Vanadium(V) Oxychloride 三氯氧钒(V)
CAS 7727-18-6 MFCD00011459
化学结构图
SMILES: O=[V](Cl)(Cl)Cl
化学属性
| Mol. Formula | VOCl3 |
|---|---|
| Mol. Weight | 173.30 |
| Boiling Point | 126-127 °C(lit.) |
| Vapor Pressure | 13.8 mmHg ( 20 °C) |
| Density | 1.84 g/mL at 25 °C(lit.) |
| Melting Point | -77 °C(lit.) |
| Refractive index | 1.829 |
| TSCA | Yes |
| Flash Point | 126-127°C |
| Solubility | 溶于乙醇、丙酮、乙酸、四氯化碳、烃类。 |
| Appearance | orange liq. |
| Stability | moisture sensitive |
别名和识别编码
| Chemical Name | Vanadium(V) Oxychloride |
|---|---|
| Synonym | Vanadium oxide trichloride vanadiumtrichloridemonooxide Trichlorooxovanadium oxide Vanadiumoxytrichlorid Vanadium(V) trichloride oxide vanadiummonoxidetrichloride Vanadium chloride oxide (VOCl3) vanadiumoxidetrichloride Trichlorovanadium oxide Vanadium, trichlorooxo- Vanadyl chloride (VOCl3) Vanadium(V)-oxytrichlorid 三氯氧化钒 Vanadium (V) trichloride oxide Vanadium, trichlorooxo-, (T-4)- trichlorooxo-vanadiu VANADIUM OXYTRICHLORIDE Vanadyl trichloride vanadiumchlorideoxide(vocl3) Vanadium oxychloride Vanadium oxytrichloride Vanadium chloride oxide 三氯氧钒(V) Vanadium trichloride oxide Vanadyl chloride trichlorooxo-,(T-4)-Vanadium 三氯一氧化钒 三氯氧钒(高纯试剂) VANADIUM(V) TRICHLORIDE OXIDE 三氯代氧化钒 VANADYL CHLORIDE trichlorooxovanadiumoxide Vanadium monoxide trichloride Vanadium,trichlorooxo- Vanadium trichloride monoxide VANADIUM (V) OXYCHLORIDE Trichlorooxovanadium(V) Vanadium chloride oxide (VCl3O) Vanadium(V) oxytrichloride 三氯代氧化钒(V), V|+^5 28.5% MIN Trichlorooxovanadium Trichlorooxovanadium oxide 三氯一氧化钒 三氯代氧化钒(V) VANADIUM(V) OXYTRICHLORIDE VANADYL(V) CHLORIDE Vanadium trichloride monooxide trichlorooxovanadium 三氯氧钒 |
| MDL Number | MFCD00011459 |
| CAS Number | 7727-18-6 |
| PubChem Substance ID | 24851980 |
| EC Number | 231-780-2 |
| Merck Number | 14,9927 |
| Chemical Name Translation | 三氯氧钒(V) |
| Wiswesser Line Notation | VA G3-O |
| LabNetwork Molecule ID | LN02144311 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, Vanadium, Vanadium Salts, 材料科学
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Materials Science, Metal and Ceramic Science, Research Essentials, Salts, Vanadium, Vanadium Salts
- {uni_hamburg} no charge; 1fragment
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Salts, Vanadium, Vanadium Salts
相关文献及参考
- Short: II/25A Title: Structure Data Of Free Polyatomic Molecules: Inorganic Molecules Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25A Year: 1998 Keyword: Free Polyatomic Molecules; Inorganic Molecules; Molecules ISBN: 3-540-61713-2 ISBN: 978-3-540-61713-6 Internet Resource: DOI:10.1007/b59072 RefComment: VII, 359 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
- Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
- Short: III/31a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cu Author: Ch
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H301 Toxic if swallowed 吞食有毒
- P301+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- R34 Causes burns 会导致灼伤
- R14 Reacts violently with water 遇水会猛烈反应
- R25 Toxic if swallowed 吞咽有毒
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S30 Never add water to this product 切勿将水加入该产品中；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S8 Keep container dry 保持容器干燥；
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 140 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969
其他信息
- 可燃性危险特性:遇水分解有毒氯化氢气体
- 灭火剂:砂土、干粉、二氧化碳
- 毒性分级:中毒
- 类别:腐蚀物品
- MOL 文件:7727-18-6.mol
- 外观性质:柠檬黄液体。
- 三氯氧钒价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 81118 Vanadium(V) trichloride oxide, V+5 28.5% min 500g 1026元 2010/05/25 81118 Vanadium(V) trichloride oxide, V+5 28.5% min 10g 270元 2010/05/25 81118 Vanadium(V) trichloride oxide, V+5 28.5% min 100g 364元
- 下游产品:钛
- 职业标准:TWA 0.05 毫克(五氧化二钒)/立方米; STEL 0.1 毫克(五氧化二钒)/立方米
- 用途一:是制取乙丙橡胶、乙烯-环戊二烯共聚合的催化剂
- 蒸气压:13.8 mm Hg ( 20 °C)
- Alfa Aesar:三氯代氧化钒(V),Puratronic|r,99.995%(metalsbasis) Vanadium(V) trichloride oxide, Puratronic|r, 99.995% (metals basis)(7727-18-6)
- MSDS 信息:三氯氧化钒(7727-18-6).msds
- 储运特性:库房通风低温干燥; 与碱分开存放
- F:10-21
- 敏感性:Moisture Sensitive
- 急性毒性:口服-大鼠 LD50: 140 毫克/公斤
- Sigma Aldrich:7727-18-6(sigmaaldrich)
