CAS 6178-42-3 MFCD00024827-1-(4-Hydroxy-3-Methoxyphenyl)-2-Nitroethene 2-甲氧基-4-(2-硝基乙烯)酚 TAO{mole}

1-(4-Hydroxy-3-Methoxyphenyl)-2-Nitroethene 2-甲氧基-4-(2-硝基乙烯)酚

CAS 6178-42-3 MFCD00024827

化学结构图

SMILES: COc1cc(/C=C/[N+](=O)[O-])ccc1O

化学属性

Mol. Formula	C9H9NO4
Mol. Weight	195.17
Melting Point	168-170°C
Appearance	黄色结晶。熔点168-172℃。
Boiling Point	347.0±27.0 °C at 760 mmHg

别名和识别编码

Chemical Name	1-(4-Hydroxy-3-Methoxyphenyl)-2-Nitroethene
MDL Number	MFCD00024827
CAS Number	6178-42-3
Synonym	2-Methoxy-4-(2-nitrovinyl)phenol {LY} 2-Methoxy-4-(2-nitrovinyl)phenol {} {LY} 2-Methoxy-4-(2-nitrovinyl)phenol {} {} {LY} 2-Methoxy-4-(2-nitrovinyl)phenol {} {} {} {LY} 2-Methoxy-4-(2-nitrovinyl)phenol {} {} {} {} {LY} 2-Methoxy-4-(2-nitrovinyl)phenol {} {} {} {} {} {LY} 2-Methoxy-4-(2-nitrovinyl)phenol {} {} {} {} {} {} {LY} 2-Methoxy-4-(2-nitrovinyl)phenol {} {} {} {} {} {} {} {LY} 2-Methoxy-4-(2-nitrovinyl)phenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methoxy-4-(2-nitrovinyl)phenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methoxy-4-(2-nitrovinyl)phenol {} {} {} {} {} {} {} {} {} {} {LY} 2-Methoxy-4-(2-nitrovinyl)phenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methoxy-4-(2-nitrovinyl)phenol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methoxy-4-(2-nitrovinyl)phenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methoxy-4-(2-nitrovinyl)phenol {} {} {} {} {
PubChem Substance ID	638439
Chemical Name Translation	2-甲氧基-4-(2-硝基乙烯)酚
LabNetwork Molecule ID	LN02184993
InChI	InChI=1S/C9H9NO4/c1-14-9-6-7(2-3-8(9)11)4-5-10(12)13/h2-6,11H,1H3/b5-4+
Canonical SMILES	OC1=CC=C(/C=C/[N+]([O-])=O)C=C1OC

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

安全信息

WGK Germany3

GHS Symbol

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338

Signal word Warning

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes Xi

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

方法一:先用15倍量乙醇溶解盐酸甲胺，搅拌冷却加入碳酸钠。静置后过滤，滤渣用乙醇洗涤。洗滤液为盐酸甲胺乙醇溶液，pH为9。将香兰醛用乙醇溶解，搅拌下加入硝基甲烷，再加入上述盐酸甲胺乙醇溶液，室温搅拌3-4h。20℃以下放置7d，过滤，滤饼用乙醇洗涤，80℃干燥，得成品，收率90%-93%。
上游原料:香兰素 --> 硝基甲烷 --> 乙醇溶液 --> 1-氨基乙醇 --> 盐酸甲胺
下游产品:2-甲氧基-4-(2-氨基乙基)苯酚
MOL 文件:6178-42-3.mol
Hazard Note:Irritant
用途一:儿茶酚类药物多巴胺的中间体。
Sigma Aldrich:6178-42-3(sigmaaldrich)