不对称 Michael 加成反应生成烯酮。

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Packing GroupIII
UN Number 1993
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
Storage condition Air Sensitive
Hazard Codes 3
Hazard Class3

系列性分类