Undec-10-Ynoic Acid 10-十一碳一炔酸

CAS 2777-65-3 MFCD00014389

化学结构图

2777-65-3
SMILES: C#CCCCCCCCCC(=O)O

化学属性

Mol. FormulaC11H18O2
Mol. Weight182
Boiling Point180
Melting Point42-46
Flash Point161°(321°F)
TSCANo

别名和识别编码

Chemical NameUndec-10-Ynoic Acid
CAS Number2777-65-3
PubChem Substance ID31039
EC Number220-471-8
Beilstein Registry Number1704918
MDL NumberMFCD00014389
Reaxys-RN1704918
Synonym LABOTEST-BB LT00233091 Hendecynoic acid 10-UNDECYNOIC ACID 10-十一碳一炔酸 10-炔-十一酸 10-十一碳炔酸 Undec-1-yn-11-oic acid TIMTEC-BB SBB008483 undec-10-ynoic acid
Chemical Name Translation10-十一碳一炔酸
Wiswesser Line NotationQV9UU1
LabNetwork Molecule IDLN00239790
InChIInChI=1S/C11H18O2/c1-2-3-4-5-6-7-8-9-10-11(12)13/h1H,3-10H2,(H,12,13)
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分类

  • {SA} Building Blocks, C11 to C12, Carbonyl Compounds, Carboxylic Acids, Chemical Synthesis, Organic Building Blocks
  • Building Blocks, C11 to C12, Carbonyl Compounds, Carboxylic Acids, Chemical Synthesis, Organic Building Blocks

相关文献及参考

  • For use in the synthesis of long-chain ω-hydroxy acids, by acetylenic coupling with bromoacetylenic alcohols (from hypobromite bromination of alkynols), see: Synthesis, 230 (1984).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
RTECSYQ3683000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 32 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#07969

其他信息

  • 上游原料:乙醚 --> 硫酸 --> 三氯甲烷 --> 溴 --> 硫酸钠 --> 氢氧化钾 --> 乙二醇二甲醚 --> 10-十一烯酸
  • 10-十一碳炔酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 U0054 10-十一碳炔酸 10-Undecynoic Acid 5G 1130元 2014/06/02 U0054 10-十一碳炔酸 10-Undecynoic Acid 1G 318元 2010/05/25 A13815 10-炔-十一酸, 96% 10-Undecynoic acid, 96% 5g 911元
  • TCI Shanghai:10-十一碳炔酸 10-Undecynoic Acid,>;95.0%(T)(2777-65-3)
  • Sigma Aldrich:2777-65-3(sigmaaldrich)
  • F:10-23
  • MOL 文件:2777-65-3.mol
  • Alfa Aesar:10-炔-十一酸,96% 10-Undecynoic acid, 96%(2777-65-3)
  • 图谱信息:10-十一碳炔酸(2777-65-3)质谱(MS) 10-十一碳炔酸(2777-65-3)红外图谱(IR1) 10-十一碳炔酸(2777-65-3)红外图谱(IR2) 10-十一碳炔酸(2777-65-3)核磁图( 13 CNMR) 10-十一碳炔酸(2777-65-3)核磁图( 1 HNMR)

系列性分类


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