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• 试剂商城
• 直接询价

分类

• Aldehydes, Building Blocks, C1 to C6, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
• {uni_hamburg} no charge; aldehyde; 1fragment
• {SA} Aldehydes, Building Blocks, C1 to C6, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
• {Chemicalbook} 农药中间体: 杀虫剂中间体: 有机磷类杀虫剂

相关文献及参考

• Short: II/27B Title: Diamagnetic Susceptibility of Organic Compounds, Oils, Paraffins and Polyethylenes Author: Kumar, M.; Gupta, R. Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27B Year: 2008 Keyword: diamagnetic susceptibility; organic compounds ISBN: 978-3-540-44359-9 (print) ISBN: 978-3-540-45860-9 (online) Internet Resource: doi:10.1007/978-3-540-45860-9 RefComment: VIII, 503 p. With CD-ROM., Hardcover RefComment: Written for: Scientists and researchers in the fields of physics, chemistry, materials science RefComment: Supplement and Revised Editon to II/16 Abstract: The volume II/27 has been divided into three subvolumes according to the classes of compounds: Subvolume A: Diamagnetic susceptibility and magnetic anisotropy of inorganic and organometallic compounds; Subvolume B: Diamagnetic susceptibility of organic compounds, oils, paraffins and polyethylenes; Subvolume C: Diamagnetic susceptibility and magnetic anisotropy of organic compounds. The data presented in this volume are based on the literature survey of the chemical abstracts up to 2005. The calculated values of diamagnetic susceptibility of organic compounds in the present subvolume II/27B are presented along with their experimental values. They have been calculated with the use of structural parameters in structural formula by using different theoretical methods available in the literature.
• Merck 14 ,9626
• Beil. 1 ,IV,3142
• Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid st

安全信息

GHS Symbol

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 440 mg/m3/4H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - ptosis
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0533728

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 5900 mg/m3/4H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - ataxia
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0571197

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BCFAAI Bollettino Chimico Farmaceutico.  (Societa Editoriale Farmaceutica,
   Via Ausonio 12, 20123 Milan, Italy)  V.33-    1894- Volume(issue)/page/year:
   111,293,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 710 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdun

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   STEVA8 Science of the Total Environment.  (Elsevier Science Pub. B.V., POB
   211, 1000 AE Amsterdam, Netherlands)  V.1-    1972- Volume(issue)/page/year:
   46,229,1985

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 1 gm/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 155,53,1985

其他信息

• 急性毒性:腹腔- 小鼠 LD50: 600 毫克/ 公斤
• 贮存:用塑料桶或内衬防腐涂层的
• 水合三氯乙醛:水合三氯乙醛简称水合氯醛。无色透明晶体。有特殊气味。分子式CCl3CH(OH)2。在空气中略挥发。比重1.9081。沸点97.5。熔点51.7 ℃。加热至沸点可分解为三氯乙醛和水。易溶于水、乙醇和乙醚，微溶于苯和二硫化碳。水溶液对石蕊试剂呈酸性反应。用于制药、三氯醋酸等。医学上用作镇静、催眠和镇痛药。成人经口急性中毒剂量为4～5g或约10g;成人经口最小致死量约为7g;经口平均致死量约10g。水合氯醛极易吸收，并可出现在脑脊液、乳汁、羊水及胎儿血液中。在体内大部还原为对中枢抑制作用更强的三氯乙醇，三氯乙醇迅即与葡萄糖醛酸结合而失去毒性，并经肾脏排出体外。内服可发生严重胃肠刺激，胃粘膜腐蚀而出现出血性胃炎。吸入高浓度蒸气可引起咽炎、支气管炎，抑制呼吸中枢导致呼吸中枢衰竭，呼吸肌麻痹。由于具有明显扩血管作用，可出现血压下降、体温降低、休克、晕厥及心律失常等。还可见瞳孔缩小，肝、肾受损等临床表现。慢性中毒可出现红斑状荨麻疹或紫癜样皮疹、结膜炎、流泪、眼睑浮肿、畏光、视力障碍;以及头痛、关节痛、食欲不振、呕吐、腹泻等表现。口服急性中毒者可用温水或1：2，000～1：5，000高锰酸钾洗胃。直肠给药中毒者应即时洗肠、导泻以及对症处理，预防心衰，呼吸衰竭和休克的发生。
• 水合三氯乙醛:水合三氯乙醛简称水合氯醛。无色透明晶体。有特殊气味。分子式CCl3CH(OH)2。在空气中略挥发。比重1.9081。沸点97.5。熔点51.7 ℃。加热至沸点可分解为三氯乙醛和水。易溶于水、乙醇和乙醚，微溶于苯和二硫化碳。水溶液对石蕊试剂呈酸性反应。用于制药、三氯醋酸等。医学上用作镇静、催眠和镇痛药。成人经口急性中毒剂量为4～5g或约10g;成人经口最小致死量约为7g;经口平均致死量约10g。水合氯醛极易吸收，并可出现在脑脊液、乳汁、羊水及胎儿血液中。在体内大部还原为对中枢抑制作用更强的三氯乙醇，三氯乙醇迅即与葡萄糖醛酸结合而失去毒性，并经肾脏排出体外。内服可发生严重胃肠刺激，胃粘膜腐蚀而出现出血性胃炎。吸入高浓度蒸气可引起咽炎、支气管炎，抑制呼吸中枢导致呼吸中枢衰竭，呼吸肌麻痹。由于具有明显扩血管作用，可出现血压下降、体温降低、休
• 下游产品:N,N-二甲基甲酰胺 --> 三氯甲烷 --> 1,2-二氯乙烷 --> 香兰素 --> 氯乙烷 --> 氯甲烷 --> 对羟基苯甲醛 --> 氯菊酯 --> 3-(2,2-二氯乙烯基)-2,2-二甲基环丙基羧酸甲基酯 --> 乙基香兰素 --> 氟氯氰菊酯 --> 三氯乙酸 --> 敌敌畏 --> 二氯菊酸乙酯 --> 水合氯醛 --> 氯氰菊酯 --> 右旋烯丙菊酯 -->
• 运输要求:一级有机酸性腐蚀物品。危规号：92008。可用管道或火车、汽车运输。
• 毒性分级:中毒
• 用途一:主要用于制造杀
• MOL 文件:75-87-6.mol
• 可燃性危险特性:受热分解有毒及催泪性气体
• 废弃物建议处理方法:三氯乙醛同其他易燃燃料混合后焚烧。必须注意，要保证完全燃烧，以防止光气产生; 为除去所产生的氢卤酸，备置酸涤气器是必要的。
• Sigma Aldrich:75-87-6(sigmaaldrich)
• 用途一:主要用于制造杀虫剂滴滴涕、敌百虫、敌敌畏和除莠剂三氯乙醛脲，也可用于医药工业及有机合成等
• 贮存:用塑料桶或内衬防腐涂层的金属桶或陶瓷坛盛装。存放在阴凉、干燥、通风良好的地方，防冻、防热、避水。
• 用途四:主要用于制造农药如杀虫剂滴滴涕、敌百虫、敌敌畏、除草剂三氯乙醛脲的原料。在医药工业中用于生产氯霉素、合霉剂、催眠剂水合三氯乙醛等，也可作为有机原料用于生产N,N-二甲基甲酰胺、三氯甲烷和氯仿等。
• 用途二:主要用于制造杀虫剂滴滴涕、敌百虫、敌敌畏和除草剂三氯乙醛脲，医药上用于生产氯霉素、合霉素等
• 危险情况:摄入有毒，有腐蚀性和麻醉性，接触皮肤时会引起灼伤，接触眼睛会使瞳孔放大; 吸入过量，严重时会造成窒息。
• 方法二:由乙醇
• 外观性质:无