4-Vinylbenzyl chloride 4-氯甲基苯乙烯

CAS 1592-20-7 MFCD00051362

化学结构图

1592-20-7
SMILES: C=Cc1ccc(CCl)cc1

化学属性

Mol. FormulaC9H9Cl
Mol. Weight152.62
Refractive indexn20/D 1.572(lit.)
Boiling Point228.9°C at 760 mmHg
Density1.083
Flash Point105°C

别名和识别编码

Chemical Name4-Vinylbenzyl chloride
Synonym 1-(Chloromethyl)-4-vinylbenzene {LY} 1-(Chloromethyl)-4-vinylbenzene {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylb
CAS Number1592-20-7
PubChem Substance ID74126
EC Number216-471-2
Beilstein Registry Number2204384
MDL NumberMFCD00051362
Reaxys-RN2204384
Chemical Name Translation4-氯甲基苯乙烯
InChIKeyZRZHXNCATOYMJH-UHFFFAOYSA-N
LabNetwork Molecule IDLN00195335
InChIInChI=1S/C9H9Cl/c1-2-8-3-5-9(7-10)6-4-8/h2-6H,1,7H2
Canonical SMILESC=CC1=CC=C(CCl)C=C1
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分类

  • {SNA} Monomers, Polymer Science, Styrene and Functionalized Styrene Monomers, 材料科学
  • {SNA} Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Organic Building Blocks
  • Materials Science, Monomers, Polymer Science, Styrene and Functionalized Styrene Monomers

相关文献及参考

  • 1. Chem. Mater. 16 , 2648-2655, (2004)
  • 2. Chem. Mater. 16 , 2282-2286, (2004)
  • 3. Polymer Prepr. 43 , 140-141, (2002)
  • FT-IR 2 (2), 1705:D / Structure Index 1 , 181:E:3

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 C
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P312
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Storage condition -20°C, stored under nitrogen {LY} -20°C, stored under nitrogen 0-10 0-10°C <0°C <;0 {} {LY} -20°C, stored under nitrogen {} {} {LY} -20°C, stored under nitrogen {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitr
UN Number 3265
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Packing GroupII
Hazard Class8

其他信息

  • Sigma Aldrich:1592-20-7(sigmaaldrich)
  • 上游原料:氢氧化钠 --> 二氯甲烷 --> 叔丁醇 --> 叔丁醇钾 --> 三氯化铝 --> 甲基叔丁基醚 --> 石脑油,原油 --> 氯甲基甲醚 --> 1,1,2,2-四氯乙烷 --> beta-溴代苯乙烷
  • 下游产品:4-(2-氰基乙基甲酰氨)苯基硼酸 --> 3-(2-氰基乙基甲酰氨)苯基硼酸 --> 4-(哌啶-1-羰基)苯基硼酸
  • 蒸气压:1 mm Hg ( 56.1 °C)
  • F:8-19
  • 存储注意事项:空气敏感;光敏感
  • 4-氯甲基苯乙烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1792 4-(氯甲基)苯乙烯(含稳定剂TBC,ONP及2-硝基对甲酚) 4-(Chloromethyl)styrene (stabilized with TBC + ONP + 2-Nitro-p-cresol) 250G 2260元 2014/06/02 C1792 4-(氯甲基)苯乙烯(含稳定剂TBC,ONP及2-硝基对甲酚) 4-(Chloromethyl)styrene (stabilized with TBC + ONP + 2-Nitro-p-cresol) 25G 369元 2010/06/21 422525000 4-氯甲基苯乙烯 4-Vinylbenzyl chloride 90%, tech. 500 GR 4836元
  • Acros Organics:4-乙烯基苄氯 4-Vinylbenzyl chloride, tech., 90%(1592-20-7)
  • 蒸气密度:5.3 (vs air)
  • MOL 文件:1592-20-7.mol
  • TCI Shanghai:对氯甲基苯乙烯(含稳定剂对叔丁基邻苯二酚,邻硝基苯酚及邻硝基甲酚) 4-(Chloromethyl)styrene (stabilized with TBC + ONP + 2-Nitro-p-cresol),>;90.0%(GC)(1592-20-7)
  • MSDS 信息:4-Chloromethyl styrene(1592-20-7).msds

系列性分类


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