CAS 118-58-1 MFCD00020034-Benzyl Salicylate 水杨酸苄酯 TAO{mole}

Benzyl Salicylate 水杨酸苄酯

CAS 118-58-1 MFCD00020034

化学结构图

SMILES: OC1C=CC=CC=1C(=O)OCC1C=CC=CC=1

化学属性

Mol. Formula	C14H12O3
Mol. Weight	228.24
Density	1.176
Refractive index	1.5800 to 1.5820
Flash Point	184°C(lit.)
TSCA	Yes
Boiling Point	168-170 °C at 5 mmHg
Melting Point	18-20 °C
Solubility	略溶于水
Appearance	稠厚液体。沸点320℃，208℃（3.33kPa），170℃（0.67kPa），相对密度1.1799（20/4℃），折光率1.5805。能与乙醇、乙醚混溶，微溶于水。具弱甜香味。

别名和识别编码

Chemical Name	Benzyl Salicylate
Synonym	Benzyl salicylate {LY} Benzyl salicylate {} {LY} Benzyl salicylate {} {} {LY} Benzyl salicylate {} {} {} {LY} Benzyl salicylate {} {} {} {} {LY} Benzyl salicylate {} {} {} {} {} {LY} Benzyl salicylate {} {} {} {} {} {} {LY} Benzyl salicylate {} {} {} {} {} {} {} {LY} Benzyl salicylate {} {} {} {} {} {} {} {} {LY} Benzyl salicylate {} {} {} {} {} {} {} {} {} {LY} Benzyl salicylate {} {} {} {} {} {} {} {} {} {} {LY} Benzyl salicylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyl salicylate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyl salicylate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyl salicylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyl salicylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyl salicylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzy
MDL Number	MFCD00020034
CAS Number	118-58-1
EC Number	204-262-9
Merck Number	1144
Beilstein Registry Number	2115365
PubChem Substance ID	8363
Chemical Name Translation	水杨酸苄酯
Reaxys-RN	2115365
Wiswesser Line Notation	QR BVO1R
LabNetwork Molecule ID	LN00193931
InChI	InChI=1S/C14H12O3/c15-13-9-5-4-8-12(13)14(16)17-10-11-6-2-1-3-7-11/h1-9,15H,10H2
Canonical SMILES	O=C(OCC1=CC=CC=C1)C2=CC=CC=C2O

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

安全信息

RTECSVO1750000

Risk Statements

R51/53
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Safety Statements

S24 Avoid contact with skin 避免皮肤接触；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S37 Wear suitable gloves 戴适当手套；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；

GHS Symbol

WGK Germany2

Hazard statements

H303 May be harmfully swallowed 吞食可能有害
H315 Causes skin irritation 会刺激皮肤
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激
H371 May cause damage to organs 可能导致器官损伤
H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。

Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352
P305+P351+P338
P305+P351+P338+P337+P313
P309+P311
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P333+P313
P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word

Hazard Codes Xi,N Xi

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2227 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 11,1029,1973

Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitro

其他信息

毒性分级:中毒
使用限量:FEMA(mg/kg)：软饮料1.4；冷饮0.89；糖果1.8；焙烤食品0.01～2.2。适度为限(FDA§172．515，2000)。
用途三:作为香料，特别是硝基麝香的溶剂，人造麝香和花香香料的定香剂。杀菌防腐剂。
方法二:由水杨酸与苄醇反应而得。也可由水杨酸钠与氯化苄反应而得。在水杨酸钠和稍过量的氯化苄混合物中，加入少量二乙胺，加热至130-140℃反应17h，冷却后用水洗涤反应物，过量的氯化苄用水蒸气蒸馏除去，对剩余的油状物进行真空蒸馏，收集170-175℃（0.93kPa）馏分。产率85%。
Sigma Aldrich:118-58-1(sigmaaldrich)
MSDS 信
方法一:由水杨酸与苯乙醇酯化而得。
急性毒性:口服-大鼠 LD50: 2227 毫克/公斤
Alfa Aesar:苄基水杨酸酯,99% Benzyl salicylate, 99%(118-58-1)
灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
爆炸物危险特性:与氧化剂反应激烈
可燃性危险特性:明火, 受热较易燃; 燃烧产生刺激烟雾
类别:易燃液体
柳酸苄酯价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 S0009 水杨酸苄酯 Benzyl Salicylate 500G 455元 2014/06/02 S0009 水杨酸苄酯 Benzyl Salicylate 25G 117元 2010/06/21 259600050 柳酸苄酯 Benzyl salicylate 98+% 5 GR 276元
FEMA:2151
毒性:GRAS(FEMA)。 LD 50 2227mg/kg(大鼠，经口)。
用途二:GB 2760—1996允许使用的食用香料。主要用于配制杏、桃、香蕉、树莓等型香精。
食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称允许使用该种添加剂的食品中文名称添加剂功能最大允许使用量（g/kg）最大允许残留量（g/kg）水杨酸苄酯食品食品用香料用于配制香精的各香料成分不得超过在GB 2760中的最大允许使用量和最大允许残留量
Acros Organics:水杨酸苄酯 Benzyl salicylate, 98+%(118-58-1)
含量分析:按酯含量测定法(OT-18)中方法二测定。试样量取1.4g。改用酚红试液(TS-66)作指示剂。计算中的当量因子(e)取114.1。
TCI Shanghai:水杨酸苄酯 Benzyl Salicylate,>;99.0%(GC)(118-58-1)
上游原料:苄基氯 --> 二乙胺 --> 苯乙醇 --> 水杨酸 --> 水杨酸钠
图谱信息:柳酸苄酯(118-58-1)Raman光谱柳酸苄酯(118-58-1)核磁图( 1 HNMR) 柳酸苄酯(118-58-1)质谱(MS) 柳酸苄酯(118-58-1)核磁图( 13 CNMR) 柳酸苄酯(118-58-1)红外图谱(IR1) 柳酸苄酯(118-58-1)红外图谱(IR2)
参考质量标准:FCC，1996 含量 ≥98.0% 折射率(n D 20 ) 1.573～1.582 相对密度(d 25 25 ) 1.176～1.180 凝固点 ≥23.5℃ 酸值(0T-4) ≤1.0(用酚红试液) 醇中溶解度(0T-43) 1ml溶于5mL 95%乙醇
储运特性:通风低温干燥; 与氧化剂分开存放
用途一:常作为花香型和非花香型香精的助溶剂与好的定香剂使用。适用于香石竹、依兰、茉莉、香罗兰、铃兰、紫丁香、晚香玉、百花型等香精。也可极微量用于杏子、桃子、梅子、香蕉、生梨等食用香精中。
MOL 文件:118-58-1.mol