1-Bromo-3,3,3-Trifluoroacetone 3-溴-1,1,1-三氟丙酮
CAS 431-35-6 MFCD00039237
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SNA} Building Blocks, C3 to C6, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
- Building Blocks, C3 to C6, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
相关文献及参考
- Beil. 1 ,IV,3220
- FT-NMR 1 (1), 652:B / RegBook 1 (1), 459:B / Structure Index 1 , 65:A:6
- A novel reductive olefination reaction with aldehydes, mediated by Ti(O-i-Pr)4 and PPh3, provides a one-pot synthesis of trifluoromethylated trans-allylic alcohols: Chem. Commun., 2195 (1998):
- The oxime is readily converted with base to the highly reactive species 1,1,1-trifluoro-2-nitroso-2-propene, which undergoes hetero-Diels-Alder reactions, e.g. with cyclopentadiene or indole to give fused oxazolines. The indole adduct rearomatizes to give 1-(3-indolyl)-3,3,3-trifluoroacetoxime: J. Org. Chem., 57, 339 (1992).
安全信息
GHS Symbol
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P403+P235
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R11 Highly flammable 非常易燃
- R37 Irritating to respiratory system 刺激呼吸道
- R34 Causes burns 会导致灼伤
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
其他信息
- F:19
- MSDS 信息:1-Bromo-3,3,3-trifluoroacetone(431-35-6).msds
- Alfa Aesar:1-溴-3,3,3-三氟丙酮97% 1-Bromo-3,3,3-trifluoroacetone, 97%(431-35-6)
- Acros Organics:3-溴-1,1,1-三氟丙酮 3-Bromo-1,1,1-trifluoroacetone, 97%(431-35-6)
- 图谱信息:3-溴-1,1,1-三氟丙酮(431-35-6)核磁图( 1 HNMR) 3-溴-1,1,1-三氟丙酮(431-35-6)质谱(MS) 3-溴-1,1,1-三氟丙酮(431-35-6)核磁图( 13 CNMR) 3-溴-1,1,1-三氟丙酮(431-35-6)红外图谱(IR1)
- TCI Shanghai:3-溴-1,1,1-三氟丙酮 3-Bromo-1,1,1-trifluoro-2-propanone,>;95.0%(GC)(431-35-6)
- Sigma Aldrich:431-35-6(sigmaaldrich)
- Hazard Note:Corrosive/Flammable/Lachrymatory
- 3-溴-1,1,1-三氟丙酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1240 1-溴-3,3,3-三氟丙酮 1-Bromo-3,3,3-trifluoroacetone 5G 429元 2014/06/02 B1240 1-溴-3,3,3-三氟丙酮 1-Bromo-3,3,3-trifluoroacetone 25G 1820元 2010/06/21 297440050 3-溴-1,1,1-三氟丙酮 3-Bromo-1,1,1-trifluoroacetone 97% 5 GR 400元
- 敏感性:Lachrymatory
- MOL 文件:431-35-6.mol