(S)-(2,2-Dimethyl-1,3-Dioxolan-4-Yl)Methyl 4-Methylbenzenesulfonate (S)-(2,2-二甲基-1,3-二氧戊环-4-基)甲基4-甲基苯磺酸酯

CAS 23735-43-5 MFCD00063234

化学结构图

23735-43-5
SMILES: CC1C=CC(=CC=1)S(=O)(=O)OC[C@@H]1COC(C)(C)O1

化学属性

Mol. FormulaC13H18O5S
Mol. Weight286.34
Refractive indexn20/D 1.506(lit.)
Density1.208
Melting Point25

别名和识别编码

Chemical Name(S)-(2,2-Dimethyl-1,3-Dioxolan-4-Yl)Methyl 4-Methylbenzenesulfonate
Synonym (S)-对甲基苯磺酸-2,2-二甲基-1,3-二氧戊环基-4-甲酯 2,3-异亚丙基-sn-甘油 1-甲苯磺酸酯 L-α,β-异亚丙基甘油-γ-甲苯磺酸酯 L-(+)-1,2-Isopropylideneglycerol 3-(p-Toluenesulfonate) (S)-对甲基苯磺酸-2,2-二甲基-1,3-二氧戊环基-4-甲酯 (S)-对甲基苯磺酸-2,2-二甲基-1,3-二氧戊环基-4-甲酯 2,3-异亚丙基-sn-甘油 1-甲苯磺酸酯 L-α,β-异亚丙基甘油-γ-甲苯磺酸酯 (S)-(+)-2,2-二甲基-1,3-二氧戊环基-4-基甲基对甲基苯磺酸酯 L-α,β-异亚丙基甘油-γ-甲苯磺酸酯 2,3-异亚丙基-sn-甘油 1-甲苯磺酸酯
CAS Number23735-43-5
PubChem Substance ID87568972
Beilstein Registry Number19(5)2,373
MDL NumberMFCD00063234
Reaxys-RN89799
Chemical Name Translation(S)-(2,2-二甲基-1,3-二氧戊环-4-基)甲基4-甲基苯磺酸酯
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Protected Alcohols
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Protected Alcohols

相关文献及参考

  • 1. M.E. Jung, T.J. Shaw J. Am. Chem. Soc. 102 , 6304, (1980)
  • Beil. 19 ,V,2,373

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P302+P352+P332+P313+P362+P364
Signal word
Storage condition 0-10 0-10°C
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类


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