Tetrabutylphosphonium bromide 四丁基溴化膦
CAS 3115-68-2 MFCD00011853
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分类
- {SNA} Chemical Synthesis, Phase Transfer Catalysts, Phosphonium Salts, Synthetic Reagents
产品应用
- A useful synthetic reagent used in proteomics research.
相关文献及参考
- Has been used as an ionic liquid solvent in the regioselective O-alkylation of C/O ambident nucleophiles: Tetrahedron Lett., 33, 4435 (1992); see Tetra-n-butylammonium bromide, A10249.
- Quaternary phosphonium salt, useful as a phase-transfer catalyst at high temperatures, at which nitrogen analogues tend to undergo elimination (see Appendix 2), e.g. as catalyst for the dealkoxycarbonylation of malonates and ß-keto esters by heating in stearic acid: Synthesis, 320 (1985).
安全信息
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
- R24 Toxic in contact with skin 与皮肤接触有毒
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
- R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
- R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
GHS Symbol
- H302 Harmful if swallowed 吞食有害
- H310 Fatal in contact with skin 皮肤接触致命
- H311 Toxic in contact with skin 皮肤接触中毒
- H315 Causes skin irritation 会刺激皮肤
- H318 Causes serious eye damage 严重伤害眼睛
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312
- P301+P312+P330
- P302+P350
- P302+P352
- P302+P352+P310+P361+P364
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
- P330 Rinse mouth. 漱口
- P332+P313
- P337+P313
- P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >3 mg/m3/1H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 24,245,1982
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 56 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03131
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 700 mg/kg TOXIC EFFECTS : Behavioral - ataxia Lungs, Thorax, or Respiration - dyspnea Nutritional and Gross Metabolic - weight loss or decreased weight gain REFERENCE : TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 24,245,1982
其他信息
- 图谱信息:四丁基溴化(3115-68-2)红外图谱(IR1) 四丁基溴化(3115-68-2)质谱(MS) 四丁基溴化(3115-68-2)红外图谱(IR2) 四丁基溴化(3115-68-2)核磁图( 13 CNMR) 四丁基溴化(3115-68-2)核磁图( 1 HNMR)
- 溶解度:70%水、20%甲醇、80%2-丙醇、50%甲苯。
- 海关编码:29310095
- 敏感性:Hygroscopic
- Sigma Aldrich:3115-68-2(sigmaaldrich)
- Acros Organics:四丁基溴化膦 Tetrabutylphosphonium bromide, 98%(3115-68-2)
- 四丁基溴化价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1124 四丁基溴化磷 Tetrabutylphosphonium Bromide 25G 247元 2014/06/02 T1124 四丁基溴化磷 Tetrabutylphosphonium Bromide 500G 1940元 2010/06/21 183015000 四丁基溴化 Tetrabutylphosphonium bromide 98% 500 GR 1626元
- TCI Shanghai:四丁基溴化磷 Tetrabutylphosphonium Bromide,>;99.0%(T)(3115-68-2)
- Alfa Aesar:四正丁基溴化膦,typically95% Tetra-n-butylphosphonium bromide, typically 95%(3115-68-2)
- MOL 文件:3115-68-2.mol
- MSDS 信息:Tetrabutylphosphonium bromide(3115-68-2).msds
