1,1-Dichloroethane 1,1-二氯乙烷
CAS 75-34-3 MFCD00013673
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {SNA} Additional Standards, Alpha Sort, Analytical Standards, Chemical Class, Chloro, Chromatography, D, Environmental Standards, Halogenated, Organic Pollutant Standards, Volatile & Semivolatile Standards, Volatiles/ Semivolatiles, 分析/色谱
- {uni_hamburg} no charge; 1fragment
- {SNA} Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chemical Class, Chloro, Chromatography, D, DIA - DIC, Environmental Standards, Halogenated, Volatiles/ Semivolatiles
- {SNA} Alpha Sort,
产品应用
- 用作溶剂及制造1,1,1-三氯乙烷的中间体
相关文献及参考
- Merck: 14,3810
- Merck: 14,3810 Beilstein: 1,IV,130
- Short: II/25B
- Short: II/2
安全信息
GHS Symbol
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P307+P311
- P337+P313
- P301+P312+P330
- P403+P233
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P303+P361+P353
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P304+P340
- P308+P313
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
- P233 Keep container tightly closed. ?保持容器密闭。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P273 Avoid release to the environment. 避免释放到环境中。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P304+P340+P312
- P305+P351+P338+P337+P313
- P308+P311
- P241+P242+P243
- P405 Store locked up. 上锁保管。
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H302 Harmful if swallowed 吞食有害
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S7 Keep container tightly closed 保存在严格密闭容器中;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- R11 Highly flammable 非常易燃
- R52/53
- R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
- R22 Harmful if swallowed 吞咽有害
- R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性:吸入,皮肤接触和吞食都会产生十分严重的不可逆危险
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
TYPE OF TEST : TD - Toxic dose (other than lowest) ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1300 gm/kg/78W-I TOXIC EFFECTS : Tumorigenic - equivocal tumorigenic agent by RTECS criteria Reproductive - Tumorigenic effects - uterine tumors REFERENCE : NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD) No.0-205. For publisher information, see NTPTR*. Volume(issue)/page/year: NCI-TR-66,1978
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 185 gm/kg/78W-I TOXIC EFFECTS : Tumorigenic - equivocal tumorigenic agent by RTECS criteria Reproductive - Tumorigenic effects - uterine tumors REFERENCE : NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD) No.0-205. For publisher information, see NTPTR*. Volume(issue)/page/year: NCI-TR-66,1978
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 13000 ppm/4H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD-A180-198
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 725 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : HYSAAV Hygiene and Sanitation (USSR). English translation of GISAAA. (Springfield, VA) 1964-71. Discontinued. Volume(issue)/page/year: 32(3),349,1967
TYPE OF TEST : Unscheduled DNA synthesis TEST SYSTEM : Rodent - rat Liver DOSE/DURATION : 13 mmol/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 221,263,1989
TYPE OF TEST : Sex chromosome loss and nondisjunction TEST SYSTEM : Mold - Aspergillus nidulans DOSE/DURATION : 2000 ppm REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 201,401,1988
TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE : 6000 ppm/7H SEX/DURATION : female 6-15 day(s) after conception TOXIC EFFECTS : Reproductive - Specific Developmental Abnormalities - musculoskeletal system REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,452,1974
其他信息
- 急性毒性:口服-大鼠 LD50: 725 毫克/公斤; 吸入-大鼠 LC50: 13000 PPM/4 小时
- 方法一:工业上由氯乙烯在氯化铝、氯化铁或氯化锌催化下,以1,1-二氯乙烷为介质,与氯化氢进行液相反应而得。在由乙烯氯化生产1,2-二氯乙烷时,还副产少量的1,1-二氯乙烷。
- 毒性分级:中毒
- MSDS 信息:1,1-二氯乙烷(75-34-3).msds
- 可燃性危险特性:易燃; 受热分解有毒氯化物气体, 如光气
- 溶于多数有机溶剂
- TCI Shanghai:1,1-二氯乙烷(含稳定剂硝基甲烷) 1,1-Dichloroethane (stabilized with Nitromethane),>;95.0%(GC)(75-34-3)
- Hazard Note:Flammable/Irritant
- 外观性质:无色带有醚味的油状液体。
- 类别:易燃液体
- 挥发性有机化合物(VOCs)单组分标准液
- 上游原料:氯化锌 --> 1,2-二氯乙烷
- 1,1-二氯乙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 TD036302 1,1-二氯乙烷 25g 589元 2011/04/16 D0363 1,1-二氯乙烷(含稳定剂硝基甲烷) 1,1-Dichloroethane (stabilized with Nitromethane) 500G 4390元 2011/04/16 D0363 1,1-二氯乙烷(含稳定剂硝基甲烷) 1,1-Dichloroethane (stabilized with Nitromethane) 25G 549元
- TSCA:T
- 灭火剂:泡沫, 干粉, 二氧化碳
- 用途一:用作溶剂和热敏质的萃取剂。工业应用上不如1,2-二氯乙烷广泛。
- 职业标准:TLV-TWA 810 毫克/立方米; STEL 1010 毫克/立方米
- 图谱信息:1,1-二氯乙烷(75-34-3)Raman光谱 1,1-二氯乙烷(75-34-3)红外图谱(IR1) 1,1-二氯乙烷(75-34-3)核磁图( 1 HNMR) 1,1-二氯乙烷(75-34-3)质谱(MS) 1,1-二氯乙烷(75-34-3)核磁图( 13 CNMR)
- 溶于多数有机溶剂。
- 爆炸物危险特性:与空气混合形成爆炸性混合物;
- 用途二:用作溶剂及制造1,1,1-三氯乙烷的中间体
- Sigma Aldrich:75-34-3(sigmaaldrich)
- MOL 文件:75-34-3.mol
- 下游产品:1,1-二氟乙烷
- 储运特性:库房通风低温干燥; 与氧化剂分开储运存放