CAS 1918-02-1 MFCD00012101-Picloram 毒莠定 TAO{mole}

Picloram 毒莠定

CAS 1918-02-1 MFCD00012101

化学结构图

SMILES: Nc1c(Cl)c(Cl)nc(C(=O)O)c1Cl

化学属性

Mol. Formula	C6H3Cl3N2O2
Mol. Weight	241.46
Melting Point	200°C
Solubility	420 MG/L
Density	1.811
Flash Point	208.1±28.7 °C

别名和识别编码

Chemical Name	Picloram,Picloram
Synonym	Picloram {LY} Picloram {} {LY} Picloram {} {} {LY} Picloram {} {} {} {LY} Picloram {} {} {} {} {LY} Picloram {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number	1918-02-1
PubChem Substance ID	15965
EC Number	217-636-1
Beilstein Registry Number	479075
MDL Number	MFCD00012101
Reaxys-RN	479075
Merck Number	7397
Alfabeta Name	AMINOTRICHLOROPYRIDINECARBOXYLICACID 43562-----,,
Chemical Name Translation	毒莠定
Wiswesser Line Notation	T6NJ BVQ CG DZ EG FG
InChI	InChI=1S/C6H3Cl3N2O2/c7-1-3(10)2(8)5(9)11-4(1)6(12)13/h(H2,10,11)(H,12,13)
Canonical SMILES	O=C(C1=NC(Cl)=C(Cl)C(N)=C1Cl)O

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产品应用

毒莠定及其盐可迅速地通过叶和根吸收与传导，除十字化科作物外大多数阔叶作物都对该药敏感，大多数禾本科作物是耐药的。

安全信息

GHS Symbol

WGK Germany2

Hazard Codes 9

Hazard statements

H303 May be harmfully swallowed 吞食可能有害
H319 Causes serious eye irritation 严重刺激眼睛
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

RTECSTJ7525000

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P317
P304+P340
P304+P340+P312
P305+P351+P338
P305+P351+P338+P337+P313
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
P319
P332+P313
P332+P317
P337+P313
P337+P317
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Warning {} {} {} {} {} {} {TCI}

UN Number 3077

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；

Risk Statements

R36 Irritating to eyes 刺激眼睛

Warnings IRRITANT

Packing GroupIII

Hazard Class9

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 416 gm/kg/80W-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Liver - tumors
   Endocrine - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-23,1978

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 417 gm/kg/80W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Endocrine - tumors
   Endocrine - thyroid tumors
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 7,207,1981

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 208 mg/kg/80W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Endocrine - tumors
   Endocrine - thyroid tumors
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 7,207,1981

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 340 gm/kg/80W-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Endocrine - tumors
   Endocrine - thyroid tumors
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >4 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   WRPCA2 World Review of Pest Control.  (London, UK)  V.1-10, 1962-71.
   Discontinued.  Volume(issue)/page/year: 9,119,1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DOEAAH Down to Earth.  (Dow Chemical USA, Agricultural Products Dept.,
   Midland, MI 48640) V.1-    1945-  Volume(issue)/page/year: 35,25,1979

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GUCHAZ Guide to the Chemicals Used in Crop Protection.  (Information Canada,
   171 Slater St., Ottawa, Ont., Canada)  Volume(issue)/page/year: 6,414,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - duck
DOSE/DURATION           : >2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DOEAAH Down to Earth.  (Dow Chemical USA, Agricultural Products Dept.,
   Midland, MI 48640) V.1-    1945-  Volume(issue)/page/year: 35,25,1979

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 200 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 57,277,1978

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 100 mg/L
REFERENCE :
   TGANAK Tsitologiya i Genetika.  Cytology and Genetics.  For English
   translation, see CYGEDX. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-    1967-  Volume(issue)/page/year: 18,455,1984

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 5 gm/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 10,797,1972

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 7500 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - urogenital system
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 10,797,1972

其他信息

储运特性:库房通风低温干燥; 与食品原料分开储运
用途一:毒莠定及其盐可迅速地通过叶和根吸收与传导，除十字化科作物外大多数阔叶作物都对该药敏感，大多数禾本科作物是耐药的。
MOL 文件:1918-02-1.mol
类别:农药
职业标准:TLTLV-TWA 10毫克/ 立方米; STEL 20 毫克/ 立方米
毒性分级:中毒
灭火剂:干粉、泡沫、砂土
急性毒性:口服- 大鼠 LD50: 2898 毫克/ 公斤; 口服- 小鼠 LD50: 1061 毫克/公斤
MSDS 信息:4-氨基-3,5,6-三氯-2-皮考林酸(1918-02-1).msds
外观性质:白色粉末或浅褐色颗粒,带有氯气气味。
可燃性危险特性:燃烧产生有毒含氯化物和氮氧化物气体
Sigma Aldrich:1918-02-1(sigmaaldrich)
4-氨基-3,5,6-三氯吡啶羧酸价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 P1864 毒莠定 Picloram 5G 931元 2014/06/02 P1864 毒莠定 Picloram 25G 2820元