Copper(I) chloride 氯化亚铜
CAS 7758-89-6 MFCD00010971
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资金保障
专业采购外包团队在线服务
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分类
- {SA} 29: Cu, Beaded Materials, Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper, Copper Salts, Crystal Grade Inorganics, Materials Science, Metal and Ceramic Science, Salts
- {SNA} ATRP, ATRP Metal Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper, Copper Salts, Crystal Grade Inorganics, Materials Science, Metal and Ceramic Science, Polymer Science, Reagents for Controlled Radical Polymerization, Reagents for Polymerization, Salts
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper
- {Chemicalboo
产品应用
- 气体分析中吸收一氧化碳,有机反应催化剂,石油脱臭、脱硫剂。防腐,脱色。
相关文献及参考
- A 1:1 mixture with 2,2'-bipyridine catalyzes the cyclization of allyl trichloroacetamides
- Merck: 14,2660
- Used in combination with Tris(3,6-dioxaheptyl)amine, L13544, in the Ullmann aryl ether synthesis: J. Org. Chem., 50, 3717 (1985), and an improved N-arylation of amides: Synthesis, 312 (1989).
- to -lactams: J. Org. Chem ., 58, 464 (1993).
- Short: II/24A
- For use in the oxidative cleavage of phenols, see Catechol, A10164.
- For use in the Simmons-Smith cyclopropanation reaction, see Dibromomethane, A10456.
- Catalyst for the Sandmeyer preparation of aryl chlorides; for use in the related conversion of aryldiazonium salts to sulfonyl chlorides with SO 2, see: Org. Synth. Coll., 7, 508 (1990).
- A 1:1 mixture with 2,2'-bipyridine catalyzes the cyclization of allyl trichloroacetamides to -lactams: J. Org. Chem ., 58, 464 (1993).
- In combination with TMEDA, promotes the Hay (improved Glaser) coupling of terminal acetylenes: Org. Synth. Coll., 8, 63 (1993).
- Catalyst for the Sandmeyer preparation of aryl chlorides; for use in the related conversion of aryldiazonium salts to sulfonyl chlorides with SO2, see: Org. Synth. Coll., 7, 508 (1990).
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H302 Harmful if swallowed 吞食有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H315 Causes skin irritation 会刺激皮肤
- H318 Causes serious eye damage 严重伤害眼睛
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S22 Do not breathe dust 不要吸入粉尘;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- R22 Harmful if swallowed 吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R38 Irritating to skin 刺激皮肤
- R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
- R50/53
- R51/53
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 347 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 35(2),42,1
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 140 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : EQSSDX Environmental Quality and Safety, Supplement. (Stuttgart, Fed. Rep. Ger.) V.1-5, 1975-76. Discontinued. Volume(issue)/page/year: 1,1,1975
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - guinea pig DOSE/DURATION : 100 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : EQSSDX Environmental Quality and Safety, Supplement. (Stuttgart, Fed. Rep. Ger.) V.1-5, 1975-76. Discontinued. Volume(issue)/page/year: 1,1,1975
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1008 mg/m3 TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 35(2),42,1991
TYPE OF TEST : Cytogenetic analysis TEST SYSTEM : Rodent - rat Ascites tumor DOSE/DURATION : 120 mg/kg REFERENCE : GANNA2 Gann. Japanese Journal of Cancer Research. (Tokyo, Japan) V.1-75, 1907-84. For publisher information, see JJCREP. Volume(issue)/page/year: 54,155,1963
其他信息
- MOL 文件:7758-89-6.mol
- 职业标准:TWA 0.1 毫克(铜)
- 氯化亚铜价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 10007718 氯化亚铜;氯化低铜 500g 63元 2011/08/23 10007728 氯化亚铜;氯化低铜 500g 61元 2010/06/21 270525000 氯化亚铜 Copper(I) chloride 97+%, extra pure 500 GR 471元
- 图谱信息:氯化亚铜(7758-89-6)红外图谱(IR1)
- 敏感性:Air & Mois
- 防护措施:对皮肤有强刺激性,粉尘使皮肤发痒起泡,刺激眼睛流泪。 生产操作人员要穿工作服、戴口罩、手套等防护用具。生产设备要密闭,车间通风良好,下班后洗淋浴,注意保护皮肤、呼吸器官。
- 毒性分级:高毒
- 急性毒性:口服-大鼠 LD50: 140 毫克/公斤; 口服-小鼠 LD50: 347 毫克/公斤
- 水中溶解度(g/100ml):每100毫升水中的溶解克数: 9.9×10-3/20℃
- Alfa Aesar:氯化亚铜(I),ACS,90+% Copper(I) chloride, ACS, 90+%(7758-89-6)
- 常规方法:用内衬2只塑料袋封口的铁桶包装,每桶净重35kg或50kg。包装上应有明显的“有毒品”标志。 属无机有毒品。应贮存在阴凉、通风、干燥、避光的库房内。容器必须密封,防止受潮。不得与食用物品和氧化剂共贮混运。运输过程中要防雨淋和日晒。装卸时要轻拿轻放,防止包装破损而潮解。保存期三个月。 失火时,可用水、砂土和各种灭火器扑救。
- 下游产品:直接蓝 86 --> N,N,N',N'-四甲基对苯二胺二盐酸盐 --> 己酸烯丙酯 --> 2-溴氯苯 --> 2-对氯苄基吡啶 --> 丙烯酰氯 --> 3,5-二氯-1H-吲唑 --> 3-氯-2-甲基苯甲腈 --> 1,4-二氯萘 --> 5-氯-2-氟苯甲酸 --> 二(三甲基甲硅烷基)乙炔 --> 7-氯喹啉 --> 3-苯氧基甲苯 --> 活性艳蓝KN-R --> 氯安定 --> 3-氯甲苯 --> 2,6-二硝基氯苯 --> 还原棕 1 --> 2-氯-3-甲基-5-溴吡啶 --> 2,4,5-三氟苯乙酸 --> 3-硝基-4-氯甲苯 --> 酸性兰 129 --> 3-氯噻吩-2-甲酰胺 --> 2,4,6-三甲氧基苯甲醛 --> 甲基二氯硅烷 --> 5-ó4-氟-3-(三氟甲烷)-2-糠醛 --> 2-氯-5-碘吡啶 --> 5-(4-溴苯基)-2-呋喃甲醛 --> 氯甲基硅烷 --> 5-ó2-氯-4-(三氟甲烷)苯基-2-
- Sigma Aldrich:7758-89-6(sigmaaldrich)
- 下游产品:直接蓝 86 --> N,N,N',N'-四甲基对苯二胺二盐酸盐 --> 己酸烯丙酯 --> 2-溴氯苯 --> 2-对氯苄基吡啶 --> 丙烯酰氯 --> 3,5-二氯-1H-吲唑 --> 3-氯-2-甲基苯甲腈 --> 1,4-二氯萘 --> 5-氯-2-氟苯甲酸 --> 二(三甲基甲硅烷基)乙炔 --> 7-氯喹啉 --> 3-苯氧基甲苯 --> 活性艳蓝KN-R --> 氯安定 --> 3-氯甲苯 --> 2,6-二硝基氯苯 --> 还原棕 1 --> 2-氯-3-甲基-5-溴吡啶 --> 2,4,5-三氟苯乙酸 --> 3-硝基-4-氯甲苯 --> 酸性兰 129 --> 3-氯噻吩-2-甲酰胺 --> 2,4,6-三甲氧基苯甲醛 --> 甲基二氯硅烷 --> 5-ó4-氟-3-(三氟甲烷)-2-糠醛 --> 2-氯-5-碘吡啶 --> 5-(4-溴苯基)-2-呋喃甲醛 --> 氯甲基硅烷 --> 5-ó2-氯-4-(三氟甲烷)苯基-2-糠醛 --> 2,3-二氯
- 蒸气压:1.3 mm Hg ( 546 °C)
- 用途二:用作有机合成催化剂,
- Acros Organics:氯化亚铜 Copper(I) chloride, extra pure, 97+%(7758-89-6)