Hexafluorosilicic acid 氟硅酸

CAS 16961-83-4 MFCD00036289

化学结构图

16961-83-4
SMILES: F.F.F[Si](F)(F)F

化学属性

Mol. FormulaF6
Mol. Weight144
Density1.31
TSCAYes
Boiling Point108-109°

别名和识别编码

Chemical NameHexafluorosilicic acid
MDL NumberMFCD00036289
PubChem Substance ID24863162
CAS Number16961-83-4
Synonym Dihydrogen hexafluorosilicate FKS Fluorosilicic acidHydrofluorosilicic acid Fluosilicic acid,Hexafluorosilicic acid Hexafluorkieselsäure Hexafluorokieselsaiure Hexafluorosilicic acid Hexafluorsiliciumsäure Hydrofluorosilicic acid Hydrogen fluorosilicate (H2SiF6) Hydrogen hexafluorosilicate Hydrosilicofluoric acid Kiezelfluorwaterstofzuur Silicon hexafluoride dihydride Wasserstoffhexafluorosilicat 氟硅酸 溶液
EC Number241-034-8
Merck Number14,4182
Chemical Name Translation氟硅酸
Wiswesser Line NotationH2 SI-F6
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分类

  • {SNA} Chemical Synthesis, Deprotecting Reagents, Fluoride Sources, Protection and Derivatization, Synthetic Reagents
  • Acids, Electronic Chemicals, Materials Science, Micro/NanoElectronics
  • {uni_hamburg} no charge; 3fragments; ionic
  • {SNA} Acids, Electronic Chemicals, Micro/NanoElectronics, 材料科学
  • {SA} Acids, Electronic Chemicals, Materials Science, Micro/NanoElectronics

相关文献及参考

  • Merck 14 ,4182
  • Short: IV/1b Title: Densities of Liquid Systems: Densities of Binary Aqueous Systems and Heat Capacities of Liquid Systems Author: D'Ans, J.; Surawski, H.; Synowietz, C. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/1b Year: 1977 ISBN: 3-540-08272-7 ISBN: 978-3-540-08272-9 Internet Resource: DOI:10.1007/b20004 RefComment: 62 figs., VII, 335 pages. Hardcover Abstract: Volume IV/1 contains information on the densities of liquid systems. It may be considered as a supplement to volume II/1 of the 6th Edition, which contains only a few data on nonaqueous systems. Data are not listed for all systems but primarily for those of greater interest where data for a larger range of concentrations were available.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Reagent, more selective than HF, for cleavage of silyl groups. Unlike HF, excess reagent is not required, and catalytic amounts are sometimes effective. TBDMS can be selectively cleaved in the presence of TBDPS or TIPS groups: J. Org. Chem., 57, 2492 (1992); 58, 5130 (1993); 60, 6674 (1995).

安全信息

WGK Germany2
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P301+P330+P331
  • P303+P361+P353
  • P304+P340+P310
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
Hazard Codes 8 C
GHS Symbol
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Danger
RTECSVV8225000
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
UN Number 1778
Risk Statements
  • R34 Causes burns 会导致灼伤
Packing GroupII
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Amphibian - frog
DOSE/DURATION           : 140 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CRSBAW Comptes Rendus des Seances de la Societe de Biologie et de Ses
   Filiales.  (SPPIF, B.P.22, F-41353 Vineuil, France)  V.1-    1849-
   Volume(issue)/page/year: 124,133,1937

系列性分类