Arsenazo III 偶氮胂III

CAS 1668-00-4 MFCD00036695

化学结构图

1668-00-4
SMILES: OC1=C2C(C=C(C(/N=N/C3C=CC=CC=3[As](O)(O)=O)=C2O)S(O)(=O)=O)=CC(=C1/N=N/C1C=CC=CC=1[As](O)(O)=O)S(O)(=O)=O

化学属性

Mol. FormulaC22H18As2N4O14S2
Mol. Weight776.37
Melting Point>320 °C
TSCANo
Stability对湿度敏感
SolubilitySoluble in water (partly), 1N NH4OH (1 mg/ml), and alcohol.

别名和识别编码

Chemical NameArsenazo III
MDL NumberMFCD00036695
CAS Number1668-00-4
Synonym Arsenazo III[Spectrophotometric reagents for uranium, thorium, zirconium and other metals, and indicators for sulfate titration with barium precipitation] {LY} Arsenazo III[Spectrophotometric reagents for uranium, thorium, zirconium and other metals, and indicators for sulfate titration with barium precipitation] {} {LY} Arsenazo III[Spectrophotometric reagents for uranium, thorium, zirconium and other metals, and indicators for sulfate titration with barium precipitation] {} {} {LY} Arsenazo III[Spectrophotometric reagents for uranium, thorium, zirconium and other metals, and indicators for sulfate titration with barium precipitation] {} {} {} {LY} Arsenazo III[Spectrophotometric reagents for uranium, thorium, zirconium and other metals, and indicators for sulfate titration with barium precipitation] {} {} {} {} {LY} Arsenazo III[Spectrophotometric reagents for uranium, thorium, zirconium and other metals, and indicators for sulfate titration with barium precipitation] {}
PubChem Substance ID87563103
Beilstein Registry Number5717957
EC Number216-788-6
Reaxys-RN5717957
Chemical Name Translation偶氮胂III
InChIKeyUQHVTNUJRKELCE-NBHCHVEOSA-N
Canonical SMILESO=S(C1=C(/N=N/C2=CC=CC=C2[As](O)(O)=O)C(O)=C3C(O)=C(/N=N/C4=CC=CC=C4[As](O)(O)=O)C(S(=O)(O)=O)=CC3=C1)(O)=O
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分类

  • {SA} Analytical Reagents, Analytical/Chromatography, Indicators, Metal Titration Indicators, Titration
  • {SNA} Analytical Reagents, Analytical/Chromatography, Indicators, Metal Titration Indicators, Titration

产品应用

  • Usually used in the determination of calcium in serum,has been used to evaluate calcium transport in permeabilized cells,has also been used for the spectrophotometric determination of uranium and thorium.

相关文献及参考

  • Beilstein: 16,IV,1194

安全信息

Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
GHS Symbol
Precautionary statements
  • P301+P310+P330
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P304+P340+P311
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P301+P310
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H301+H331
WGK Germany3
Signal word Danger
Hazard Codes T,N
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S20/21 When using do not eat, drink or smoke 使用时,不得进食,饮水或吸烟;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
  • R50/53
Packing GroupII
UN Number UN3465 3465
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {ALD} 密封保存。
Hazard Class6.1

其他信息

  • 易溶于水,在水溶液中呈玫瑰色,在硫酸中为红色,在碱性溶液中为蓝色。

系列性分类


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