Antimony trifluoride 氟化锑
CAS 7783-56-4 MFCD00011218
化学结构图
SMILES: F[Sb](F)F
化学属性
| Mol. Formula | SbF3 |
|---|---|
| Mol. Weight | 179 |
| Density | 4.38 |
| Melting Point | 235 |
| TSCA | Yes |
| Boiling Point | 376°C |
| Solubility | Soluble in water (4430 mg/ml at 20 °C), methanol (1540 mg/ml), and acetone. Insoluble in ammonia. |
| Flash Point | 376°C |
| Appearance | powder |
| Stability | 对湿度敏感 |
别名和识别编码
| Chemical Name | Antimony trifluoride |
|---|---|
| Synonym | ANTIMONY FLUORIDE, TRI ANTIMONY TRIFLUORIDE ANTIMONY(III) FLUORIDE Antimoine fluorure Antimon(III)-fluorid Antimontrifluorid Antimony trifluoride Antimony trifluoride; Trifluorostibine Antimony(III) fluoride Antimony(iii) fluoride (1:3) NA 1549 Stibine, trifluoro- Trifluorostibine Trifluorostibine 三氟化锑 antimoinefluorure antimoinefluorure(french) antimonousfluoride antimony (III) fluoride antimony(iii)fluoride(1:3) trifluoro-stibin trifluorostibine 三氟化锑 三氟化锑,氟化亚锑 三氟化锑; 氟化亚锑 氟化銻 氟化锑(III) 氟化锑, 99+% |
| CAS Number | 7783-56-4 |
| EC Number | 232-009-2 |
| Beilstein Registry Number | 2384789 |
| MDL Number | MFCD00011218 |
| PubChem Substance ID | 24554 |
| Merck Number | 14,709 |
| Chemical Name Translation | 氟化锑 |
| LabNetwork Molecule ID | LN01255692 |
| InChI | InChI=1S/3FH.Sb/h3*1H;/q;;;+3/p-3 |
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分类
- {SNA} Antimony, Antimony Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Materials Science, Metal and Ceramic Science, Research Essentials, Salts
- {SNA} Antimony Catalysts, Antimony Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, 材料科学
- {uni_hamburg} no charge; 1fragment
- {SNA} Antimony, Antimony Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Research Essentials,
产品应用
- 氟化反应催化剂，氯氟化合物的制备。棉织物的媒染剂。
相关文献及参考
- Merck: 14,709
- Short: III/20c
- Short: III/31b
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S7 Keep container tightly closed 保存在严格密闭容器中；
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
- R51/53
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P281 Use personal protective equipment as required. 使用所需的个人防护装备。
- P301+P310
- P301+P312
- P301+P330+P331
- P302+P352
- P303+P361+P353
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P308+P313
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P332+P313
- P337+P313
- P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H301 Toxic if swallowed 吞食有毒
- H301+H311+H331
- H311 Toxic in contact with skin 皮肤接触中毒
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H331 Toxic if inhaled 吸入中毒
- H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
其他信息
- 三氟化锑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 191240050 三氟化锑 Antimony trifluoride 98% 5 GR 291元 2010/06/21 191241000 三氟化锑 Antimony trifluoride 98% 100 GR 475元 2010/06/21 191245000 三氟化锑 Antimony trifluoride 98% 500 GR 1573元
- 毒性分级:高毒
- MOL 文件:7783-56-4.mol
- 可燃性危险特性:不燃; 遇水或酸放出腐蚀的氟化氢气体; 受热产生有毒氟化物和含锑化物烟雾
- 职业标准:TWA 0.5 毫克(锑)/ 立方米; STEL 2.5 毫克 (氟)/立方米
- 升华点:376 °C
- MSDS 信息:三氟化锑(7783-56-4).msds
- 用途二:氟化反应催化剂，氯氟化合物的制备。棉织物的媒染剂。
- Sigma Aldrich:7783-56-4(sigmaaldrich)
- 急性毒性:皮下- 小鼠 LDL0: 22.9 毫克/ 公斤; 口服- 小鼠 LD50: 804 毫克/ 公斤
- Acros Organics:三氟化锑 Antimony trifluoride, 98%(7783-56-4)
- Alfa Aesar:氟化锑,99+% Antimony(III) fluoride, 99+%(7783-56-4)
- 敏感性:Moisture Sensitive
- 有吸湿性、腐蚀性；溶于水，水中溶解度: 385 G/100ML (20°C)，并产生一定程度的水解，生成［SbF4]-和许多溶解性盐，不溶于氨水。有毒，最小致死量(蛙，皮下)224mg/kg。对皮肤有刺激性。
- F:10
- 储运特性:库房通风低温干燥; 与酸类、食品添加剂分开存放
- Hazard Note:Corrosive/Highly Toxic
- 外观性质:白色至灰色结晶, 易潮解。
- 水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 385g/0℃;444g/20℃;562g/30℃;水解/40℃
- 用途一:用作分析试剂和棉织物的媒染剂
- 类别:有毒物品
