CAS 2642-71-9 MFCD00055539-Azinphos-Ethyl 乙基古硫磷标准溶液 TAO{mole}

Azinphos-Ethyl 乙基古硫磷标准溶液

CAS 2642-71-9 MFCD00055539

化学结构图

SMILES: CCOP(=S)(OCC)SCn1nnc2ccccc2c1=O

化学属性

Mol. Formula	C12H16N3O3PS2
Mol. Weight	345.40
Density	0.7915
Refractive index	1.5928
Boiling Point	111℃
Melting Point	53℃
Solubility	不溶于水，溶于多数有机溶剂。

别名和识别编码

Chemical Name	Azinphos-ethyl
MDL Number	MFCD00055539
Beilstein Registry Number	0297468
CAS Number	2642-71-9
EC Number	220-147-6
Synonym	,3-benzotriazin-4(3h)-one 3,4-Dihydro-4-oxo-3-benzotriazinylmethyl O,O-diethyl phosphorodithioate 3,4-dihydro-4-oxo-3-benzotriazinylmethylo,o-diethylphosphorodithio 3-diethyloxyphosphinothioylthiomethyl-1,2,3-benzotriazin-4(3h)-one O,O-diethyl S-[(4-oxo-1,2,3-benzotriazin- O,O-diethyl S-[(4-oxo-1,2,3-benzotriazin-3(4H)-yl)methyl] phosphorodithioate AZINUGEC E Azinophos-ethyl Azinos Azinphos-ethyl (ISO) Azinphos-etile Bayer 16259 Bionex COTNION-ETHYL Cotnion-ethyl Ethyl Guthion GUTHION ETHYL O,O-DIETHYL-S-[4-OXO-1,2,3-BENZO TRIAZIN-3-[4H]-YLMETHYL]PHOSPHORODITHIOATE O,O-Diaethyl-S-(4-oxobenzotriazin-3-methyl)-dithiophosphat O,O-Diethyl phosphorodithioate S-ester with {PubChem}
Chemical Name Translation	乙基古硫磷标准溶液
Wiswesser Line Notation	T66 BNNNVJ D1SPS&O2&O2
PubChem Substance ID	17531
InChI	InChI=1S/C12H16N3O3PS2/c1-3-17-19(20,18-4-2)21-9-15-12(16)10-7-5-6-8-11(10)13-14-15/h5-8H,3-4,9H2,1-2H3

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产品应用

该品味有机磷杀虫杀螨剂，有很好的稳定性和持久性，主要用于防治棉花，果树，蔬菜等作物的害虫。

安全信息

RTECSTD8400000

GHS Symbol

WGK Germany3

Precautionary statements

P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P301+P310+P330
P301+P316
P302+P352
P302+P352+P312
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P316
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
P361+P364
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H300 Fatal if swallowed 吞食致命
H311 Toxic in contact with skin 皮肤接触中毒
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。

Hazard Codes T+,N

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Signal word Danger

Packing GroupII

Hazard Class6.1(a)

Storage condition 储存温度2-8℃ 0-6°C

UN Number 2783

Safety Statements

S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；

Risk Statements

R24 Toxic in contact with skin 与皮肤接触有毒
R50/53
R28 Very toxic if swallowed 吞咽极毒

Restrict 剧毒化学品

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OB

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 7 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARSIM* Agricultural Research Service, USDA Information Memorandum.
   (Beltsville, MD 20705)  Volume(issue)/page/year: 20,2,1966

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 390 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GYAV "Pflanzenschutz-und Schaedlingsbekaempfungsmittel: Abriss einer
   Toxikologie und Therapie von Vergiftungen," 2nd ed., Klimmer, O.R.,
   Hattingen, Fed. Rep. Ger., Hundt-Verlag, 1971  Volume(issue)/page/year:
   -,16,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - chicken
DOSE/DURATION           : 34400 ug/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - flaccid paralysis without anesthesia
   (usually neuromuscular blockage)
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   11,49,1967

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :

其他信息

灭火剂:砂土、干粉、泡沫
储运特性:库房通风低温干燥; 与食品原料分开储运
Sigma Aldrich:2642-71-9(sigmaaldrich)
类别:农药
毒性分级:剧毒
MOL 文件:2642-71-9.mol
杀虫剂单一组分标准液
用途一:该品为有机磷杀虫杀螨剂，有很好的稳定性和持久性，主要用于防治棉花、果树、蔬菜等作物的害虫。
上游原料:氨茴酸甲酯
溶于苯、丙酮，不溶于水，20℃时的蒸气压为0.293*10-4pa，对热稳定性好，遇碱易水解。
方法一:由邻氨基苯甲酸甲酯经重氮化、环合、羟甲基化、氯甲基化、缩合而得。
急性毒性:口服-大鼠 LD50: 7 毫克/公斤
可燃性危险特性:明火可燃; 受热放出有毒氧化氮、氧化硫、氧化磷气体
MSDS 信息:乙基谷硫磷(2642-71-9).msds
外观性质:无色针状结晶。