Palladium(II) Trifluoroacetate 三氟乙酸钯
CAS 42196-31-6 MFCD00013204
化学结构图
SMILES: O=C(O[Pd]OC(=O)C(F)(F)F)C(F)(F)F
化学属性
| Mol. Formula | C4F6O4Pd |
|---|---|
| Mol. Weight | 332 |
| Melting Point | 210 |
| TSCA | No |
| Density | 1.422 |
| Redox | Reduction |
别名和识别编码
| Chemical Name | Palladium(II) Trifluoroacetate |
|---|---|
| Synonym | 2,7-DICHLORO-9-FLUORENONE, TECH., 90% PALLADIUM (II) TRIFLUOROACETATE 97+% PALLADIUM TRIFLUOROACETATE Palladium(II) trifluoroacetate, min. 97% Palladium(II)trifluoroacetate,min.97% Pd(TFA)2 Trifluoroacetic acid palladium(II) salt 三氟乙酸 钯(II) 盐 |
| MDL Number | MFCD00013204 |
| PubChem Substance ID | 2733347 |
| CAS Number | 42196-31-6 |
| Reaxys-RN | 15732764 |
| EC Number | 250-023-7 |
| Beilstein Registry Number | 2384789 |
| Chemical Name Translation | 三氟乙酸钯 |
| LabNetwork Molecule ID | LN00197814 |
| InChI | InChI=1S/2C2HF3O2.Pd/c2*3-2(4,5)1(6)7;/h2*(H,6,7);/q;;+2/p-2 |
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分类
- {SNA} C-H Activation, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis, Homogeneous Pd Catalysts, Material
- {SNA} C-H Activation, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis, Homogeneous Pd Catalysts, Micro/NanoElectronics, Palla
相关文献及参考
- Readily forms π-allylpalladium dimers with acyclic alkenes: J. Am. Chem. Soc., 102, 3572 (1980). See also Allylpalladium(II) chloride dimer, 10005. In combination with a phosphine ligand, particularly Tri(2-furyl)phosphine, L13329, has been found to give superior results to Palladium(II) acetate, 10516, or Tris(dibenzylideneacetone)dipalladium(0), 12760, as a Pd source in Heck, Stille and Suzuki coupling reactions carried out in supercritical CO2: Tetrahedron Lett., 40, 2221 (1999).
- Kato, K.; Motodate, S. et al. Angew. Chem. Int. Ed. Engl. 48 , 3326, (2009)
- 2. Science 316 , 1172, (2007) 摘要
- Tetrahedron Lett. 25 , 4187, (1984)
- Readily forms π-allylpalladium dimers with acyclic alkenes: J. Am. Chem. Soc., 102, 3572 (1980). See also Allylpalladium(II) chloride dimer, 10005. In combination with a phosphine ligand, particularly Tri(2-furyl)phosphine, L13329, has been found to give superior results to Palladium(II) acetate, 10516, or Tris(d
- R'kyek, O.; Halland, N. et al. Chem. Eur. J. 16 , 9986, (2010)
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
