CAS 536-17-4 MFCD00064857-5-(4-Dimethylaminobenzylidene)rhodanine 5-(4-二甲氨基亚苄基)罗丹宁 TAO{mole}

5-(4-Dimethylaminobenzylidene)rhodanine 5-(4-二甲氨基亚苄基)罗丹宁

CAS 536-17-4 MFCD00064857

化学结构图

SMILES: CN(C)c1ccc(/C=C2/SC(=S)NC2=O)cc1

化学属性

Mol. Formula	C12H12N2OS2
Mol. Weight	264
Melting Point	285-288
TSCA	Yes
Density	1.36

别名和识别编码

Chemical Name	5-(4-Dimethylaminobenzylidene)rhodanine
MDL Number	MFCD04969049
PubChem Substance ID	87567291
Beilstein Registry Number	27,433
CAS Number	536-17-4
EC Number	208-625-2
Reaxys-RN	6723919
Merck Number	3231
Synonym	5-(p-Dimethylaminobenzoylidene)rhodanine 5-(p-dimethylaminobenzal)rhodanine 对二甲氨基苄叉罗丹宁 p-Dimethylaminobenzalrhodanine 5-(P-DIMETHYLAMINOBENZYLIDENE)-RHODAMINE 5-(4-DIMETHYLAMINOBENZYLIDENE)RHODANINE 5-[4-(dimethylamino)phenyl]methylene-2-thioxo-4-Thiazolidinone p-Dimethylaminobenzylidene rhodamine 二甲基胺亚苄基罗丹宁 4-二甲基氨基苯亚甲基罗丹宁;5-(对二甲氨基亚苄基)罗丹宁對二甲胺苯亞甲若丹林 5-[4-(二甲基氨基)苯基]亚甲基-2-硫代-4-噻唑烷酮 5-[[4-(dimethylamino)phenyl]methylene]-2-thioxo-4-thiazolidinon 试银灵 5-［4-（二甲基氨基）苯基］亚甲基-2-硫代-4-噻唑烷酮 4-Dimethylaminobenzalrhodanine {Chemicalb 对二甲氨基亚苄罗丹宁 5-(4-二甲氨
Chemical Name Translation	5-(4-二甲氨基亚苄基)罗丹宁
Wiswesser Line Notation	T5SYMV EHJ BUS E1U1R DN1&1
LabNetwork Molecule ID	LN00195906
InChI	InChI=1S/C12H12N2OS2/c1-14(2)9-5-3-8(4-6-9)7-10-11(15)13-12(16)17-10/h3-7H,1-2H3,(H,13,15,16)/b10-7+

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分类

{SNA} Building Blocks, C12 to C20+, Chemical Synthesis, Heterocyclic Building Blocks, Thiazoles
Alkaloids, Amines, Amino Acids, Analytical Reagents, Analytical/Chromatography, Derivatization Reagents, Derivatization Reagents HPLC, Derivatization Reagents TLC, Hydrazines, Indoles, Metals, precious, Peroxides, Proteins & Peptides, TLC Reagents, D-F, TLC Visualization Reagents (alphabetic sort), TLC Visualization Reagents (by application), UV-VIS
{SA} Alkaloids, Amines, Amino Acids, Analytical Reagents, Analytical/Chromatograp

产品应用

用于检测Ag、Au、 Cu、Hg、Pd、Pt、生物碱(alkaloids)、安替比林、尿蓝母(indican)、硫铵安类药剂和尿胆素原(urobilinogen)
主要是测定银、钯和汞的试剂1,2；也用于检测金3；用于光度法测定放射自显影4。
参考文献：
1. G.H. Ayres et al. Anal. Chim. Acta 24, 241, (1961)
2. G. Jangg Fresenius J. Anal. Chem. 183, 255, (1961)
3. L.E. Lichtenstein Anal. Chem. 47, 465, (1975)
4. J.W. Ludlow et al. Anal. Biochem. 154, 104, (1986) abstract

安全信息

RTECSVI8090000

WGK Germany3

Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

Signal word

Hazard statements

H315 Causes skin irritation 会刺激皮肤

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P350
P302+P352+P332+P313+P362+P364
P305+P351+P338
P305+P351+P338+P337+P313
P332+P313
P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用

Safety Statements

S22 Do not breathe dust 不要吸入粉尘；
S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；

GHS Symbol

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,11,1953

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 150 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD603-561

其他信息

检测方法:HPLC,NMR
Acros Organics:5-(对二甲氨基亚苄基)罗丹宁/试银灵 5-(4-Dimethylaminobenzylidene)rhodanine, 99%(536-17-4)
Sigma Aldrich:536-17-4(sigmaaldrich)
图谱信息:试银灵 (536-17-4)红外图谱(IR2) 试银灵 (536-17-4)红外图谱(IR1) 试银灵 (536-17-4)质谱(MS)
用途一:用于检测Ag、Au、 Cu、Hg、Pd、Pt、生物碱(alkaloids)、安替比林、尿蓝母(indican)、硫铵安类药剂和尿胆素原(urobilinogen) 主要是测定银、钯和汞的试剂1,2；也用于检测金3；用于光度法测定放射自显影4。参考文献：1. G.H. Ayres et al. Anal. Chim. Acta 24, 241, (1961)2. G. Jangg Fresenius J. Anal. Chem. 183, 255, (1961)3. L.E. Lichtenstein Anal. Chem. 47, 465, (1975)4. J.W. Ludlow et al. Anal. Biochem. 154, 104, (1986) abstract
Alfa Aesar:5-(4-二甲基氨基苯亚甲基)绕丹宁,98% 5-(4-Dimethylaminobenzylidene)rhodanine 98%(536-17-4)
MOL 文件:536-17-4.mol
TCI Shanghai:5-[4-(二甲基氨基)苯基]亚甲基-2-硫代-4-噻唑烷酮 4-Dimethylaminobenzylidenerhodanine,>;98.0%(LC)(T)(536-17-4)