(E)-Benzaldehyde Oxime α-苯甲醛肟

CAS 622-31-1 MFCD00002119

化学结构图

622-31-1
SMILES:

化学属性

Mol. FormulaC7H7NO
Mol. Weight121.14
Refractive indexn20/D 1.591(lit.)
Boiling Point104 °C at 6 mmHg
Melting Point30-33 °C
Density1.110
Flash Point108°(226°F)
TSCAYes

别名和识别编码

Chemical Name(E)-Benzaldehyde Oxime
CAS Number622-31-1
Synonym (E)-Benzaldehyde oxime {LY} (E)-Benzaldehyde oxime {} {LY} (E)-Benzaldehyde oxime {} {} {LY} (E)-Benzaldehyde oxime {} {} {} {LY} (E)-Benzaldehyde oxime {} {} {} {} {LY} (E)-Benzaldehyde oxime {} {} {} {} {} {LY} (E)-Benzaldehyde oxime {} {} {} {} {} {} {LY} (E)-Benzaldehyde oxime {} {} {} {} {} {} {} {LY} (E)-Benzaldehyde oxime {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (E)-Benzaldehyde oxime {} {} {} {} {} {} {} {} {} {LY} (E)-Benzaldehyde oxime {} {} {} {} {} {} {} {} {} {} {LY} (E)-Benzaldehyde oxime {} {} {} {} {} {} {} {} {} {} {} {LY} (E)-Benzaldehyde oxime {} {} {} {} {} {} {} {} {} {} {} {} {LY} (E)-Benzaldehyde oxime {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (E)-Benzaldehyde oxime {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (E)-Benzaldehyde oxime {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (E)-Benzal
PubChem Substance ID87563225
MDL NumberMFCD00002119
Reaxys-RN1209596
Beilstein Registry Number7,218
EC Number213-261-2
Chemical Name Translationα-苯甲醛肟
InChIKeyVTWKXBJHBHYJBI-SOFGYWHQSA-N
Canonical SMILESO/N=C/C1=CC=CC=C1
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分类

  • {SA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Oximes
  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Oximes
  • Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Oximes

产品应用

  • An antioxidant

相关文献及参考

  • Jeong, H., et al.: Bioorg. Med. Chem. Lett., 16, 5576 (2006),
  • Andresen Bergstroem, M., et al.: J. Med. Chem., 51, 2541 (2008),
  • Beil. 7 ,218
  • Corp MSDS 1 (1), 346:B / FT-NMR 1 (3), 492:A / Structure Index 1 , 423:E:5 / Vapor Phase 3 , 1578:B
  • Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.
  • The oximate anion displaces activated aromatic nitro (or halogen) substituents. A second mole of oximate functions as base with elimination of benzonitrile and overall conversion of the nitro-compound to a phenol: J. Org. Chem., 39, 3343 (1974):
  • Conjugate addition of the oximate anion to ɑß-unsaturated acetylenic carbonyl compounds gives ß-dicarbonyl compounds: J. Org. Chem., 59, 1219 (1994). For example with reaction scheme, see Methyl­ phenyl­propiolate, B24587.
  • Aldoximes are conventionally dehydrated to nitriles with acetic anhydride; see, e.g.: Org. Synth. Coll., 2, 622 (1943). Many other dehydration methods have been described, including: Triethyl orthoformate and acid: J. Org. Chem., 39, 3424 (1974). DMF - SOCl2: Tetrahedron Lett., 25,

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
Signal word Warning
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moist

系列性分类


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