p-Tolylhydrazine hydrochloride 对甲基苯肼盐酸盐

CAS 637-60-5 MFCD00012940

化学结构图

637-60-5
SMILES: Cc1ccc(NN)cc1.Cl

化学属性

Mol. FormulaC7H10N2
Mol. Weight159
Melting Point>;200 °C (dec.)(lit.)
TSCAYes
Solubilitysoluble
Density1.18

别名和识别编码

Chemical Namep-Tolylhydrazine hydrochloride
CAS Number637-60-5
Alfabeta NameTOLYLHYDRAZINEHYDROCHLORIDE P-
MDL NumberMFCD00012940
Synonym 4-甲基苯肼 盐酸盐 (4-methylphenyl)-hydrazinmonohydrochloride 4-METHYLPHENYLHYDRAZINE HYDROCHLORIDE 4-TOLYLHYDRAZINE HYDROCHLORIDE Tolyl Hydrazine Hcl P(4)-tolylhydrazine hydrochoride 4-甲基苯肼盐酸盐 4-Methylphenylhydrazine hydrochloride 98% PARA-TOLYLHYDRAZINEHCL 4-TOLYLHYDRAZINE HCL -METHYL PHENYL HYDRAZINE HYDROCHLORIDE 4-Methylphenylhydrazine hydrochloride 1-(4-methylphenyl)hydrazine hydrochloride HYDRAZINE,PARA-TOLYL,HYDROCHLORIDE P-TOLYL HYDRAZINE HCL p-tolyhydrazine hydrochloride p-tolyl-hydrazinhydrochloride P-METHYLPHENYLHYDRAZINE HYDROCHLORIDE p-tolylhydrazinium(1+) chloride 对甲基苯肼 盐酸盐 对甲苯肼盐酸盐 4-METHYLPHENYLHYDRAZINE HCL p-Tolylhydrazine hydrochloride (4-Methylphenyl)hydrazinemonohydrochloride P-TOLYLHYDRAZINE HYDROCHLORIDE 对甲基苯肼盐酸盐 p-Tolylhydrazinehydrochloride,98%
PubChem Substance ID12504
EC Number211-295-2
Beilstein Registry Number15,510
Chemical Name Translation对甲基苯肼盐酸盐
Merck Number9542
Reaxys-RN3563996
Wiswesser Line NotationZMR D1 &GH
InChIKeyHMHWNJGOHUYVMD-UHFFFAOYSA-N
LabNetwork Molecule IDLN00173223
InChIInChI=1S/C7H10N2.ClH/c1-6-2-4-7(9-8)5-3-6;/h2-5,9H,8H2,1H3;1H
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分类

  • Building Blocks, Chemical Synthesis, Hydrazines, Nitrogen Compounds, Organic Building Blocks
  • {SNA} Building Blocks, Chemical Synthesis, Hydrazines, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 医药及染料中间体。

相关文献及参考

  • Beilstein:15,510

安全信息

Warnings TOXIC
GHS Symbol
WGK Germany3
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes Xn Xn,Xi
RTECSMW0195000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310+P330
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P332+P313
  • P301+P310
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P405 Store locked up. 上锁保管。
  • P305+P351+P338+P337+P313
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P302+P350
Signal word Danger
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Packing GroupIII
UN Number UN 2811 6.1/PG 3 UN2811 2811
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
Hazard Class6.1
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1750 mg/kg/7W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Vascular - tumors
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   ZKKOBW Zeitschrift fuer Krebsforschung und Klinische Onkologie.  (Berlin,
   Fed. Rep. Ger.)  V.76-92, 1971-78.  For publisher information, see JCROD7.
   Volume(issue)/page/year: 89,245,1977

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3640 mg/kg/26W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 8,1,1981

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1400 mg/kg/10W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   ZKKOBW Zeitschrift fuer Krebsforschung und Klinische Onkologie.  (Berlin,
   Fed. Rep. Ger.)  V.76-92, 1971-78.  For publisher information, see JCROD7.
   Volume(issue)/page/year: 89,245,1977

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 237 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Lungs, Thorax, or Respiration - cyanosis
   Skin and Appendages - hair
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0546022

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 262 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Lungs, Thorax, or Respiration - cyanosis
   Skin and Appendages - hair
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0546022

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 800 ug/plate
REFERENCE :
   NEZAAQ Nippon Eiseigaku Zasshi.  Japanese Journal of Hygiene.  (Nippon Eisei
   Gakkai, c/o Kyoto Daigaku Igakubu, Konoe-cho, Yoshida, Sakyo-ku, Kyoto 606,
   Japan)  V.1-    1946-  Volume(issue)/page/year: 33,474,1978

其他信息

  • 图谱信息:4-甲基苯肼盐酸盐(637-60-5)核磁图( 13 CNMR) 4-甲基苯肼盐酸盐(637-60-5)质谱(MS) 4-甲基苯肼盐酸盐(637-60-5)核磁图( 1 HNMR) 4-甲基苯肼盐酸盐(637-60-5)红外图谱(IR1) 4-甲基苯肼盐酸盐(637-60-5)红外图谱(IR2)
  • 用途一:用作医药及染料中间体
  • Sigma Aldrich:637-60-5(sigmaaldrich)
  • Acros Organics:对甲苯肼盐酸盐 p-Tolylhydrazine hydrochloride, 98%(637-60-5)
  • Alfa Aesar:对甲苯肼盐酸盐,98% p-Tolylhydrazine hydrochloride, 98%(637-60-5)
  • 4-甲基苯肼盐酸盐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010112 4-甲基苯肼盐酸盐 10g 500元 2011/04/16 T0319 对甲苯肼盐酸盐 p-Tolylhydrazine Hydrochloride 25G 1080元 2011/04/16 T0319 对甲苯肼盐酸盐 p-Tolylhydrazine Hydrochloride 250G 6250元
  • 溶于水。
  • 用途二:医药及染料中间体。
  • 存储注意事项:热敏感
  • 检测方法:AT
  • MOL 文件:637-60-5.mol
  • 下游产品:
  • Hazard Note:Harmful/Irritant
  • MSDS 信息:4-Methylphenylhydrazine hydrochloride(637-60-5).msds
  • TCI Shanghai:对甲苯肼盐酸盐 p-Tolylhydrazine Hydrochloride,>;98.0%(T)(637-60-5)
  • 海关编码:29280090

系列性分类


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