Lithium Tert-Butoxide 叔丁醇锂
CAS 1907-33-1 MFCD00050479
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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现货库存
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分类
- {SNA} Acids & Bases, Bases, Chemical Synthesis, Lithium, Materials Science, Micro/NanoElectronics, Organic Bases, Solution Deposition Precursors, Synthetic Reagents
- {SNA} Chemical Synthesis,
- {SNA} Acids & Bases, Bases, Chemical Synthesis, Lithium, Micro/NanoElectronics, Organic Bases, Solution Deposition Precursors, Synthetic Reagents, 材料科学
- {uni_hamburg} no charge; 2fragments; ionic
- {SA} Chemical Synthesis, Lithium, Materials Science, Micro/NanoElectronics, Organic Bases, Solution Deposition Precursors, Synthetic Reagents
产品应用
- 用于有机合成,在有机金属的聚合反应中改变催化剂的活性和选择性。
相关文献及参考
- Structure Index 1 , 484:A:9
- Short: III/5a Title: Structure Data of Organic Crystals: C ... C 13 Author: Schudt, E.; Weitz, G. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/5a Year: 1971 ISBN: 3-540-05177-5 ISBN: 978-3-540-05177-0 Internet Resource: DOI:10.1007/b19970 RefComment: XXI, 736 pages, and VII, 890 pages. Hardcover Abstract: Volume III/5 offers a compitation as complete as possible of the space groups and lattice con-stants of all crystals which have been studied by means of X-rays, neutron and electron diffraction.
- Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
安全信息
GHS Symbol
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H228 Flammable solid 易燃固体
- H251 Self-heating: may catch fire 自我放热:可能着火
- H302 Harmful if swallowed 吞食有害
- H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
- H351 Suspected of causing cancer 怀疑致癌
- H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P235 Keep cool. 保持凉爽。
- P235+P410
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P301+P312
- P301+P317
- P301+P330+P331
- P302+P361+P354
- P303+P361+P353
- P304+P340
- P305+P351+P338
- P305+P354+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P316
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P330 Rinse mouth. 漱口
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P370+P378
- P402+P404
- P403+P235
- P405 Store locked up. 上锁保管。
- P407 Maintain air gap between stacks/pallets. 在堆叠/货板间保持气隙。
- P410 Protect from sunlight. 防止阳光照射。
- P413 Store bulk masses greater than … kg/…lbs at temperatures not exceeding … oC/…oF. 商店散装超过…kg/…lbs 时温度不应超过…oC/…oF.
- P420 Store away from other materials. 远离其他材料。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S33 Take precautionary measures against static discharges 对静电采取预防措施;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S7/8 Keep container tightly closed and dry 保存在严格密闭容器中,保持干燥;
- R11 Highly flammable 非常易燃
- R14 Reacts violently with water 遇水会猛烈反应
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R22 Harmful if swallowed 吞咽有害
- R34 Causes burns 会导致灼伤
- R37 Irritating to respiratory system 刺激呼吸道
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
- R48/20
- R51/53
- R62 Possible risk of impaired fertility 有削弱生殖能力的危险
- R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1682 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - respiratory depression REFERENCE : TOVEFN Toksikologicheskii Vestnik. (18-20 Vadkovskii per. Moscow, 101479, Russia) History Unknown Volume(issue)/page/year: (3),37,1996
其他信息
- MOL 文件:1907-33-1.mol
- MSDS 信息:Lithium 2-methylpropan-2-olate(1907-33-1).msds
- 外观性质:白色或淡黄色粉末,密度约0.5kg/L,熔点283℃,吸水分解,溶于甲苯、己烷、四氢呋喃等有机溶剂中。和水剧烈反应。
- F:3-10
- color:brown
- 吸水分解,溶于甲苯、己烷、四氢呋喃等有机溶剂中。和水剧烈反应。
- Acros Organics:叔丁醇锂 Lithium tert-butoxide, 1M solution in hexanes, AcroSeal?(1907-33-1)
- Alfa Aesar:叔丁醇锂,99.9%(metalsbasis) Lithium tert-butoxide, 99.9% (metals basis)(1907-33-1)
- Sigma Aldrich:1907-33-1(sigmaaldrich)
- 用途一:用于有机合成,在有机金属的聚合反应中改变催化剂的活性和选择性。
- 敏感性:Moisture Sensitive
- 叔丁醇锂价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 379311000 叔丁醇锂 Lithium tert-butoxide , 2.2M solution in THF, AcroSeal® 100 ML 1179元 2010/06/21 379318000 叔丁醇锂 Lithium tert-butoxide , 2.2M solution in THF, AcroSeal® 800 ML 4138元 2010/06/21 301220250 叔丁醇锂 Lithium tert-butoxide 99% 25 GR 1253元
- TSCA:Yes