Cyclopentadienylvanadium Tetracarbonyl Cyclopentadienylvanadium Tetracarbonyl
CAS 12108-04-2 MFCD00014259
化学结构图
SMILES: [V].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1 |^1:9,10,11,12,13|
化学属性
| TSCA | No |
|---|---|
| Mol. Formula | C5H5V(CO)4 |
| Mol. Weight | 228 |
| Appearance | orange to red xtl. |
| Stability | air sensitive, store cold |
| Boiling Point | (subl. 80-110°C/0.1mm) |
| Melting Point | 138°C |
别名和识别编码
| Chemical Name | Cyclopentadienylvanadium Tetracarbonyl |
|---|---|
| Synonym | Vanadium, tetracarbonyl(η5-2,4-cyclopentadien-1-yl)- Cyclopentadienyl-vanadium-tetracarbonyl Tetracarbonyl-π-cyclopentadienylvanadium Cyclopentadienyltetracarbonylvanadium Vanadium, tetracarbonyl(η5-2,4-cyclopentadien-1-yl)- Cyclopentadienylvanadium tetracarbonyl Vanadium, tetracarbonyl-π-cyclopentadienyl- Vanadium, tetracarbonylcyclopentadienyl- η5-Cyclopentadienylvanadium tetracarbonyl π-Cyclopentadienyltetracarbonylvanadium Tetracarbonyl(η5-cyclopentadienyl)vanadium Tetracarbonylcyclopentadienylvanadium Vanadium cyclopentadienyltetracarbonyl tetracarbonyl(eta5-cyclopenta-2,4-dien-1-yl)vanadium Vanadium, tetracarbonyl(η(5)-2,4-cyclopentadien-1-yl)- tetracarbonyl(η5-cyclopenta-2,4-dien-1-yl)vanadium |
| EC Number | 235-163-9 |
| Chemical Name Translation | Cyclopentadienylvanadium Tetracarbonyl |
| MDL Number | MFCD00014259 |
| CAS Number | 12108-04-2 |
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分类
- {uni_hamburg} no charge; metal-organic; other heterocycle; carbocycle; alicycle; fused rings; 3ring; 4ring; 5ring; 6ring; metal carbonyl; 1fragment; zwitterion
相关文献及参考
- Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.
- Short: II/24A Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, l-type, Centrifugal Distortion and Related Constants of Diamagnetic Diatomic, Linear, and Symmetric Top Molecules Author: Demaison, J.; Hübner, H.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24A Year: 1998 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-63267-0 ISBN: 978-3-540-63267-2 Internet Resource: DOI:10.1007/b60165 RefComment: VIII, 286 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index takin
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
- S20 When using do not eat or drink 使用时，不得进食，饮水；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S4 Keep away from living quarters 远离生活区；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
