CAS 52462-29-0 MFCD00064793-Dichloro(p-cymene)ruthenium(II) dimer 二氯(4-甲基异丙苯)钌(II)二聚体 TAO{mole}

Dichloro(p-cymene)ruthenium(II) dimer 二氯(4-甲基异丙苯)钌(II)二聚体

CAS 52462-29-0 MFCD00064793

化学结构图

SMILES: Cc1ccc(C(C)C)cc1.Cc1ccc(C(C)C)cc1.Cl[Ru]Cl.Cl[Ru]Cl

化学属性

Mol. Formula	C20H28Cl4Ru2
Mol. Weight	612.39
TSCA	No
Melting Point	247.0-250.0°C
Density	1.422
Stability	对光敏感

别名和识别编码

Chemical Name	Dichloro(p-cymene)ruthenium(II) dimer
MDL Number	MFCD00064793
Synonym	Dichloro(p-cymene)ruthenium(II) dimer {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {}
EC Number	435-530-5
CAS Number	52462-29-0
PubChem Substance ID	87569153
Beilstein Registry Number	2384789
Chemical Name Translation	二氯(4-甲基异丙苯)钌(II)二聚体
LabNetwork Molecule ID	LN00155202
Canonical SMILES	Cc1ccc(C(C)C)cc1.Cc2ccc(C(C)C)cc2.Cl[Ru]3Cl[Ru](Cl)Cl3

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产品应用

Hydrosilylation Catalysts
Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Cyclometalated ruthenium complexes with arylimines and nitrogen-containing heterocycles via C-H bond activation

安全信息

Safety Statements

S24 Avoid contact with skin 避免皮肤接触；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R22 Harmful if swallowed 吞咽有害
R36 Irritating to eyes 刺激眼睛
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
R52/53

WGK Germany2

GHS Symbol

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352+P332+P313+P362+P364
P305+P351+P338
P305+P351+P338+P337+P313
P332+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Warning

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
H302 Harmful if swallowed 吞食有害
H319 Causes serious eye irritation 严重刺激眼睛

Hazard Codes Xn

Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr