Tetrakis(Diethylamino)Titanium(Iv) 四（二乙氨基）钛（IV）

CAS 4419-47-0 MFCD00015648

化学结构图

4419-47-0
SMILES: CCN(CC)[Ti](N(CC)CC)(N(CC)CC)N(CC)CC

化学属性

Mol. Formula[(C2H5)2N]4Ti
Mol. Weight336.38
Refractive indexn20/D 1.536(lit.)
Boiling Point112 °C/0.1 mmHg(lit.)
Density0.931 g/mL at 25 °C(lit.)
TSCAYes
Flash Point10 ºC
Melting Point<4 ºC
Appearance yellow to orange liq.
Stabilitymoisture sensitive

别名和识别编码

Chemical NameTetrakis(Diethylamino)Titanium(Iv)
Synonym Titanium diethylamide 四(乙氨基)钛, 99.99% (METALS BASIS) 四(二乙氨基)钛 TETRAKIS(DIETHYLAMINO)TITANIUM Tetrakis(diethylamino)titanium,99.99%(metalsbasis) Ti 四(二乙基氨基)钛(IV) TDEAT 四(二乙基氨基)钛(IV) 四(二乙胺基钛) tetrakis(diethylamido)titanium(iv) Tetrakis(diethylamino)titanium(IV), Titanium(IV) tetrakis(diethylamide) TITANIUM (IV) DIETHYLAMIDE TETRAKIS(DIETHYLAMINO)TITANIUM, TECH. Ethanamine, N-ethyl-, titanium(4+) salt 四(乙氨基)钛 Titanium tetrakis(diethylamide) titanium diethylamide TITANIUM TETRAKIS(DIETHYLAMIDE) TDEAT 四(二乙基胺基)钛(IV) 四(二乙胺基钛) TETRAKIS(DIETHYLAMINO)TITANIUM, 99.999% TETRAKIS DIETHYL AMINO TITANIUM (IV)
CAS Number4419-47-0
PubChem Substance ID123216
Beilstein Registry Number3621431
MDL NumberMFCD00015648
Chemical Name Translation四（二乙氨基）钛（IV）
InChIKeyVJDVOZLYDLHLSM-UHFFFAOYSA-N
InChIInChI=1S/4C4H10N.Ti/c4*1-3-5-4-2;/h4*3-4H2,1-2H3;/q4*-1;+4
LabNetwork Molecule IDLN01253380
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分类

  • {SNA} CVD and ALD Precursors by Metal,
  • {SNA} CVD and
  • {SNA} 22: Titanium, CVD and ALD Precursors Packaged for Deposition Systems, CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis,
  • {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Titanium, Titanium Catalysts,

相关文献及参考

  • Beil. 4 ,IV,313
  • FT-IR 2 (3), 4497:A / Structure Index 1 , 485:B:6
  • Lukosius, M.; Wenger, C; Pasko, S.; Muessig, H-J. et. al Chem. Vap. Deposition 14 , 123, (2008)

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F,C F;Xi F,C,Xi
Precautionary statements
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P422 Store contents under… 存储目录在…之下。
  • P231+P232
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P370+P378
Signal word Danger
UN Number UN3129 3398 UN 3398 4.3/PG 1
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
  • R11 Highly flammable 非常易燃
  • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Storage condition Flammables area Air & Moisture Sensitive
Packing GroupII
Hazard Class4.3

其他信息

  • Sigma Aldrich:4419-47-0(sigmaaldrich)
  • MOL 文件:4419-47-0.mol
  • Acros Organics:Tetrakis(diethylamino)titanium, 99%(4419-47-0)
  • 四(二乙胺基钛)价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 293820050 四(二乙胺基钛) Tetrakis(diethylamino)titanium 99% 5 ML 1127元 2010/06/21 293820250 四(二乙胺基钛) Tetrakis(diethylamino)titanium 99% 25 ML 4501元 2010/05/25 40469 四(乙氨基)钛, 99.99% (metals basis) Tetrakis(diethylamino)titanium, 99.99% (metals basis) 2g 466元
  • Alfa Aesar:四(乙氨基)钛,99.99%(metalsbasis) Tetrakis(diethylamino)titanium, 99.99% (metals basis)(4419-47-0)
  • 敏感性:Moisture Sensitive
  • F:10-21
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Titanium - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Titanium - Catalysis and Inorganic Chemistry
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors Packaged for Deposition Systems - Vapor Deposition Precursors
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Titanium - CVD and ALD Precursors by Metal
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Tin
  1. CVD & ALD Precursors
  1. CVD & ALD Precursors
  2. Titanium
  1. Metal Alkylamides
  2. Titanium

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