CAS 535-75-1 MFCD00064347-Pipecolic acid 六氢吡啶-alpha-羧酸 TAO{mole}

Pipecolic acid 六氢吡啶-alpha-羧酸

CAS 535-75-1 MFCD00064347

化学结构图

SMILES: O=C(O)C1CCCCN1

化学属性

Mol. Formula	C6H11NO2
Mol. Weight	129.16
Melting Point	282 °C
TSCA	T
Density	1.125
Appearance	白色结晶性粉未，溶于乙醇及水中。
Stability	对光敏感
Solubility	soluble
Boiling Point	239.22 °C at 760 mmHg

别名和识别编码

Chemical Name	DL-Pipecolic Acid
CAS Number	535-75-1
Alfabeta Name	PIPERIDINECARBOXYLICACID 2--
MDL Number	MFCD00064347
EC Number	208-616-3
Beilstein Registry Number	81095
Synonym	Pipecolic acid {LY} Pipecolic acid homopipecolic acid pipecolic acid pipecolic acid hydrochloride, (+-)-isomer pipecolic acid, (+,-)-isomer pipecolic acid, (-)- pipecolic acid, (R)-isomer pipecolic acid, (S)-isomer pipecolic acid, 14C-labeled cpd, (+,-)-isomer pipecolic acid, ion (1-) pipecolic acid, ion(1-), (+,-)-isomer pipecolic acid, ion(1-), (S)-isomer pipecolic acid, monopotassium salt {} {LY} Pipecolic acid {} {} {LY} Pipecolic acid {} {} {} {LY} Pipecolic acid {} {} {} {} {LY} Pipecolic acid {} {} {} {} {} {LY} Pipecolic acid {} {} {} {} {} {} {LY} Pipecolic acid {} {} {} {} {} {} {} {LY} Pipecolic acid {} {} {} {} {} {} {} {} {LY} Pipecolic acid {} {} {} {} {} {} {} {} {} {LY} Pipecolic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Pipecolic acid {} {} {} {} {} {} {} {} {
Merck Number	7458
PubChem Substance ID	849
Chemical Name Translation	六氢吡啶-alpha-羧酸
Reaxys-RN	81095
LabNetwork Molecule ID	LN00008325
InChI	InChI=1S/C6H11NO2/c8-6(9)5-3-1-2-4-7-5/h5,7H,1-4H2,(H,8,9)
Canonical SMILES	O=C(O)C1CCCCN1

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安全信息

Warnings IRRITANT

Signal word Warning

GHS Symbol

WGK Germany3

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S37 Wear suitable gloves 戴适当手套；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352
P304+P340
P305+P351+P338
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P313
P332+P317
P337+P313
P337+P317
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

RTECSTK6021000

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes Xi

Storage condition 2-8°C {LY} 2-8°C Store at RT. {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 610 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CEXPB9 Clinical and Experimental Pharmacology and Physiology.  (Blackwell
   Scientific Publications, (Australia) Pty Ltd., 107 Barry St., Carlton, Vic.
   3053, Australia)  V.1-  1974-  Volume(issue)/page/year: 21,997,1994

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   THERAP Therapie.  (Doin, Editeurs, 8, Place de l'Odeon, F-75006 Paris,
   France)  V.1-    1946-  Volume(issue)/page/year: 23,1343,1968

其他信息

MOL 文件:4043-87-2.mol
MSDS 信息:DL-Pipecolic acid(4043-87-2).msds
检测方法:T,NMR
用途一:用作医药中间体
TCI Shanghai:DL-哌啶-2-甲酸 DL-Pipecolic Acid,>;98.0%(T)(535-75-1)
下游产品:(1-甲基-2-哌啶)甲胺 --> 2-(叔丁氧羰基氨基甲基)-哌啶
MOL 文件:535-75-1.mol
六氢吡啶-alpha-羧酸价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 P0442 DL-哌啶甲酸 DL-Pipecolic Acid 25G 690元 2014/06/02 P0442 DL-哌啶甲酸 DL-Pipecolic Acid 250G 3920元 2010/06/21 131281000 六氢吡啶-alpha-羧酸 DL-Pipecolinic acid 99% 100 GR 2356元
Alfa Aesar:DL-2-哌啶酸,99% DL-Pipecolinic acid, 99%(535-75-1)
Hazard Note:Irritant
Sigma Aldrich:535-75-1(sigmaaldrich)
Sigma Aldrich:4043-87-2(sigmaaldrich)
TSCA:T
2-哌啶甲酸价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 xw010319 2-哌啶甲酸 25g 400元
Acros Organics:DL-2-哌啶甲酸 DL-Pipecolinic acid, 99%(535-75-1)
下游产品:(1-甲基-2-哌啶)甲胺