2-Acetoxy-2-methylpropionyl bromide 2-乙酰氧基异丁酰溴
CAS 40635-67-4 MFCD00040923
化学结构图
SMILES: CC(=O)OC(C)(C)C(=O)Br
化学属性
| Mol. Formula | CH3COOC(CH3)2COBr |
|---|---|
| Mol. Weight | 209 |
| Refractive index | n20/D 1.457(lit.) |
| Boiling Point | 75-77 °C/12 mmHg(lit.) |
| Density | 1.431 g/mL at 25 °C(lit.) |
| Flash Point | >110°(230°F) |
| TSCA | No |
别名和识别编码
| Chemical Name | 2-Acetoxy-2-methylpropionyl bromide |
|---|---|
| Synonym | 乙酸 1-溴羰基-1-甲基乙酯 2-乙酰氧基异丁酰溴 2-Acetoxy-2-methylpropionyl bromide α-乙酰氧基异丁酰溴 2-乙酰氧基异丁酰溴 α-乙酰氧基异丁酰溴 2-Acetoxy-2-methylpropionyl bromide1-Bromocarbonyl-1-methylethyl acetate |
| PubChem Substance ID | 24862463 |
| Beilstein Registry Number | 2432585 |
| MDL Number | MFCD00040923 |
| CAS Number | 40635-67-4 |
| Chemical Name Translation | 2-乙酰氧基异丁酰溴 |
| LabNetwork Molecule ID | LN01281159 |
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分类
- {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
相关文献及参考
- Reagent for conversion of glycols to bromoacetates, useful in the formation of 3'-deoxynucleosides: J. Am. Chem. Soc., 95, 4016 (1973); Tetrahedron Lett., 26, 4295 (1985); 30, 6257 (1989).
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- R37 Irritating to respiratory system 刺激呼吸道
- R14 Reacts violently with water 遇水会猛烈反应
- R34 Causes burns 会导致灼伤
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
