(S)-3,3,3-Trifluoro-2-Methoxy-2-Phenylpropanoyl Chloride (S)-3,3,3-三氟-2-甲氧基-2-苯基丙酰氯
CAS 20445-33-4 MFCD00067105
化学结构图
SMILES: CO[C@@](C(=O)Cl)(c1ccccc1)C(F)(F)F
化学属性
| Mol. Formula | C10H8ClF3O2 |
|---|---|
| Mol. Weight | 253 |
| Boiling Point | 68-72 |
| Refractive index | 1.4670 to 1.4700 |
| Density | 1.35 |
| Flash Point | 89°C(lit.) |
| TSCA | No |
别名和识别编码
| Chemical Name | (S)-3,3,3-Trifluoro-2-Methoxy-2-Phenylpropanoyl Chloride |
|---|---|
| CAS Number | 20445-33-4 |
| Alfabeta Name | METHOXYTRIFLUOROMETHYLPHENYLACETYLCHLORIDE ALPHAALPHAS+(())------ |
| MDL Number | MFCD00067105 |
| Synonym | (S)-(+)-ALPHA-METHOXY-ALPHA-(TRIFLUOROMETHYL)BENZENEACETYLCHLORIDE (S)-(+)-MTPA-Cl (S)-(+)-MTPA-Cl Mosher 酸氯化物 (+)-ALPHA-METHOXY-ALPHA-(TRIFLUOROMETHYL)PHENYLACETYL CHLORIDE (R)-(-)-A-METHOXY-A-(TRIFLUOROMETHYL)PHENYLACETYL CHLORIDE (S)-(+)-Mosher's acid chloride R(-)-MTPA-CL (+)-MTPA-CL (R)-(-)-ALPHA-METHOXY-ALPHA-(TRIFLUOROMETHYL)BENZENEACETYLCHLORIDE Mosher 酸氯化物 (S)-(+)-1-METHOXY-1-(TRIFLUOROMETHYL)PHENYL ACETYL CHLORIDE (S)-(+)-MTPA-CL MOSHER'S ACID CHLORIDE (S)-(-)-ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETYL CHLORIDE (S)-(+)-ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETYL CHLORIDE (R)-(+)-1-METHOXY-1-(TRIFLUOROMETHYL)PHENYLACETYL CHLORIDE (S)-(+)-A-METHOXY-A-(TRIFLUOROMETHYL)PHENYLACETYL CHLORIDE (S)-(+)-α-甲氧基-α-三氟甲基苯乙酰氯 R(-)-ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETIC ACID CHLORIDE (+)-MOSHER'S ACID CHLORIDE (R)-(-)-1-METHOXY-1-(TRIFLUOROMETHYL)PHENYL ACETYL CHLORIDE (S)-(+)-α-Methoxy-α-trifluoromethylphenylacetyl chloride (R)-(-)-ALPHA-METHOXY-ALPHA-(TRIFLUOROMETHYL)PHENYLACETYL CHLORIDE (+)-MOSHER'S CHLORIDE (+)-alpha-Methoxy-alpha-(trifluoromethyl)phenylacetylChloride[forDeterminationoftheopticalpurityofAlcoholsandAmines] |
| PubChem Substance ID | 160871159 |
| Beilstein Registry Number | 3591562 |
| Reaxys-RN | 3591562 |
| Merck Number | 6280 |
| Chemical Name Translation | (S)-3,3,3-三氟-2-甲氧基-2-苯基丙酰氯 |
| InChIKey | PAORVUMOXXAMPL-VIFPVBQESA-N |
| LabNetwork Molecule ID | LN00118763 |
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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现货库存
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分类
- Acid Halides, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Organic Building Blocks
- {SNA} Chiral, Chiral Derivatization Reagents, Chiral GC Derivatization Reagents, Derivatization Reagents, Derivatization Reagents HPLC, 分析/色谱, 分析试剂
- {SNA} Analytical Reagents, Analytical/Chromatography, Chiral, Chiral Derivatization Reagents, Chiral GC Derivatization Reagents, Derivatization Reagents, Derivatization Reagents HPLC
相关文献及参考
- 1. Angew. Chem. Int. Ed. Engl. 43 , 2420-2423, (2004) 摘要
- 2. Org. Lett. 6 , 1757-1760, (2004) 摘要
- 3. J. Chem. Ecol. 30 , 819-834, (2004) 摘要
- Hoye, T. R.; Jeffrey, C. S.; Shao, F. Nat. Protoc. 2 , 2451-2458, (2007) 摘要
- Merck 14 ,6280
- FT-NMR 1 (2), 1333:C / RegBook 1 (2), 1965:I / Structure Index 1 , 316:C:2
安全信息
GHS Symbol
- H290 May be corrosive to metals 可能腐蚀金属。
- H227 Combustible liquid 可燃液体
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P234 Keep only in original container. 只保留在原来的容器中。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P303+P361+P353+P310+P363
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P308+P311
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P370+P378
- P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P403+P233
- P405 Store locked up. 上锁保管。
- P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R34 Causes burns 会导致灼伤
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
其他信息
- Sigma Aldrich:20445-33-4(sigmaaldrich)
- F:10-21
