CAS 2835-06-5 MFCD00064402-DL-α-Phenylglycine DL-苯苷氨酸(DL-2-苯基甘氨酸) TAO{mole}

DL-α-Phenylglycine DL-苯苷氨酸(DL-2-苯基甘氨酸)

CAS 2835-06-5 MFCD00064402

化学结构图

SMILES: NC(C(=O)O)c1ccccc1

化学属性

Mol. Formula	C8H9NO2
Mol. Weight	151.16
Density	1.422
Melting Point	290°C
TSCA	Yes

别名和识别编码

Chemical Name	DL-α-Phenylglycine
CAS Number	2835-06-5
Alfabeta Name	PHENYLGLYCINE DLALPHA--
MDL Number	MFCD00064402
EC Number	220-608-1
Beilstein Registry Number	3197862
Synonym	2-Phenylglycine {LY} 2-Phenylglycine {} {LY} 2-Phenylglycine {} {} {LY} 2-Phenylglycine {} {} {} {LY} 2-Phenylglycine {} {} {} {} {LY} 2-Phenylglycine {} {} {} {} {} {LY} 2-Phenylglycine {} {} {} {} {} {} {LY} 2-Phenylglycine {} {} {} {} {} {} {} {LY} 2-Phenylglycine {} {} {} {} {} {} {} {} {LY} 2-Phenylglycine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Phenylglycine {} {} {} {} {} {} {} {} {} {} {LY} 2-Phenylglycine {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Phenylglycine {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Phenylglycine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Phenylglycine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Phenylglycine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Phenylglycine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Phenylglycine {} {} {} {} {} {} {} {} {} {} {} {}
Merck Number	7291
PubChem Substance ID	3866
Reaxys-RN	608018
Chemical Name Translation	DL-苯苷氨酸(DL-2-苯基甘氨酸)
LabNetwork Molecule ID	LN00173283
InChI	InChI=1S/C8H9NO2/c9-7(8(10)11)6-4-2-1-3-5-6/h1-5,7H,9H2,(H,10,11)
Canonical SMILES	O=C(O)C(N)C1=CC=CC=C1

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

头孢氨苄、头孢克罗的中间体。

安全信息

Warnings IRRITANT

Signal word Warning

GHS Symbol

WGK Germany3

Safety Statements

S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352
P304+P340
P305+P351+P338
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P313
P332+P317
P337+P313
P337+P317
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

其他信息

上游原料:氰化钠 --> 4-氯苯甲醛 --> 乙醛酸 --> 碳酸氢氨
图谱信息:2-氨基-2-苯基乙酸(2835-06-5)质谱(MS) 2-氨基-2-苯基乙酸(2835-06-5)红外图谱(IR1) 2-氨基-2-苯基乙酸(2835-06-5)红外图谱(IR2)
Alfa Aesar:DL-1-苯基甘氨酸,98% DL-2-Phenylglycine, 98%(2835-06-5)
约255℃升华而不熔化。微溶于醇及有机溶剂，不溶于水，溶于碱溶液。
TCI Shanghai:DL-α-氨基苯乙酸 DL-2-Phenylglycine,>;98.0%(T)(2835-06-5)
MOL 文件:2835-06-5.mol
外观性质:片状结晶。约255℃升华而不熔化。微溶于醇及有机溶剂，不溶于水，溶于碱溶液。熔点：290 °C
用途一:用于制造左旋苯甘氨酸
Sigma Aldrich:2835-06-5(sigmaaldrich)
下游产品:1-甲基-3-苯基哌嗪
方法一:苯甲醛经环合、水解、中和而得该品。将碳酸氢氨及氰化钠溶液投入反应锅，在搅拌下滴入苯甲醛，75-80℃保温反应3h，得苯乙内酰脲。抽入高压釜内，加氢氧化钠溶液，升温，将反应生成的氨气放空1h，然后在130-160℃水解3h。放料，加HCl中和至pH=6-7，离心甩干，得DL-2-苯基甘氨酸。还有乙醛酸路线，可降低生产成本，解决传统工艺原料毒性高的难题。
用途二:头孢氨苄、头孢克罗的中间体。
Acros Organics:DL-alpha-苯甘氨酸 DL-alpha-Phenylglycine, 99%(2835-06-5)
2-氨基-2-苯基乙酸价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 P0326 DL-2-苯甘氨酸 DL-2-Phenylglycine 500G 912元 2014/06/02 P0326 DL-2-苯甘氨酸 DL-2-Phenylglycine 25G 138元 2010/06/21 130641000 2-氨基-2-苯基乙酸 DL-alpha-Phenylglycine 99% 100 GR 367元