2,4,6-Triphenylpyrylium tetrafluoroborate 2,4,6-三苯基吡喃四氟化硼盐

CAS 448-61-3 MFCD00012001

化学结构图

448-61-3
SMILES: F[B-](F)(F)F.c1ccc(-c2cc(-c3ccccc3)[o+]c(-c3ccccc3)c2)cc1

化学属性

Mol. FormulaC23H17BF4O
Mol. Weight396.19
Melting Point250-251 °C
TSCANo
Density1.0

别名和识别编码

Chemical Name2,4,6-Triphenylpyrylium tetrafluoroborate
MDL NumberMFCD00012001
CAS Number448-61-3
Beilstein Registry Number3586533
EC Number207-186-4
PubChem Substance ID9930615
Synonym 2,4,6-Triphenylpyrylium tetrafluoroborate {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetraflu
Chemical Name Translation2,4,6-三苯基吡喃四氟化硼盐
InChIKeyVQYPWMWEJGDSTF-UHFFFAOYSA-N
Wiswesser Line NotationT6OJ BR& DR& FR &.B-F4 &3/19
LabNetwork Molecule IDLN00201404
InChIInChI=1S/C23H17O.BF4/c1-4-10-18(11-5-1)21-16-22(19-12-6-2-7-13-19)24-23(17-21)20-14-8-3-9-15-20;2-1(3,4)5/h1-17H;/q+1;-1
Canonical SMILESFB(F)F.C1(C2=CC=CC=C2)=CC(C3=CC=CC=C3)=CC(C4=CC=CC=C4)=[O+]1.[F-]
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, O-Containing, Others
  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, O-Containing, Other Heterocyclic Building Blocks

相关文献及参考

  • Amines react with pyrylium salts to give N-alkylpyridinium salts. Since the pyridine can be displaced by a variety of nucleophiles, the result is that the amine has been converted to a useful alkylating species: J. Chem. Soc., Perkin 1, 418 (1979). Reviews: Tetrahedron, 36, 679 (1980); Angew. Chem. Int. Ed., 23, 420 (1984); Russ. Chem. Rev., 51, 469 (1982):
  • For a review on use as an electron-transfer photosensitizer, see: Chem. Rev., 94, 1063 (1994).

安全信息

RTECSUZ1370000
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S22 Do not breathe dust 不要吸入粉尘;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect fro
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02142

其他信息

  • 图谱信息:2,4,6-三苯基吡喃四氟化硼盐(448-61-3)核磁图( 1 HNMR)
  • 2,4,6-三苯基吡喃四氟化硼盐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 389290250 2,4,6-三苯基吡喃四氟化硼盐 2,4,6-Triphenylpyrylium tetrafluoroborate 97+% 25 GR 1349元 2010/06/21 389290050 2,4,6-三苯基吡喃四氟化硼盐 2,4,6-Triphenylpyrylium tetrafluoroborate 97+% 5 GR 341元 2010/05/25 A18217 2,4,6-三苯基吡喃四氟硼酸盐, 97% 2,4,6-Triphenylpyrylium tetrafluoroborate, 97% 25g 1302元
  • MOL 文件:448-61-3.mol
  • Alfa Aesar:2,4,6-三苯基吡喃四氟硼酸盐,97% 2,4,6-Triphenylpyrylium tetrafluoroborate, 97%(448-61-3)
  • Acros Organics:2,4,6-Triphenylpyrylium tetrafluoroborate, 97+%(448-61-3)
  • 敏感性:Moisture Sensitive
  • Sigma Aldrich:448-61-3(sigmaaldrich)

系列性分类


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