Demeton-S-methyl solution 甲基内吸磷/异吸硫磷/内吸磷-S-甲基

CAS 919-86-8 MFCD00055464

化学结构图

919-86-8
SMILES: CCSCCSP(=O)(OC)OC

化学属性

Mol. FormulaC6H15O3PS2
Mol. Weight230

别名和识别编码

Chemical NameDemeton-S-methyl solution
CAS Number919-86-8
Synonym {uni_hamburg} 甲基内吸磷 { S-(2-(Ethylthio)ethyl) O,O-dimethyl thiophosphate demeton-S-methyl (ISO) Metasystox I Metaisoseptox Metasystox J Thiophosphate de O,O-dimethyle et de S-2-ethylthio-ethyle demeton S methyl Demeton-S-metile Methyl-mercaptofos teolery O,O-dimethyl S-[2-(ethylthio)ethyl]thi Metasystox forte Dimethyl S-(2-eththioethyl)thiophosphate O,O-Dimethyl-S-(2-aethylthio-aethyl)-monothiophosphat S-[2-(Ethylthio)ethyl] O,O-dimethyl thiophosphate {uni_hambur Thiophosphorsäure-S-(2-ethylthioethyl)-O,O-dimethylester Isometasystox Demethon methyl (II) Methylthionodemeton Methyl Isosystox Methyl isosystox O,O-Dimethyl 2-ethylmercaptoethyl thiophosphate, thiolo isomer O,O-Dimethyl S-(2-eththioethyl)phosphorothioate Ethanethiol, 2-(ethylthio)-, S-ester with O,O-dimethyl phosphorothioate O,O-Dimethyl S-2-(ethylthio) S-(2-Ethylthioethyl)-O,O-dimethyl-thiophosphat O,O-Dimethyl S-(2-(ethylthio)ethyl)phosphorothioate Metasystox 55 BAY 18436 Thiometon oxo Metasystox (I) S-(2-(ethylthio)ethyl) O,O-dimethylphosphorothioate Metaisosystox Methyl thionodemeton Demeton-S-methyl S-[2-(Ethylthio)ethyl] O,O-dimethyl phosphorothioate demeton S methyl (ISO) S-2-ethylthioethyl dimethyl phosphorothioate S-(2-(Ethylthio)ethyl) dimethyl phosphorothiolate Metaiso Bayer 25/154 Phosphorothioic acid, O,O-dimethyl S-(2-(ethylthio)ethyl) ester
MDL NumberMFCD00055464
PubChem Substance ID13526
Beilstein Registry Number1707311
EC Number213-052-6
Chemical Name Translation甲基内吸磷/异吸硫磷/内吸磷-S-甲基
Wiswesser Line Notation2S2SPO&O1&O1
InChIInChI=1S/C6H15O3PS2/c1-4-11-5-6-12-10(7,8-2)9-3/h4-6H2,1-3H3
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分类

  • {SNA} Acaricides,
  • Sulfur & Selenium Compounds
  • {SNA} Acaricides, All alphabetically sorted, Analytical Standards, Analytical/Chromatography, Chromatography, D, Demeton metabolites, Environmental Standards, Insecticides, Metabolites, Organophorous,
  • {SNA} Acaricides, All alphabetically sorted, Analytical Standards, Analytical/Chromatography, Chromatography, D, Demeton metabolites, Environmental Standards, Insecticides, Metabolites, Organophorous, Pesticides, Pesticides & Metabolites, Thiometon metabolite
  • {SNA} Acaricides,

产品应用

  • Colinesterase inhibitor. Used as insecticide.

相关文献及参考

  • Merck: 14,6051
  • Mezcua, M., et al.: Anal. Chem., 81, 913 (2009),
  • Short: IV/20A
  • Short: EINECS
  • Short: IV/20B
  • Pozo, O., et al.: Anal. Bioanal. Chem., 389, 1765 (2007),
  • Edson, E.F., et al.: Pharm. J., 185, 365 (1960),

安全信息

GHS Symbol
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Hazard statements
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302+H312+H332
WGK Germany2
Signal word Danger
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSTG1750000
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Hazard Codes F,Xn
Risk Statements
  • R11 Highly flammable 非常易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36 Irritating to eyes 刺激眼睛
Storage condition 储存温度2-8℃
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 30 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FMCHA2 Farm Chemicals Handbook.  (Meister Pub., 37841 Euclid Ave.,
   Willoughy, OH 44094)  Volume(issue)/page/year: -,C197,1991

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85DPAN "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel,"
   Perkow, W., Berlin, Verlag Paul Parey, 1971-1976  Volume(issue)/page/year:
   -,-,1971/1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 65 mg/kg
TOXIC EFFECTS :
   Biochemical - Enzyme inhibition, induction, or change in blood or tissue
   levels - other esterases
REFERENCE :
   BIJOAK Biochemical Journal.  (Biochemical Soc. Book Depot, POB 32, Commerce
   Way, Colchester, Essex CO2 8HP, UK)  V.1-    1906- Volume(issue)/page/year:
   67,187,1957

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 40 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag
   New York, Inc., 1971  Volume(issue)/page/year: -,346,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SP

{ha

{hazard

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 5 mg/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 28,405,1975

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 5 mg/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 28,405,1975

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 80 ppm
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 28,405,1975

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