Dibenzyl diazene-1,2-dicarboxylate 偶氮二羟酸二苄酯

CAS 2449-05-0 MFCD00016737

化学结构图

2449-05-0
SMILES: O=C(N=NC(=O)OCc1ccccc1)OCc1ccccc1

化学属性

Mol. FormulaC16H14N2O4
Mol. Weight298.30
Density1.19
Melting Point43-47°C
Flash Point>110°C
TSCAYes
Boiling Point456.8°C at 760 mmHg

别名和识别编码

Chemical NameDibenzyl Azodicarboxylate
CAS Number2449-05-0
EC Number219-508-0
Beilstein Registry Number2298734
MDL NumberMFCD00016737
Synonym Dibenzyl diazene-1,2-dicarboxylate {LY} Dibenzyl diazene-1,2-dicarboxylate {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {} {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {} {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {} {} {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {}
PubChem Substance ID75557
Alfabeta NameDIBENZYLAZODICARBOXYLATE
Reaxys-RN5292523
Chemical Name Translation偶氮二羟酸二苄酯
LabNetwork Molecule IDLN00226655
InChIInChI=1S/C16H14N2O4/c19-15(21-11-13-7-3-1-4-8-13)17-18-16(20)22-12-14-9-5-2-6-10-14/h1-10H,11-12H2
Canonical SMILESO=C(OCC1=CC=CC=C1)\N=N\C(=O)OCC1=CC=CC=C1
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分类

  • {SNA} Azo/Diazo Compounds, Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • For the formation of functionalized ß-amino alcohols by the three-component asymmetric assembly with an aldehyde and a ketone, see: Org. Lett, 5, 1685 (2003).
  • Beilstein: 6,IV,2467
  • Aza-dienophile; the cycloaddition products can be debenzylated by hydrogenolysis: J. Am. Chem. Soc., 109, 285 (1987); 110, 5229 (1988); 111, 2995 (1989). Compare Di-tert-butyl­ azodicarboxyl­ate, L00294, Diethyl­ azodicarboxyl­ate, L19348, and Diisopropyl­ azodicarboxyl­ate, L10386. Effects enantioselective ɑ-amination of aldehydes, mediated by L-Proline, A10199: J. Am. Chem. Soc., 124, 5656 (2002):

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R11 Highly flammable 非常易燃
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H242 Heating may cause a fire 加热可能会引起火灾
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes F;Xi
Warnings IRRITANT
Storage condition 2-8°C {LY} 2-8°C Light Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
UN Number 3223
Hazard Class4.1

其他信息

  • 外观性质:柠檬黄结晶固体。 熔点:44℃-46℃
  • Acros Organics:Dibenzyl azodicarboxylate, 94%(2449-05-0)
  • 偶氮二甲酸二苄酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0776 偶氮二甲酸二苄酯(40%的二氯甲烷溶液,约1.7mol/L) Dibenzyl Azodicarboxylate (40% in Dichloromethane, ca. 1.7mol/L) 25G 1170元 2010/06/21 270270050 偶氮二甲酸二苄酯 Dibenzyl azodicarboxylate 94% 5 GR 666元 2010/06/21 270270250 偶氮二甲酸二苄酯 Dibenzyl azodicarboxylate 94% 25 GR 2294元
  • MSDS 信息:Dibenzyl azodicarboxylate(2449-05-0).msds
  • Sigma Aldrich:2449-05-0(sigmaaldrich)
  • Alfa Aesar:偶氮二羟酸二苄酯,98% Dibenzyl azodicarboxylate, 98%(2449-05-0)
  • MOL 文件:2449-05-0.mol

系列性分类


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