(Acetylacetonato)Dicarbonyliridium(I) 乙酰丙酮二羰基铱(I)

CAS 14023-80-4 MFCD00049135

化学结构图

14023-80-4
SMILES: [C-]#[O+].[C-]#[O+].C/C(=C/C(C)=O)/O[Ir]

化学属性

Mol. FormulaIr(CO)2(CH3COCHCOCH3)
Mol. Weight347
TSCANo
Melting Point>145 ºC

别名和识别编码

Chemical Name(Acetylacetonato)Dicarbonyliridium(I)
Synonym Dicarbonyl(2,4-pentanedionato)iridium (Acetylacetonato)dicarbonyliridium (I) dicarbonyl(2,4-pentandione)iridium Dicarbonylacetylacetonato iridium(I) 二羰基乙酰丙酮铱(I) (Acetylacetonato)dicarbonyliridium(I) Dicarbonylacetylacetonatoiridium(I) Dicarbonyl-(2,4-pentandione)-iridium
MDL NumberMFCD00049135
PubChem Substance ID24866841
CAS Number14023-80-4
Chemical Name Translation乙酰丙酮二羰基铱(I)
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分类

  • {uni_hamburg} no charge; metal-organic; oxygen heterocycle; other heterocycle; 6RingOnly; 6ring; metal carbonyl; 1fragment; zwitterion
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iridium
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iridium Catalysts

相关文献及参考

  • Short: IV/20A Title: Vapor Pressure and Antoine Coefficients for Hydrocarbons and Sulfur-, Selenium-, Tellurium-, and Halogen-Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20A Year: 1999 Keyword: organic compounds; vapor pressure ISBN: 3-540-64735-X ISBN: 978-3-540-64735-5 Internet Resource: DOI:10.1007/b71086 RefComment: VIII, 373 pages.
  • Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Year: 2000 Keyword: organic compounds; vapor pressure ISBN: 3-540-64968-9 ISBN: 978-3-540-64968-7 Internet Resource: DOI:10.1007/b71424 RefComment: VII, 320 pages.

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S22 Do not breathe dust 不要吸入粉尘;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Packing GroupIII
UN Number UN3466
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R25 Toxic if swallowed 吞咽有毒
Hazard Codes Xn

系列性分类


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