2,2,2-trifluoroacetyl chloride 三氟乙酰氯
CAS 354-32-5 MFCD00039307
化学结构图
SMILES: O=C(Cl)C(F)(F)F
化学属性
| Mol. Formula | C2ClF3O |
|---|---|
| Mol. Weight | 132.47 |
| Vapor Density | 4.6 (vs air) |
| Boiling Point | -27 °C(lit.) |
| Melting Point | -146 °C(lit.) |
| Density | 1,335 g/cm3 |
别名和识别编码
| Chemical Name | 2,2,2-trifluoroacetyl chloride |
|---|---|
| Synonym | {uni_hamburg} Perfluoroacetyl chloride TRIFLUOROACETYL CHLORIDE Acetyl chloride, trifluoro- Trifluoroacetic acid chloride trifluoroacetyl acid chloride TRIFLUOROACETYL CHLORIDE CYL. WITH 800 perfluoroacetylchloride Trifluoroacetylchloride trifluoro-acetyl chloride 氯化三氟乙酰 Trifluoroacetyl chloride 三氟乙酰氯 trifluoro-acetylchlorid Trifluoroacetylchloride97% Trifluoracetylchlorid 三氟乙醯氯 |
| EC Number | 206-556-2 |
| Beilstein Registry Number | 1098994 |
| MDL Number | MFCD00039307 |
| PubChem Substance ID | 61106 |
| CAS Number | 354-32-5 |
| Chemical Name Translation | 三氟乙酰氯 |
| Wiswesser Line Notation | GVXFFF |
| LabNetwork Molecule ID | LN01808571 |
| InChI | InChI=1S/C2ClF3O/c3-1(7)2(4,5)6 |
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分类
- {uni_hamburg} no charge; carbonyl chloride; 1fragment
- {SNA} Chemical Synthesis, Specialty Gases, Synthetic Reagents
相关文献及参考
- Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.
- Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
- Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Year: 2000 Keyword: organic compounds; vapor press
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R37 Irritating to respiratory system 刺激呼吸道
- R14 Reacts violently with water 遇水会猛烈反应
- R35 Causes severe burns 会导致严重灼伤
TYPE OF TEST : LCLo - Lowest published lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 35300 ppb/6H TOXIC EFFECTS : Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - changes in structure or function of salivary glands REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0536764
TYPE OF TEST : LCLo - Lowest published lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 35300 ppb/6H TOXIC EFFECTS : Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - changes in structure or function of salivary glands REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0536764
TYPE OF TEST : LC - Lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - guinea pig DOSE/DURATION : >35300 ppb/6H TOXIC EFFECTS : Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - changes in structure or function of salivary glands REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0536764
其他信息
- MSDS 信息:三氟乙酰氯(354-32-5).msds
- 外观性质:无色、有刺激性的气体。
- 储运特性:库房通风低温干燥; 与酸、碱、易燃物、还原剂分开存放
- 灭火剂:水
- MOL 文件:354-32-5.mol
- Sigma Aldrich:354-32-5(sigmaaldrich)
- F:4.5-19-21
- 蒸气密度:4.6 (vs air)
- Hazard Note:Corrosive
- 类别:压缩气体和液化气体
- 可燃性危险特性:遇水分解有毒氯化氢和氟化氢气体
