Allylboronic acid pinacol ester 烯丙基硼酸频哪醇酯
CAS 72824-04-5 MFCD00013347
化学结构图
SMILES: CC1(C)OB(CC=C)OC1(C)C
化学属性
| Mol. Formula | C9H17BO2 |
|---|---|
| Mol. Weight | 168 |
| Refractive index | 1.4250 to 1.4290 |
| Boiling Point | 50-53 |
| Density | 0.896 |
| Flash Point | 46°C(lit.) |
| TSCA | No |
别名和识别编码
| Chemical Name | Allylboronic acid pinacol ester |
|---|---|
| CAS Number | 72824-04-5 |
| Alfabeta Name | ALLYLBORONICACIDPINACOLCYCLICESTER , |
| MDL Number | MFCD00013347 |
| Synonym | AKOS BRN-1082 Allylboronic acid pinacolate 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, Pinacol allylboronate ALLBORONIC ACID,PINACOL CYCLIC ESTER 2-ALLYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE 烯丙基硼酸频哪醇酯 PINACOL ALLYLBORONATE 丙烯基硼酸邻二叔醇酯 Allylboronic acid pinacol ester, 98+% Allylboronic acid piracol ester 4,4,5,5-Tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane 2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧杂环戊硼烷 2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧环戊硼烷 4,4,5,5-tetramethyl-2-(2-propen-1-yl)-1,3,2-dioxaborolane 4,4,5,5-tetramethyl-2-(2-propenyl)-1,3,2-dioxaborolane Allyl pinacol boronate Pinacolyl 2-propenylboronate 丙烯基硼酸频哪醇酯 丙烯基硼酸邻二叔醇酯R, 98+% 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ALLYLBORONIC ACID, PINACOL CYCLIC ESTER ALLYLBORONIC ACID PINACOL ESTER |
| PubChem Substance ID | 87560602 |
| Beilstein Registry Number | 4244068 |
| Chemical Name Translation | 烯丙基硼酸频哪醇酯 |
| Reaxys-RN | 4244068 |
| LabNetwork Molecule ID | LN00008794 |
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信息真实价格透明
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分类
- {SNA} Alkyl Boronate Esters, Boronate Esters, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents
相关文献及参考
- Reacts with carboxylic acids, in the presence of tri-n-butyltin hydride, to give homoallylic alcohols in good yield: Synthesis, 1573 (2001):
- Homoallylic alcohols can also be formed by allylboration of aldehydes; the reaction has been found to be accelerated by Lewis acids, e.g. AlCl3 or Sc(OTf)3: J. Am. Chem. Soc., 124, 12414 (2002).
安全信息
GHS Symbol
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P303+P361+P353
- P305+P351+P338
- P305+P351+P338+P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P370+P378
- P403+P235
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R10 Flammable 易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- TCI Shanghai:2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧杂硼烷 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane,>;97.0%(GC)(72824-04-5)
- 海关编码:29310095
- Alfa Aesar:丙烯基硼酸邻二叔醇酯r,98+% Allylboronic acid pinacol ester, 98+%(72824-04-5)
- 烯丙基硼酸频哪醇酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A2157 2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧杂环戊硼烷(含稳定剂噻吩嗪) 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) 5G 1390元 2014/06/02 A2157 2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧杂环戊硼烷(含稳定剂噻吩嗪) 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) 1G 455元 2010/06/21 395130010 烯丙基硼酸频哪醇酯 Allylboronic acid pinacol ester 98% 1 GR 449元
- Hazard Note:Irritant
- Sigma Aldrich:72824-04-5(sigmaaldrich)
- MOL 文件:72824-04-5.mol
- 烯丙基硼酸频哪醇酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 A2157 2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧杂环戊硼烷(含稳定剂噻吩嗪) 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) 5G 1310元 2011/04/16 A2157 2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧杂环戊硼烷(含稳定剂噻吩嗪) 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) 1G 436元 2010/06/21 395130010 烯丙基硼酸频哪醇酯 Allylboronic acid pinacol ester 98% 1 GR 449元
- Acros Organics:Allylboronic acid pinacol ester, 98%(72824-04-5)
- MSDS 信息:2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(72824-04-5).msds
