p-Nitrophenyl Formate 4-硝基苯基甲酸酯

CAS 1865-01-6 MFCD00014713

化学结构图

1865-01-6
SMILES: O=COc1ccc([N+](=O)[O-])cc1

化学属性

Mol. FormulaC7H5NO4
Mol. Weight167.12
Melting Point71-74 °C
TSCAYes
Boiling Point279.0±32.0 °C at 760 mmHg

别名和识别编码

Chemical Namep-Nitrophenyl Formate
CAS Number1865-01-6
Synonym 4-Nitrophenyl formate {LY} 4-Nitrophenyl formate {} {LY} 4-Nitrophenyl formate {} {} {LY} 4-Nitrophenyl formate {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00014713
PubChem Substance ID74628
Beilstein Registry Number1950897
EC Number217-473-6
Chemical Name Translation4-硝基苯基甲酸酯
InChIKeyIEXRKQFZXJSHOB-UHFFFAOYSA-N
LabNetwork Molecule IDLN01303809
Canonical SMILESO=COC1=CC=C([N+]([O-])=O)C=C1
InChIInChI=1S/C7H5NO4/c9-5-12-7-3-1-6(2-4-7)8(10)11/h1-5H
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分类

  • {SNA} Amine Protection, Chemical Biology, Chemical Synthesis, Others, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
  • Aromatics
  • Miscellaneous Reagents

产品应用

  • A selective formylating agent for one of two amino groups in such basic amino acids as ornithine or lysine.

相关文献及参考

  • Schiller, P., et al.: J. Med. Chem., 43, 551 (2000),
  • Schreiner, E., et al.: Bioorg. Med. Chem. Lett., 14, 4999 (2004),
  • Convenient and selective reagent for the formylation of amino groups: Bull. Chem. Soc. Jpn., 36, 754 (1963); Synthesis, 979 (1982); Synth. Commun., 29, 1819 (1999).

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C Moisture & Light Sensitive
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....

其他信息

  • 甲酸对硝基苯酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 L00316 4-硝基苯酚甲酯, 98% 4-Nitrophenyl formate, 98% 5g 451元 2010/05/25 L00316 4-硝基苯酚甲酯, 98% 4-Nitrophenyl formate, 98% 25g 1806元
  • F:8-9-21
  • Sigma Aldrich:1865-01-6(sigmaaldrich)
  • 敏感性:Moisture & Light Sensitive
  • MOL 文件:1865-01-6.mol
  • Alfa Aesar:4-硝基苯酚甲酯,98% 4-Nitrophenyl formate, 98%(1865-01-6)

系列性分类


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